Standard

X-ray emission spectroscopic data on the state of impurity Cu2+ ion in crystal lattices of nickel(II), magnesium(II), and zinc(II) oxides. / Makarov, L. L.; Batrakov, Yu F.; Myagkova-Romanova, M. A.; Tupitsyn, I. I.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 22, No. 11, 01.11.1996, p. 800-806.

Research output: Contribution to journal › Article › peer-review

Harvard

Makarov, LL, Batrakov, YF, Myagkova-Romanova, MA & Tupitsyn, II 1996, 'X-ray emission spectroscopic data on the state of impurity Cu2+ ion in crystal lattices of nickel(II), magnesium(II), and zinc(II) oxides', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 22, no. 11, pp. 800-806.

APA

Makarov, L. L., Batrakov, Y. F., Myagkova-Romanova, M. A., & Tupitsyn, I. I. (1996). X-ray emission spectroscopic data on the state of impurity Cu2+ ion in crystal lattices of nickel(II), magnesium(II), and zinc(II) oxides. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 22(11), 800-806.

Vancouver

Makarov LL, Batrakov YF, Myagkova-Romanova MA, Tupitsyn II. X-ray emission spectroscopic data on the state of impurity Cu2+ ion in crystal lattices of nickel(II), magnesium(II), and zinc(II) oxides. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 1996 Nov 1;22(11):800-806.

Author

Makarov, L. L. ; Batrakov, Yu F. ; Myagkova-Romanova, M. A. ; Tupitsyn, I. I. / X-ray emission spectroscopic data on the state of impurity Cu2+ ion in crystal lattices of nickel(II), magnesium(II), and zinc(II) oxides. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 1996 ; Vol. 22, No. 11. pp. 800-806.

BibTeX

@article{04df2a9310d84272b23c4b1f8a550378,
title = "X-ray emission spectroscopic data on the state of impurity Cu2+ ion in crystal lattices of nickel(II), magnesium(II), and zinc(II) oxides",
abstract = "The state of a typical Jahn-Teller Cu2+ (3d9) ion doped in the NiO, MgO, or ZnO crystal lattices having nearly perfect cubic symmetry is studied. The changes in the atomic electronic states that accompany formation of the solid solutions are revealed. The Ni1-xCuxO, Mg1-xCuxO, and Zn1-xCuxO solid solutions are synthesized and analyzed. The chemical shifts and widths of the CuKα2, CuKα1, and NiKα1 lines are obtained. The copper atom shows a well-defined x dependence. The distinctions between the Cu states in the Ni-, Mg(Zn)-containing systems are found to be due to the distinctions in the electronic structures of the cations of a {"}host{"} lattice component. The chemical effects are found to be rather complicated. A possible role is revealed and estimations are made for the ratio between the relaxation times of the inner- and outer-shell electrons of the emitting atom, for the spin-polarized X-ray transitions, and for the partial effective atomic charges. The correlation between the obtained data and magnetic properties of solid solutions is established.",
author = "Makarov, {L. L.} and Batrakov, {Yu F.} and Myagkova-Romanova, {M. A.} and Tupitsyn, {I. I.}",
year = "1996",
month = nov,
day = "1",
language = "English",
volume = "22",
pages = "800--806",
journal = "Russian Journal of Coordination Chemistry",
issn = "1070-3284",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "11",

}

RIS

TY - JOUR

T1 - X-ray emission spectroscopic data on the state of impurity Cu2+ ion in crystal lattices of nickel(II), magnesium(II), and zinc(II) oxides

AU - Makarov, L. L.

AU - Batrakov, Yu F.

AU - Myagkova-Romanova, M. A.

AU - Tupitsyn, I. I.

PY - 1996/11/1

Y1 - 1996/11/1

N2 - The state of a typical Jahn-Teller Cu2+ (3d9) ion doped in the NiO, MgO, or ZnO crystal lattices having nearly perfect cubic symmetry is studied. The changes in the atomic electronic states that accompany formation of the solid solutions are revealed. The Ni1-xCuxO, Mg1-xCuxO, and Zn1-xCuxO solid solutions are synthesized and analyzed. The chemical shifts and widths of the CuKα2, CuKα1, and NiKα1 lines are obtained. The copper atom shows a well-defined x dependence. The distinctions between the Cu states in the Ni-, Mg(Zn)-containing systems are found to be due to the distinctions in the electronic structures of the cations of a "host" lattice component. The chemical effects are found to be rather complicated. A possible role is revealed and estimations are made for the ratio between the relaxation times of the inner- and outer-shell electrons of the emitting atom, for the spin-polarized X-ray transitions, and for the partial effective atomic charges. The correlation between the obtained data and magnetic properties of solid solutions is established.

AB - The state of a typical Jahn-Teller Cu2+ (3d9) ion doped in the NiO, MgO, or ZnO crystal lattices having nearly perfect cubic symmetry is studied. The changes in the atomic electronic states that accompany formation of the solid solutions are revealed. The Ni1-xCuxO, Mg1-xCuxO, and Zn1-xCuxO solid solutions are synthesized and analyzed. The chemical shifts and widths of the CuKα2, CuKα1, and NiKα1 lines are obtained. The copper atom shows a well-defined x dependence. The distinctions between the Cu states in the Ni-, Mg(Zn)-containing systems are found to be due to the distinctions in the electronic structures of the cations of a "host" lattice component. The chemical effects are found to be rather complicated. A possible role is revealed and estimations are made for the ratio between the relaxation times of the inner- and outer-shell electrons of the emitting atom, for the spin-polarized X-ray transitions, and for the partial effective atomic charges. The correlation between the obtained data and magnetic properties of solid solutions is established.

UR - http://www.scopus.com/inward/record.url?scp=27644515252&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:27644515252

VL - 22

SP - 800

EP - 806

JO - Russian Journal of Coordination Chemistry

JF - Russian Journal of Coordination Chemistry

SN - 1070-3284

IS - 11

ER -

ID: 49960647