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Uranyl sulfate nanotubules templated by N-phenylglycine. / Назарчук, Евгений Васильевич; Сийдра, Олег Иоханнесович; Бочаров, Сергей Николаевич.

In: Nanomaterials, Vol. 8, No. 4, 216, 04.2018.

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@article{12e91c8eddb84296bdc04e1eaf7cf27d,
title = "Uranyl sulfate nanotubules templated by N-phenylglycine",
abstract = "The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH +) 7[(UO 2) 6(SO 4) 10](H 2O) 3.5 (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO 2) 6(SO 4) 10] 8- nanotubules templated by protonated N-phenylglycine (C 6H 5NH 2CH 2COOH) +. Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO 4 tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π-π interaction with their side chains extending into the gaps between the nanotubules. ",
keywords = "Actinide materials, Microporous compounds, Nanostructured materials, Nanotubes, Organically templated compounds, Sulfates, Uranium",
author = "Назарчук, {Евгений Васильевич} and Сийдра, {Олег Иоханнесович} and Бочаров, {Сергей Николаевич}",
year = "2018",
month = apr,
doi = "10.3390/nano8040216",
language = "English",
volume = "8",
journal = "Nanomaterials",
issn = "2079-4991",
publisher = "MDPI AG",
number = "4",

}

RIS

TY - JOUR

T1 - Uranyl sulfate nanotubules templated by N-phenylglycine

AU - Назарчук, Евгений Васильевич

AU - Сийдра, Олег Иоханнесович

AU - Бочаров, Сергей Николаевич

PY - 2018/4

Y1 - 2018/4

N2 - The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH +) 7[(UO 2) 6(SO 4) 10](H 2O) 3.5 (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO 2) 6(SO 4) 10] 8- nanotubules templated by protonated N-phenylglycine (C 6H 5NH 2CH 2COOH) +. Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO 4 tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π-π interaction with their side chains extending into the gaps between the nanotubules.

AB - The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH +) 7[(UO 2) 6(SO 4) 10](H 2O) 3.5 (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO 2) 6(SO 4) 10] 8- nanotubules templated by protonated N-phenylglycine (C 6H 5NH 2CH 2COOH) +. Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO 4 tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π-π interaction with their side chains extending into the gaps between the nanotubules.

KW - Actinide materials

KW - Microporous compounds

KW - Nanostructured materials

KW - Nanotubes

KW - Organically templated compounds

KW - Sulfates

KW - Uranium

UR - http://www.scopus.com/inward/record.url?scp=85044998464&partnerID=8YFLogxK

U2 - 10.3390/nano8040216

DO - 10.3390/nano8040216

M3 - Article

VL - 8

JO - Nanomaterials

JF - Nanomaterials

SN - 2079-4991

IS - 4

M1 - 216

ER -

ID: 33333550