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Using the rotating disk electrode for evaluating film porosity of conductive polymers. / Levin, O. V.; Kondratiev, V. V.; Malev, V. V.

In: Russian Journal of Electrochemistry, Vol. 44, No. 1, 01.01.2008, p. 98-103.

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@article{11d7a5b8923648d9bdf71200c48ddd54,
title = "Using the rotating disk electrode for evaluating film porosity of conductive polymers",
abstract = "Conductive polymer (poly-o-phenylenediamine and poly-3-methylthiophene) films were synthesized on a rotating disk electrode. Dependences of the limiting penetration currents on the nature of the polymer and film thickness were obtained in solutions containing electroactive substances (hydroquinone, quinone) reducing or oxidiring at redox potentials beyond the range of polymer electroactivity (selected by adjusting the pH value). The transport of hydroquinone and quinone test species through the pores in polymer films was examined based on the results of these studies, and the degree of film porosity was evaluated.",
keywords = "Degree of porosity, Poly-3-methylthiophene, Poly-o-phenylenediamine, Rotating disk electrode",
author = "Levin, {O. V.} and Kondratiev, {V. V.} and Malev, {V. V.}",
year = "2008",
month = jan,
day = "1",
doi = "10.1007/s11175-008-1014-9",
language = "English",
volume = "44",
pages = "98--103",
journal = "Russian Journal of Electrochemistry",
issn = "1023-1935",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "1",

}

RIS

TY - JOUR

T1 - Using the rotating disk electrode for evaluating film porosity of conductive polymers

AU - Levin, O. V.

AU - Kondratiev, V. V.

AU - Malev, V. V.

PY - 2008/1/1

Y1 - 2008/1/1

N2 - Conductive polymer (poly-o-phenylenediamine and poly-3-methylthiophene) films were synthesized on a rotating disk electrode. Dependences of the limiting penetration currents on the nature of the polymer and film thickness were obtained in solutions containing electroactive substances (hydroquinone, quinone) reducing or oxidiring at redox potentials beyond the range of polymer electroactivity (selected by adjusting the pH value). The transport of hydroquinone and quinone test species through the pores in polymer films was examined based on the results of these studies, and the degree of film porosity was evaluated.

AB - Conductive polymer (poly-o-phenylenediamine and poly-3-methylthiophene) films were synthesized on a rotating disk electrode. Dependences of the limiting penetration currents on the nature of the polymer and film thickness were obtained in solutions containing electroactive substances (hydroquinone, quinone) reducing or oxidiring at redox potentials beyond the range of polymer electroactivity (selected by adjusting the pH value). The transport of hydroquinone and quinone test species through the pores in polymer films was examined based on the results of these studies, and the degree of film porosity was evaluated.

KW - Degree of porosity

KW - Poly-3-methylthiophene

KW - Poly-o-phenylenediamine

KW - Rotating disk electrode

UR - http://www.scopus.com/inward/record.url?scp=42349116733&partnerID=8YFLogxK

U2 - 10.1007/s11175-008-1014-9

DO - 10.1007/s11175-008-1014-9

M3 - Article

AN - SCOPUS:42349116733

VL - 44

SP - 98

EP - 103

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 1

ER -

ID: 36236248