Research output: Contribution to journal › Article › peer-review
Uranyl sulfate nanotubules templated by N-phenylglycine. / Назарчук, Евгений Васильевич; Сийдра, Олег Иоханнесович; Бочаров, Сергей Николаевич.
In: Nanomaterials, Vol. 8, No. 4, 216, 04.2018.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Uranyl sulfate nanotubules templated by N-phenylglycine
AU - Назарчук, Евгений Васильевич
AU - Сийдра, Олег Иоханнесович
AU - Бочаров, Сергей Николаевич
PY - 2018/4
Y1 - 2018/4
N2 - The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH +) 7[(UO 2) 6(SO 4) 10](H 2O) 3.5 (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO 2) 6(SO 4) 10] 8- nanotubules templated by protonated N-phenylglycine (C 6H 5NH 2CH 2COOH) +. Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO 4 tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π-π interaction with their side chains extending into the gaps between the nanotubules.
AB - The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH +) 7[(UO 2) 6(SO 4) 10](H 2O) 3.5 (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO 2) 6(SO 4) 10] 8- nanotubules templated by protonated N-phenylglycine (C 6H 5NH 2CH 2COOH) +. Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO 4 tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π-π interaction with their side chains extending into the gaps between the nanotubules.
KW - Actinide materials
KW - Microporous compounds
KW - Nanostructured materials
KW - Nanotubes
KW - Organically templated compounds
KW - Sulfates
KW - Uranium
UR - http://www.scopus.com/inward/record.url?scp=85044998464&partnerID=8YFLogxK
U2 - 10.3390/nano8040216
DO - 10.3390/nano8040216
M3 - Article
VL - 8
JO - Nanomaterials
JF - Nanomaterials
SN - 2079-4991
IS - 4
M1 - 216
ER -
ID: 33333550