Standard

Vapor pressures and thermodynamic properties of simple and complex iodides. / Shugurov, S. M.; Panin, A. I.; Lopatin, S. I.; Panaeva, M. A.

In: Thermochimica Acta, Vol. 703, 178996, 01.09.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Shugurov, SM, Panin, AI, Lopatin, SI & Panaeva, MA 2021, 'Vapor pressures and thermodynamic properties of simple and complex iodides', Thermochimica Acta, vol. 703, 178996. https://doi.org/10.1016/j.tca.2021.178996

APA

Shugurov, S. M., Panin, A. I., Lopatin, S. I., & Panaeva, M. A. (2021). Vapor pressures and thermodynamic properties of simple and complex iodides. Thermochimica Acta, 703, [178996]. https://doi.org/10.1016/j.tca.2021.178996

Vancouver

Shugurov SM, Panin AI, Lopatin SI, Panaeva MA. Vapor pressures and thermodynamic properties of simple and complex iodides. Thermochimica Acta. 2021 Sep 1;703. 178996. https://doi.org/10.1016/j.tca.2021.178996

Author

Shugurov, S. M. ; Panin, A. I. ; Lopatin, S. I. ; Panaeva, M. A. / Vapor pressures and thermodynamic properties of simple and complex iodides. In: Thermochimica Acta. 2021 ; Vol. 703.

BibTeX

@article{6709b4afea104095af9f9c0df3238ba7,
title = "Vapor pressures and thermodynamic properties of simple and complex iodides",
abstract = "The vapor composition above KI, FeI2, CdI2, KI-FeI2-Ag and KI-CdI2-Ag systems were studied by the Knudsen effusion mass spectrometry. Temperature dependences of partial pressures of gaseous species above pure iodides were determined. Equilibrium constants and reaction enthalpies of compounds with the participation of formed complex iodides were obtained. Structures, molecular parameters and thermodynamic functions of gaseous KCdI3, KFeI3 and KAgI2 were calculated by quantum chemistry methods. The obtained values of formation enthalpies (ΔfH0 (298.15) for gaseous complex iodides KCdI3, KFeI3 and KAgI2 are equal to −320.0±7.3 −218.0±6.6 and −174.5±12.0 kJ/mol, respectively.",
keywords = "Complex gaseous iodides, Equilibrium constants, Formation enthalpies, Knudsen effusion mass spectrometry, Vapor pressure, THERMOCHEMISTRY, GASEOUS SALTS, SUBLIMATION, ENTROPIES, MOLECULAR ASSOCIATION, OXYGEN-CONTAINING ACIDS, EQUILIBRIUM, VAPORIZATION, SPECTRA, ALKALI-HALIDE",
author = "Shugurov, {S. M.} and Panin, {A. I.} and Lopatin, {S. I.} and Panaeva, {M. A.}",
note = "Publisher Copyright: {\textcopyright} 2021",
year = "2021",
month = sep,
day = "1",
doi = "10.1016/j.tca.2021.178996",
language = "English",
volume = "703",
journal = "Thermochimica Acta",
issn = "0040-6031",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Vapor pressures and thermodynamic properties of simple and complex iodides

AU - Shugurov, S. M.

AU - Panin, A. I.

AU - Lopatin, S. I.

AU - Panaeva, M. A.

N1 - Publisher Copyright: © 2021

PY - 2021/9/1

Y1 - 2021/9/1

N2 - The vapor composition above KI, FeI2, CdI2, KI-FeI2-Ag and KI-CdI2-Ag systems were studied by the Knudsen effusion mass spectrometry. Temperature dependences of partial pressures of gaseous species above pure iodides were determined. Equilibrium constants and reaction enthalpies of compounds with the participation of formed complex iodides were obtained. Structures, molecular parameters and thermodynamic functions of gaseous KCdI3, KFeI3 and KAgI2 were calculated by quantum chemistry methods. The obtained values of formation enthalpies (ΔfH0 (298.15) for gaseous complex iodides KCdI3, KFeI3 and KAgI2 are equal to −320.0±7.3 −218.0±6.6 and −174.5±12.0 kJ/mol, respectively.

AB - The vapor composition above KI, FeI2, CdI2, KI-FeI2-Ag and KI-CdI2-Ag systems were studied by the Knudsen effusion mass spectrometry. Temperature dependences of partial pressures of gaseous species above pure iodides were determined. Equilibrium constants and reaction enthalpies of compounds with the participation of formed complex iodides were obtained. Structures, molecular parameters and thermodynamic functions of gaseous KCdI3, KFeI3 and KAgI2 were calculated by quantum chemistry methods. The obtained values of formation enthalpies (ΔfH0 (298.15) for gaseous complex iodides KCdI3, KFeI3 and KAgI2 are equal to −320.0±7.3 −218.0±6.6 and −174.5±12.0 kJ/mol, respectively.

KW - Complex gaseous iodides

KW - Equilibrium constants

KW - Formation enthalpies

KW - Knudsen effusion mass spectrometry

KW - Vapor pressure

KW - THERMOCHEMISTRY

KW - GASEOUS SALTS

KW - SUBLIMATION

KW - ENTROPIES

KW - MOLECULAR ASSOCIATION

KW - OXYGEN-CONTAINING ACIDS

KW - EQUILIBRIUM

KW - VAPORIZATION

KW - SPECTRA

KW - ALKALI-HALIDE

UR - http://www.scopus.com/inward/record.url?scp=85110761394&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/2565394f-a7b8-3705-a9a4-e118149e27e4/

U2 - 10.1016/j.tca.2021.178996

DO - 10.1016/j.tca.2021.178996

M3 - Article

AN - SCOPUS:85110761394

VL - 703

JO - Thermochimica Acta

JF - Thermochimica Acta

SN - 0040-6031

M1 - 178996

ER -

ID: 85284248