Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
13C-detected 1H-2H separated local field NMR spectroscopy. / Dvinskikh, S. V.; Sandström, D.; Zimmermann, H.; Maliniak, A.
в: Chemical Physics Letters, Том 382, № 3-4, 05.12.2003, стр. 410-417.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - 13C-detected 1H-2H separated local field NMR spectroscopy
AU - Dvinskikh, S. V.
AU - Sandström, D.
AU - Zimmermann, H.
AU - Maliniak, A.
PY - 2003/12/5
Y1 - 2003/12/5
N2 - We present a new NMR method for measuring 1H-2H dipolar couplings in macroscopically oriented media. To overcome the lack of dipolar resolution in 1D 1H and 2H spectra of deuterated molecules, we use a 2D heteronuclear correlation experiment where 1H chemical shifts and 1H-2H dipolar interactions in the first dimension are correlated with 13C chemical shifts and 2H-13C dipolar interactions in the second dimension. The technique is demonstrated on a columnar liquid-crystalline phase.
AB - We present a new NMR method for measuring 1H-2H dipolar couplings in macroscopically oriented media. To overcome the lack of dipolar resolution in 1D 1H and 2H spectra of deuterated molecules, we use a 2D heteronuclear correlation experiment where 1H chemical shifts and 1H-2H dipolar interactions in the first dimension are correlated with 13C chemical shifts and 2H-13C dipolar interactions in the second dimension. The technique is demonstrated on a columnar liquid-crystalline phase.
UR - http://www.scopus.com/inward/record.url?scp=0345724932&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2003.10.071
DO - 10.1016/j.cplett.2003.10.071
M3 - Article
AN - SCOPUS:0345724932
VL - 382
SP - 410
EP - 417
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 3-4
ER -
ID: 48949803