Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A complete NMR study involving both 1D and 2D 13C-{103Rh} and 31P-{103Rh} HMQC measurements, on [Rh6C(CO)14(PPh3)]2- are reported and discussed, together with the multiple Rh quantum effects found for resonances associated with edge- and face-bridging CO's. As found in [Rh6C(CO)15]2-, the carbonyl ligands in [Rh6C(CO)14(PPh3)]2- undergo CO-intermolecular exchange with 13CO at different rates; for the edge-bridging CO's, the lower the value of 1J(Rh-CO), the faster the rate of intermolecular exchange with 13CO.
Язык оригинала | английский |
---|---|
Страницы (с-по) | 339-348 |
Число страниц | 10 |
Журнал | Journal of Cluster Science |
Том | 12 |
Номер выпуска | 1 |
DOI | |
Состояние | Опубликовано - 2001 |
ID: 88617796