Кристаллизация в условиях “мягкой” химии новых наноматериалов на основе неорганических фторидов и перспективы их применения

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Кристаллизация в условиях “мягкой” химии новых наноматериалов на основе неорганических фторидов и перспективы их применения. / Гулина, Лариса Борисовна ; Толстой, Валерий Павлович ; Мурин, Игорь Васильевич.

в: ЖУРНАЛ НЕОРГАНИЧЕСКОЙ ХИМИИ, Том 69, № 3, 17.07.2024, стр. 6-19.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{bc8f59b258ea40afa5fdccd83ef58173,

title = "Кристаллизация в условиях “мягкой” химии новых наноматериалов на основе неорганических фторидов и перспективы их применения",

abstract = "Abstract: The formation and growth specifics of metal fluoride MF2 (where M = Ca, Sr, or Pb) and MF3 (where M = Sc, La, or Ln) crystals by reacting components of aqueous metal salt solutions with hydrogen fluoride gas at the planar solution–gas interface at room temperature are considered. Compounds with different crystal structures: PbF2 (space groups Pnma and Fmm), ScF3 (sp. gr. Pmm and P6/mmm), and LaF3 (space group 1) were chosen as objects of study. The factors having a significant influence on the morphology, size, and ordering of the grown crystals have been identified. An opportunity to prepare 1D and 2D crystals has been shown for some compounds. Probable applications fields of nanomaterials based on the prepared compounds are analyzed. The conclusion is made about a potential of the interface technique for use in the design of new solid electrolytes, optically active materials, and functional coatings.",

keywords = "ionic conductors, nanocrystals, solution–gas interface",

author = "Гулина, {Лариса Борисовна} and Толстой, {Валерий Павлович} and Мурин, {Игорь Васильевич}",

year = "2024",

month = jul,

day = "17",

doi = "10.1134/s0036023623603070",

language = "русский",

volume = "69",

pages = "6--19",

journal = "ЖУРНАЛ НЕОРГАНИЧЕСКОЙ ХИМИИ",

issn = "0044-457X",

publisher = "Издательство {"}Наука{"}",

number = "3",

}

RIS

TY - JOUR

T1 - Кристаллизация в условиях “мягкой” химии новых наноматериалов на основе неорганических фторидов и перспективы их применения

AU - Гулина, Лариса Борисовна

AU - Толстой, Валерий Павлович

AU - Мурин, Игорь Васильевич

PY - 2024/7/17

Y1 - 2024/7/17

N2 - Abstract: The formation and growth specifics of metal fluoride MF2 (where M = Ca, Sr, or Pb) and MF3 (where M = Sc, La, or Ln) crystals by reacting components of aqueous metal salt solutions with hydrogen fluoride gas at the planar solution–gas interface at room temperature are considered. Compounds with different crystal structures: PbF2 (space groups Pnma and Fmm), ScF3 (sp. gr. Pmm and P6/mmm), and LaF3 (space group 1) were chosen as objects of study. The factors having a significant influence on the morphology, size, and ordering of the grown crystals have been identified. An opportunity to prepare 1D and 2D crystals has been shown for some compounds. Probable applications fields of nanomaterials based on the prepared compounds are analyzed. The conclusion is made about a potential of the interface technique for use in the design of new solid electrolytes, optically active materials, and functional coatings.

AB - Abstract: The formation and growth specifics of metal fluoride MF2 (where M = Ca, Sr, or Pb) and MF3 (where M = Sc, La, or Ln) crystals by reacting components of aqueous metal salt solutions with hydrogen fluoride gas at the planar solution–gas interface at room temperature are considered. Compounds with different crystal structures: PbF2 (space groups Pnma and Fmm), ScF3 (sp. gr. Pmm and P6/mmm), and LaF3 (space group 1) were chosen as objects of study. The factors having a significant influence on the morphology, size, and ordering of the grown crystals have been identified. An opportunity to prepare 1D and 2D crystals has been shown for some compounds. Probable applications fields of nanomaterials based on the prepared compounds are analyzed. The conclusion is made about a potential of the interface technique for use in the design of new solid electrolytes, optically active materials, and functional coatings.

KW - ionic conductors

KW - nanocrystals

KW - solution–gas interface

UR - https://www.mendeley.com/catalogue/14af00a9-031a-3b0a-80f5-322485d66ba7/

U2 - 10.1134/s0036023623603070

DO - 10.1134/s0036023623603070

M3 - статья

VL - 69

SP - 6

EP - 19

JO - ЖУРНАЛ НЕОРГАНИЧЕСКОЙ ХИМИИ

JF - ЖУРНАЛ НЕОРГАНИЧЕСКОЙ ХИМИИ

SN - 0044-457X

IS - 3

ER -

ID: 114037387