Research output: Contribution to journal › Article › peer-review
Utilization of the concept of quasi solutions in the thermodynamics of polymer homologues. / Golubev, V. M.; Rusanov, A. I.
In: Polymer Science U.S.S.R., Vol. 28, No. 7, 1986, p. 1734-1737.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Utilization of the concept of quasi solutions in the thermodynamics of polymer homologues
AU - Golubev, V. M.
AU - Rusanov, A. I.
PY - 1986
Y1 - 1986
N2 - It is proposed that an infinite sequence of linear polymer homologues be described as an open thermodynamic system whose equilibrium state is characterized by an additional parameter, i.e. by the length of macromolecules. This idea has led to the derivation of basic equations for the energy of a system: the repeat-units of chain molecules and the endgroups figure as independent components, like other substances present in the system. An analysis of the phase equilibria led to the derivation of an analogue of the known generalized differential van der Waals equation.
AB - It is proposed that an infinite sequence of linear polymer homologues be described as an open thermodynamic system whose equilibrium state is characterized by an additional parameter, i.e. by the length of macromolecules. This idea has led to the derivation of basic equations for the energy of a system: the repeat-units of chain molecules and the endgroups figure as independent components, like other substances present in the system. An analysis of the phase equilibria led to the derivation of an analogue of the known generalized differential van der Waals equation.
UR - http://www.scopus.com/inward/record.url?scp=46149135218&partnerID=8YFLogxK
U2 - 10.1016/0032-3950(86)90351-5
DO - 10.1016/0032-3950(86)90351-5
M3 - Article
AN - SCOPUS:46149135218
VL - 28
SP - 1734
EP - 1737
JO - Polymer science USSR
JF - Polymer science USSR
SN - 0032-3950
IS - 7
ER -
ID: 95725841