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@article{1e289285df0d47dcb3fabc74079c87e5,
title = "Vapor-Liquid Equilibrium in the Acetic Acid-Ethanol-Ethyl Acetate-Water Quaternary System: Critical Literature Review and Thermodynamic Consistency of the Experimental Data",
abstract = "This study presents a critical review of the experimental vapor-liquid equilibrium (VLE) data for the quaternary acetic acid-ethanol-ethyl acetate-water system and its subsystems that are reported in the literature. The thermodynamic consistency of the VLE data were verified using two integral tests: the Redlich–Kister test and the direct integration of the Gibbs–Duhem equation. The VLE data were correlated using the NRTL equation for further integration. Additionally, the reliable value of the integral derived from the direct integration of the Gibbs–Duhem equation for multicomponent systems under isothermal-isobaric conditions was estimated. This integral can be used for testing the thermodynamic consistency of experimental VLE data.",
author = "Georgii Misikov and Maya Trofimova and Igor Prikhodko",
year = "2023",
month = nov,
day = "13",
doi = "10.3390/chemistry5040165",
language = "English",
volume = "5",
pages = "2542--2565",
journal = "Chemistry (Switzerland)",
issn = "2624-8549",
publisher = "MDPI AG",
number = "4",

}

RIS

TY - JOUR

T1 - Vapor-Liquid Equilibrium in the Acetic Acid-Ethanol-Ethyl Acetate-Water Quaternary System: Critical Literature Review and Thermodynamic Consistency of the Experimental Data

AU - Misikov, Georgii

AU - Trofimova, Maya

AU - Prikhodko, Igor

PY - 2023/11/13

Y1 - 2023/11/13

N2 - This study presents a critical review of the experimental vapor-liquid equilibrium (VLE) data for the quaternary acetic acid-ethanol-ethyl acetate-water system and its subsystems that are reported in the literature. The thermodynamic consistency of the VLE data were verified using two integral tests: the Redlich–Kister test and the direct integration of the Gibbs–Duhem equation. The VLE data were correlated using the NRTL equation for further integration. Additionally, the reliable value of the integral derived from the direct integration of the Gibbs–Duhem equation for multicomponent systems under isothermal-isobaric conditions was estimated. This integral can be used for testing the thermodynamic consistency of experimental VLE data.

AB - This study presents a critical review of the experimental vapor-liquid equilibrium (VLE) data for the quaternary acetic acid-ethanol-ethyl acetate-water system and its subsystems that are reported in the literature. The thermodynamic consistency of the VLE data were verified using two integral tests: the Redlich–Kister test and the direct integration of the Gibbs–Duhem equation. The VLE data were correlated using the NRTL equation for further integration. Additionally, the reliable value of the integral derived from the direct integration of the Gibbs–Duhem equation for multicomponent systems under isothermal-isobaric conditions was estimated. This integral can be used for testing the thermodynamic consistency of experimental VLE data.

UR - https://www.mendeley.com/catalogue/369946b2-bd84-3048-a379-9c618a3c8702/

U2 - 10.3390/chemistry5040165

DO - 10.3390/chemistry5040165

M3 - Article

VL - 5

SP - 2542

EP - 2565

JO - Chemistry (Switzerland)

JF - Chemistry (Switzerland)

SN - 2624-8549

IS - 4

ER -

ID: 114005742