Research output: Contribution to journal › Article › peer-review
Vapor-Liquid Equilibrium in the Acetic Acid-Ethanol-Ethyl Acetate-Water Quaternary System: Critical Literature Review and Thermodynamic Consistency of the Experimental Data. / Misikov, Georgii; Trofimova, Maya; Prikhodko, Igor.
In: Chemistry, Vol. 5, No. 4, 13.11.2023, p. 2542-2565.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Vapor-Liquid Equilibrium in the Acetic Acid-Ethanol-Ethyl Acetate-Water Quaternary System: Critical Literature Review and Thermodynamic Consistency of the Experimental Data
AU - Misikov, Georgii
AU - Trofimova, Maya
AU - Prikhodko, Igor
PY - 2023/11/13
Y1 - 2023/11/13
N2 - This study presents a critical review of the experimental vapor-liquid equilibrium (VLE) data for the quaternary acetic acid-ethanol-ethyl acetate-water system and its subsystems that are reported in the literature. The thermodynamic consistency of the VLE data were verified using two integral tests: the Redlich–Kister test and the direct integration of the Gibbs–Duhem equation. The VLE data were correlated using the NRTL equation for further integration. Additionally, the reliable value of the integral derived from the direct integration of the Gibbs–Duhem equation for multicomponent systems under isothermal-isobaric conditions was estimated. This integral can be used for testing the thermodynamic consistency of experimental VLE data.
AB - This study presents a critical review of the experimental vapor-liquid equilibrium (VLE) data for the quaternary acetic acid-ethanol-ethyl acetate-water system and its subsystems that are reported in the literature. The thermodynamic consistency of the VLE data were verified using two integral tests: the Redlich–Kister test and the direct integration of the Gibbs–Duhem equation. The VLE data were correlated using the NRTL equation for further integration. Additionally, the reliable value of the integral derived from the direct integration of the Gibbs–Duhem equation for multicomponent systems under isothermal-isobaric conditions was estimated. This integral can be used for testing the thermodynamic consistency of experimental VLE data.
UR - https://www.mendeley.com/catalogue/369946b2-bd84-3048-a379-9c618a3c8702/
U2 - 10.3390/chemistry5040165
DO - 10.3390/chemistry5040165
M3 - Article
VL - 5
SP - 2542
EP - 2565
JO - Chemistry (Switzerland)
JF - Chemistry (Switzerland)
SN - 0861-9255
IS - 4
ER -
ID: 114005742