Research output: Contribution to journal › Article › peer-review
X-ray absorption evidence for the back-donation in iron cyanide complexes. / Vinogradov, A. S.; Preobrajenski, A. B.; Krasnikov, S. A.; Chassé, T.; Szargan, R.; Knop-Gericke, A.; Schlögl, R.; Bressler, P.
In: Surface Review and Letters, Vol. 9, No. 1, 01.02.2002, p. 359-364.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - X-ray absorption evidence for the back-donation in iron cyanide complexes
AU - Vinogradov, A. S.
AU - Preobrajenski, A. B.
AU - Krasnikov, S. A.
AU - Chassé, T.
AU - Szargan, R.
AU - Knop-Gericke, A.
AU - Schlögl, R.
AU - Bressler, P.
PY - 2002/2/1
Y1 - 2002/2/1
N2 - High-resolution, uniformly calibrated Fe 2p 3/2 absorption spectra of various Fe(II) and Fe(III) compounds with the metal atom octahedrally coordinated to atomic and molecular ligands are analyzed expecting changes in the absorption spectra due to differences in the formal valence state and in the character of the chemical bond. Particular attention is given to revealing spectral characteristics of the 3dπ-2π(π*) charge transfer (π-back-donation effect) between the iron atom and cyanide ligands.
AB - High-resolution, uniformly calibrated Fe 2p 3/2 absorption spectra of various Fe(II) and Fe(III) compounds with the metal atom octahedrally coordinated to atomic and molecular ligands are analyzed expecting changes in the absorption spectra due to differences in the formal valence state and in the character of the chemical bond. Particular attention is given to revealing spectral characteristics of the 3dπ-2π(π*) charge transfer (π-back-donation effect) between the iron atom and cyanide ligands.
UR - http://www.scopus.com/inward/record.url?scp=0036463132&partnerID=8YFLogxK
U2 - 10.1142/S0218625X02002270
DO - 10.1142/S0218625X02002270
M3 - Article
AN - SCOPUS:0036463132
VL - 9
SP - 359
EP - 364
JO - Surface Review and Letters
JF - Surface Review and Letters
SN - 0218-625X
IS - 1
ER -
ID: 127647095