DOI

  • Javad S.Z. Sabounchei
  • Brian T. Heaton
  • Jonathan A. Iggo
  • Chacko Jacob
  • Ivan S. Podkorytov

A complete NMR study involving both 1D and 2D 13C-{103Rh} and 31P-{103Rh} HMQC measurements, on [Rh6C(CO)14(PPh3)]2- are reported and discussed, together with the multiple Rh quantum effects found for resonances associated with edge- and face-bridging CO's. As found in [Rh6C(CO)15]2-, the carbonyl ligands in [Rh6C(CO)14(PPh3)]2- undergo CO-intermolecular exchange with 13CO at different rates; for the edge-bridging CO's, the lower the value of 1J(Rh-CO), the faster the rate of intermolecular exchange with 13CO.

Язык оригиналаанглийский
Страницы (с-по)339-348
Число страниц10
ЖурналJournal of Cluster Science
Том12
Номер выпуска1
DOI
СостояниеОпубликовано - 2001

    Предметные области Scopus

  • Биохимия
  • Химия (все)
  • Материаловедение (все)
  • Физика конденсатов

ID: 88617796