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2,1,3-Benzoselenadiazole-containing Zinc(II) Halide Complexes: Chalcogen Bonding in the Solid State and Catalytic Activity in the Schiff Condensation. / Сысоева, Александра Александровна; Новиков, Александр Сергеевич; Суслонов, Виталий Валерьевич; Болотин, Дмитрий Сергеевич; Ильин, Михаил Вячеславович.

в: Inorganica Chimica Acta, Том 561, 121867, 01.02.2024.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Сысоева, АА, Новиков, АС, Суслонов, ВВ, Болотин, ДС & Ильин, МВ 2024, '2,1,3-Benzoselenadiazole-containing Zinc(II) Halide Complexes: Chalcogen Bonding in the Solid State and Catalytic Activity in the Schiff Condensation', Inorganica Chimica Acta, Том. 561, 121867. https://doi.org/10.1016/j.ica.2023.121867

APA

Сысоева, А. А., Новиков, А. С., Суслонов, В. В., Болотин, Д. С., & Ильин, М. В. (2024). 2,1,3-Benzoselenadiazole-containing Zinc(II) Halide Complexes: Chalcogen Bonding in the Solid State and Catalytic Activity in the Schiff Condensation. Inorganica Chimica Acta, 561, [121867]. https://doi.org/10.1016/j.ica.2023.121867

Vancouver

Сысоева АА, Новиков АС, Суслонов ВВ, Болотин ДС, Ильин МВ. 2,1,3-Benzoselenadiazole-containing Zinc(II) Halide Complexes: Chalcogen Bonding in the Solid State and Catalytic Activity in the Schiff Condensation. Inorganica Chimica Acta. 2024 Февр. 1;561. 121867. https://doi.org/10.1016/j.ica.2023.121867

Author

Сысоева, Александра Александровна ; Новиков, Александр Сергеевич ; Суслонов, Виталий Валерьевич ; Болотин, Дмитрий Сергеевич ; Ильин, Михаил Вячеславович. / 2,1,3-Benzoselenadiazole-containing Zinc(II) Halide Complexes: Chalcogen Bonding in the Solid State and Catalytic Activity in the Schiff Condensation. в: Inorganica Chimica Acta. 2024 ; Том 561.

BibTeX

@article{25cb70e7f68f43119fda3070232f8e04,
title = "2,1,3-Benzoselenadiazole-containing Zinc(II) Halide Complexes: Chalcogen Bonding in the Solid State and Catalytic Activity in the Schiff Condensation",
abstract = "XRD study of crystals of zinc(II) halide complexes featuring 2,1,3-benzoselenadiazole (L) ligands [ZnL2X2] (X = Cl, Br, I) indicated availability of intramolecular chalcogen bonds between the Se atom and the halide ligands, which affect a rotation barrier around the Zn–N bonds and thus control a geometry of these species. In the solid state, the Se atom additionally forms intermolecular chalcogen bonds with the N atom of the 2,1,3-benzoselenadiazole ligands, which results in formation of infinite 1D chains. Theoretical calculations and experimental kinetic study indicated that although the Se atom serves as a Lewis acid, coordination of the organic ligand to the zinc(II) center does not provide enhanced catalytic activity of the latter in the model reaction of the Schiff condensation.",
keywords = "Catalytic activity, Chalcogen bond, Noncovalent interactions, Zinc(II) complexes",
author = "Сысоева, {Александра Александровна} and Новиков, {Александр Сергеевич} and Суслонов, {Виталий Валерьевич} and Болотин, {Дмитрий Сергеевич} and Ильин, {Михаил Вячеславович}",
year = "2024",
month = feb,
day = "1",
doi = "10.1016/j.ica.2023.121867",
language = "English",
volume = "561",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - 2,1,3-Benzoselenadiazole-containing Zinc(II) Halide Complexes: Chalcogen Bonding in the Solid State and Catalytic Activity in the Schiff Condensation

AU - Сысоева, Александра Александровна

AU - Новиков, Александр Сергеевич

AU - Суслонов, Виталий Валерьевич

AU - Болотин, Дмитрий Сергеевич

AU - Ильин, Михаил Вячеславович

PY - 2024/2/1

Y1 - 2024/2/1

N2 - XRD study of crystals of zinc(II) halide complexes featuring 2,1,3-benzoselenadiazole (L) ligands [ZnL2X2] (X = Cl, Br, I) indicated availability of intramolecular chalcogen bonds between the Se atom and the halide ligands, which affect a rotation barrier around the Zn–N bonds and thus control a geometry of these species. In the solid state, the Se atom additionally forms intermolecular chalcogen bonds with the N atom of the 2,1,3-benzoselenadiazole ligands, which results in formation of infinite 1D chains. Theoretical calculations and experimental kinetic study indicated that although the Se atom serves as a Lewis acid, coordination of the organic ligand to the zinc(II) center does not provide enhanced catalytic activity of the latter in the model reaction of the Schiff condensation.

AB - XRD study of crystals of zinc(II) halide complexes featuring 2,1,3-benzoselenadiazole (L) ligands [ZnL2X2] (X = Cl, Br, I) indicated availability of intramolecular chalcogen bonds between the Se atom and the halide ligands, which affect a rotation barrier around the Zn–N bonds and thus control a geometry of these species. In the solid state, the Se atom additionally forms intermolecular chalcogen bonds with the N atom of the 2,1,3-benzoselenadiazole ligands, which results in formation of infinite 1D chains. Theoretical calculations and experimental kinetic study indicated that although the Se atom serves as a Lewis acid, coordination of the organic ligand to the zinc(II) center does not provide enhanced catalytic activity of the latter in the model reaction of the Schiff condensation.

KW - Catalytic activity

KW - Chalcogen bond

KW - Noncovalent interactions

KW - Zinc(II) complexes

UR - https://www.mendeley.com/catalogue/6faf37a9-c09d-3b76-a909-7f935f5acd2c/

U2 - 10.1016/j.ica.2023.121867

DO - 10.1016/j.ica.2023.121867

M3 - Article

VL - 561

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 121867

ER -

ID: 114244306