Voltammetric study of PrF3:Sr2+ and NdF3:Ba2+ solid electrolytes

Standard

Voltammetric study of PrF₃:Sr²⁺ and NdF₃:Ba²⁺ solid electrolytes. / Turaeva, M. S.; Tarasenkova, I. V.; Sorokin, N. I.; Urchukova, M. M.; Murin, I. V.

In: Russian Journal of Electrochemistry, Vol. 51, No. 5, 01.05.2015, p. 429-434.

Research output: Contribution to journal › Article › peer-review

Author

Turaeva, M. S. ; Tarasenkova, I. V. ; Sorokin, N. I. ; Urchukova, M. M. ; Murin, I. V. / Voltammetric study of PrF₃:Sr²⁺ and NdF₃:Ba²⁺ solid electrolytes. In: Russian Journal of Electrochemistry. 2015 ; Vol. 51, No. 5. pp. 429-434.

BibTeX

@article{cb3a49f34da8409f9099873546e32785,

title = "Voltammetric study of PrF3:Sr2+ and NdF3:Ba2+ solid electrolytes",

abstract = "Studies of single crystals of nonstoichiometric fluorides of PrF3:Sr2+ and NdF3:Ba2+ in contact with a Pt electrode were carried out using the method of voltammetry with a linear potential sweep, chronoamperometry, and cyclic voltammetry. The reaction of gaseous oxygen reduction (GOR) at the PrF3:Sr2+/Pt interface was accompanied by appearance of mobile oxygen forms. The catalytic activity of PrF3:Sr2+ with respect to gaseous oxygen, same as CeF3:Sr2+, can be explained by variable valency of praseodymium and cerium fluoride, which creates opportunities for using them in oxygen and oxygen-containing gas sensors. The GOR reaction at the NdF3:Ba2+/Pt interface appeared as a result of anodic polarization. After charging at E = 3.2 V, the NdF3:Ba2+ single crystal was successfully used for fluorination of Sb and Ag. NdF3:Ba2+ is most promising in devices based on reactions with participation of mobile fluoride ion in solid electrolytes, particularly, for generation of gaseous fluorine.",

keywords = "generation of gaseous fluorine, nonstoichiometric praseodymium and neodymium fluorides, oxygen reduction, solid electrolytes, voltammetry",

author = "Turaeva, {M. S.} and Tarasenkova, {I. V.} and Sorokin, {N. I.} and Urchukova, {M. M.} and Murin, {I. V.}",

note = "Publisher Copyright: {\textcopyright} 2015, Pleiades Publishing, Ltd.",

year = "2015",

month = may,

day = "1",

doi = "10.1134/S1023193515050158",

language = "English",

volume = "51",

pages = "429--434",

journal = "Russian Journal of Electrochemistry",

issn = "1023-1935",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "5",

}

RIS

TY - JOUR

T1 - Voltammetric study of PrF3:Sr2+ and NdF3:Ba2+ solid electrolytes

AU - Turaeva, M. S.

AU - Tarasenkova, I. V.

AU - Sorokin, N. I.

AU - Urchukova, M. M.

AU - Murin, I. V.

PY - 2015/5/1

Y1 - 2015/5/1

N2 - Studies of single crystals of nonstoichiometric fluorides of PrF3:Sr2+ and NdF3:Ba2+ in contact with a Pt electrode were carried out using the method of voltammetry with a linear potential sweep, chronoamperometry, and cyclic voltammetry. The reaction of gaseous oxygen reduction (GOR) at the PrF3:Sr2+/Pt interface was accompanied by appearance of mobile oxygen forms. The catalytic activity of PrF3:Sr2+ with respect to gaseous oxygen, same as CeF3:Sr2+, can be explained by variable valency of praseodymium and cerium fluoride, which creates opportunities for using them in oxygen and oxygen-containing gas sensors. The GOR reaction at the NdF3:Ba2+/Pt interface appeared as a result of anodic polarization. After charging at E = 3.2 V, the NdF3:Ba2+ single crystal was successfully used for fluorination of Sb and Ag. NdF3:Ba2+ is most promising in devices based on reactions with participation of mobile fluoride ion in solid electrolytes, particularly, for generation of gaseous fluorine.

AB - Studies of single crystals of nonstoichiometric fluorides of PrF3:Sr2+ and NdF3:Ba2+ in contact with a Pt electrode were carried out using the method of voltammetry with a linear potential sweep, chronoamperometry, and cyclic voltammetry. The reaction of gaseous oxygen reduction (GOR) at the PrF3:Sr2+/Pt interface was accompanied by appearance of mobile oxygen forms. The catalytic activity of PrF3:Sr2+ with respect to gaseous oxygen, same as CeF3:Sr2+, can be explained by variable valency of praseodymium and cerium fluoride, which creates opportunities for using them in oxygen and oxygen-containing gas sensors. The GOR reaction at the NdF3:Ba2+/Pt interface appeared as a result of anodic polarization. After charging at E = 3.2 V, the NdF3:Ba2+ single crystal was successfully used for fluorination of Sb and Ag. NdF3:Ba2+ is most promising in devices based on reactions with participation of mobile fluoride ion in solid electrolytes, particularly, for generation of gaseous fluorine.

KW - generation of gaseous fluorine

KW - nonstoichiometric praseodymium and neodymium fluorides

KW - oxygen reduction

KW - solid electrolytes

KW - voltammetry

UR - http://www.scopus.com/inward/record.url?scp=84930196334&partnerID=8YFLogxK

U2 - 10.1134/S1023193515050158

DO - 10.1134/S1023193515050158

M3 - Article

VL - 51

SP - 429

EP - 434

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 5

ER -

ID: 3936168