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Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials. / Родыгин, Константин Сергеевич; Богаченков, Александр Сергеевич; Анаников, Валентин Павлович.

In: Molecules, Vol. 23, No. 3, 648, 2018.

Research output: Contribution to journal › Article › peer-review

Harvard

Родыгин, КС, Богаченков, АС & Анаников, ВП 2018, 'Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials', Molecules, vol. 23, no. 3, 648. https://doi.org/10.3390/molecules23030648

APA

Родыгин, К. С., Богаченков, А. С., & Анаников, В. П. (2018). Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials. Molecules, 23(3), [648]. https://doi.org/10.3390/molecules23030648

Vancouver

Родыгин КС, Богаченков АС, Анаников ВП. Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials. Molecules. 2018;23(3). 648. https://doi.org/10.3390/molecules23030648

Author

Родыгин, Константин Сергеевич ; Богаченков, Александр Сергеевич ; Анаников, Валентин Павлович. / Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials. In: Molecules. 2018 ; Vol. 23, No. 3.

BibTeX

@article{55afa8be922c46a5bbaa04b761bb28e6,
title = "Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials",
abstract = "We developed a simple and efficient strategy to access N-vinyl secondary amines of various naturally occurring materials using readily available solid acetylene reagents (calcium carbide, KF, and KOH). Pyrrole, pyrazole, indoles, carbazoles, and diarylamines were successfully vinylated in good yields. Cross-linked and linear polymers were synthesized from N-vinyl carbazoles through free radical and cationic polymerization. Post-modification of olanzapine (an antipsychotic drug substance) was successfully performed.",
keywords = "Acetylene, Calcium carbide, Functionalization, Olanzapine, Vinylation",
author = "Родыгин, {Константин Сергеевич} and Богаченков, {Александр Сергеевич} and Анаников, {Валентин Павлович}",
note = "Funding Information: Acknowledgments: We acknowledge the generous support of Russian Science Foundation (RSF), No. 16-13-10301. This research used resources of the {\textquoteleft}Magnetic Resonance Research Centre{\textquoteright}, {\textquoteleft}Chemical Analysis and Materials Research Centre{\textquoteright}, and {\textquoteleft}Centre for X-ray Diffraction Studies{\textquoteright} of Research Park of Saint Petersburg State University.",
year = "2018",
doi = "10.3390/molecules23030648",
language = "English",
volume = "23",
journal = "Molecules",
issn = "1420-3049",
publisher = "MDPI AG",
number = "3",

}

RIS

TY - JOUR

T1 - Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials

AU - Родыгин, Константин Сергеевич

AU - Богаченков, Александр Сергеевич

AU - Анаников, Валентин Павлович

N1 - Funding Information: Acknowledgments: We acknowledge the generous support of Russian Science Foundation (RSF), No. 16-13-10301. This research used resources of the ‘Magnetic Resonance Research Centre’, ‘Chemical Analysis and Materials Research Centre’, and ‘Centre for X-ray Diffraction Studies’ of Research Park of Saint Petersburg State University.

PY - 2018

Y1 - 2018

N2 - We developed a simple and efficient strategy to access N-vinyl secondary amines of various naturally occurring materials using readily available solid acetylene reagents (calcium carbide, KF, and KOH). Pyrrole, pyrazole, indoles, carbazoles, and diarylamines were successfully vinylated in good yields. Cross-linked and linear polymers were synthesized from N-vinyl carbazoles through free radical and cationic polymerization. Post-modification of olanzapine (an antipsychotic drug substance) was successfully performed.

AB - We developed a simple and efficient strategy to access N-vinyl secondary amines of various naturally occurring materials using readily available solid acetylene reagents (calcium carbide, KF, and KOH). Pyrrole, pyrazole, indoles, carbazoles, and diarylamines were successfully vinylated in good yields. Cross-linked and linear polymers were synthesized from N-vinyl carbazoles through free radical and cationic polymerization. Post-modification of olanzapine (an antipsychotic drug substance) was successfully performed.

KW - Acetylene

KW - Calcium carbide

KW - Functionalization

KW - Olanzapine

KW - Vinylation

UR - http://www.scopus.com/inward/record.url?scp=85044343208&partnerID=8YFLogxK

U2 - 10.3390/molecules23030648

DO - 10.3390/molecules23030648

M3 - Article

VL - 23

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 3

M1 - 648

ER -

ID: 34659432