Standard

When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family. / Volkov, Sergey N.; Charkin, Dmitri O.; Krzhizhanovskaya, Maria G.; Gorianskii, Alexandr M.; Banaru, Daria A.; Povolotskiy, Alexey V.; Gosteva, Alevtina N.; Stefanovich, Sergey Yu.; Arsent’ev, Maxim Yu.; Ugolkov, Valery L.; Savchenko, Yevgeny E.; Topalov, Eduard V.; Aksenov, Sergey M.

In: Inorganic Chemistry Communications, Vol. 169, 113059, 01.11.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Volkov, SN, Charkin, DO, Krzhizhanovskaya, MG, Gorianskii, AM, Banaru, DA, Povolotskiy, AV, Gosteva, AN, Stefanovich, SY, Arsent’ev, MY, Ugolkov, VL, Savchenko, YE, Topalov, EV & Aksenov, SM 2024, 'When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family', Inorganic Chemistry Communications, vol. 169, 113059. https://doi.org/10.1016/j.inoche.2024.113059

APA

Volkov, S. N., Charkin, D. O., Krzhizhanovskaya, M. G., Gorianskii, A. M., Banaru, D. A., Povolotskiy, A. V., Gosteva, A. N., Stefanovich, S. Y., Arsent’ev, M. Y., Ugolkov, V. L., Savchenko, Y. E., Topalov, E. V., & Aksenov, S. M. (2024). When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family. Inorganic Chemistry Communications, 169, [113059]. https://doi.org/10.1016/j.inoche.2024.113059

Vancouver

Volkov SN, Charkin DO, Krzhizhanovskaya MG, Gorianskii AM, Banaru DA, Povolotskiy AV et al. When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family. Inorganic Chemistry Communications. 2024 Nov 1;169. 113059. https://doi.org/10.1016/j.inoche.2024.113059

Author

Volkov, Sergey N. ; Charkin, Dmitri O. ; Krzhizhanovskaya, Maria G. ; Gorianskii, Alexandr M. ; Banaru, Daria A. ; Povolotskiy, Alexey V. ; Gosteva, Alevtina N. ; Stefanovich, Sergey Yu. ; Arsent’ev, Maxim Yu. ; Ugolkov, Valery L. ; Savchenko, Yevgeny E. ; Topalov, Eduard V. ; Aksenov, Sergey M. / When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family. In: Inorganic Chemistry Communications. 2024 ; Vol. 169.

BibTeX

@article{037b684135ef4988a2dc15822e16aab5,
title = "When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family",
abstract = "Extensive searches for new monovalent metal borates as promising nonlinear optical materials continuously provide new exciting results. Attempts to add the iodine end-member of the acentric Na3B4O7X family resulted in a compound with a complex twofold monoclinic superstructure, Na17B24O42I5. As for the lighter-halide analogies, its crystal structure is formed by a 12B:∞3[3(4:2Δ + 2T)] framework of B4O9 tetraborate groups, 4B:2Δ2□:=, yet the guest metal-halide sublattice is less dense and contains 5 NaI per 6 Na2B4O7 formula units, most likely due to the large size of the iodide ion. Upon heating in the presence of excess NaI, Na17B24O42I5 converts into a simple hexagonal Na3B4O7I structure, completely analogous to Na3B4O7Br, which exists above 444 °C.",
author = "Volkov, {Sergey N.} and Charkin, {Dmitri O.} and Krzhizhanovskaya, {Maria G.} and Gorianskii, {Alexandr M.} and Banaru, {Daria A.} and Povolotskiy, {Alexey V.} and Gosteva, {Alevtina N.} and Stefanovich, {Sergey Yu.} and Arsent{\textquoteright}ev, {Maxim Yu.} and Ugolkov, {Valery L.} and Savchenko, {Yevgeny E.} and Topalov, {Eduard V.} and Aksenov, {Sergey M.}",
year = "2024",
month = nov,
day = "1",
doi = "10.1016/j.inoche.2024.113059",
language = "English",
volume = "169",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family

AU - Volkov, Sergey N.

AU - Charkin, Dmitri O.

AU - Krzhizhanovskaya, Maria G.

AU - Gorianskii, Alexandr M.

AU - Banaru, Daria A.

AU - Povolotskiy, Alexey V.

AU - Gosteva, Alevtina N.

AU - Stefanovich, Sergey Yu.

AU - Arsent’ev, Maxim Yu.

AU - Ugolkov, Valery L.

AU - Savchenko, Yevgeny E.

AU - Topalov, Eduard V.

AU - Aksenov, Sergey M.

PY - 2024/11/1

Y1 - 2024/11/1

N2 - Extensive searches for new monovalent metal borates as promising nonlinear optical materials continuously provide new exciting results. Attempts to add the iodine end-member of the acentric Na3B4O7X family resulted in a compound with a complex twofold monoclinic superstructure, Na17B24O42I5. As for the lighter-halide analogies, its crystal structure is formed by a 12B:∞3[3(4:2Δ + 2T)] framework of B4O9 tetraborate groups, 4B:2Δ2□:=, yet the guest metal-halide sublattice is less dense and contains 5 NaI per 6 Na2B4O7 formula units, most likely due to the large size of the iodide ion. Upon heating in the presence of excess NaI, Na17B24O42I5 converts into a simple hexagonal Na3B4O7I structure, completely analogous to Na3B4O7Br, which exists above 444 °C.

AB - Extensive searches for new monovalent metal borates as promising nonlinear optical materials continuously provide new exciting results. Attempts to add the iodine end-member of the acentric Na3B4O7X family resulted in a compound with a complex twofold monoclinic superstructure, Na17B24O42I5. As for the lighter-halide analogies, its crystal structure is formed by a 12B:∞3[3(4:2Δ + 2T)] framework of B4O9 tetraborate groups, 4B:2Δ2□:=, yet the guest metal-halide sublattice is less dense and contains 5 NaI per 6 Na2B4O7 formula units, most likely due to the large size of the iodide ion. Upon heating in the presence of excess NaI, Na17B24O42I5 converts into a simple hexagonal Na3B4O7I structure, completely analogous to Na3B4O7Br, which exists above 444 °C.

UR - https://www.mendeley.com/catalogue/c53c2bb7-6719-3efe-9900-9fe80092569e/

U2 - 10.1016/j.inoche.2024.113059

DO - 10.1016/j.inoche.2024.113059

M3 - Article

VL - 169

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

M1 - 113059

ER -

ID: 125108873