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Utilization of the concept of quasi solutions in the thermodynamics of polymer homologues. / Golubev, V. M.; Rusanov, A. I.

In: Polymer Science U.S.S.R., Vol. 28, No. 7, 1986, p. 1734-1737.

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@article{400b2d80485e4f528020c228b52c8579,
title = "Utilization of the concept of quasi solutions in the thermodynamics of polymer homologues",
abstract = "It is proposed that an infinite sequence of linear polymer homologues be described as an open thermodynamic system whose equilibrium state is characterized by an additional parameter, i.e. by the length of macromolecules. This idea has led to the derivation of basic equations for the energy of a system: the repeat-units of chain molecules and the endgroups figure as independent components, like other substances present in the system. An analysis of the phase equilibria led to the derivation of an analogue of the known generalized differential van der Waals equation.",
author = "Golubev, {V. M.} and Rusanov, {A. I.}",
year = "1986",
doi = "10.1016/0032-3950(86)90351-5",
language = "English",
volume = "28",
pages = "1734--1737",
journal = "Polymer science USSR",
issn = "0032-3950",
publisher = "Pergamon Press",
number = "7",

}

RIS

TY - JOUR

T1 - Utilization of the concept of quasi solutions in the thermodynamics of polymer homologues

AU - Golubev, V. M.

AU - Rusanov, A. I.

PY - 1986

Y1 - 1986

N2 - It is proposed that an infinite sequence of linear polymer homologues be described as an open thermodynamic system whose equilibrium state is characterized by an additional parameter, i.e. by the length of macromolecules. This idea has led to the derivation of basic equations for the energy of a system: the repeat-units of chain molecules and the endgroups figure as independent components, like other substances present in the system. An analysis of the phase equilibria led to the derivation of an analogue of the known generalized differential van der Waals equation.

AB - It is proposed that an infinite sequence of linear polymer homologues be described as an open thermodynamic system whose equilibrium state is characterized by an additional parameter, i.e. by the length of macromolecules. This idea has led to the derivation of basic equations for the energy of a system: the repeat-units of chain molecules and the endgroups figure as independent components, like other substances present in the system. An analysis of the phase equilibria led to the derivation of an analogue of the known generalized differential van der Waals equation.

UR - http://www.scopus.com/inward/record.url?scp=46149135218&partnerID=8YFLogxK

U2 - 10.1016/0032-3950(86)90351-5

DO - 10.1016/0032-3950(86)90351-5

M3 - Article

AN - SCOPUS:46149135218

VL - 28

SP - 1734

EP - 1737

JO - Polymer science USSR

JF - Polymer science USSR

SN - 0032-3950

IS - 7

ER -

ID: 95725841