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Uranyl silicate nanotubules in Rb2[(UO2)2O(Si3O8)]: synthesis and crystal structure. / Назарчук, Евгений Васильевич; Сийдра, Олег Иоханнесович; Чаркин, Д. О.; Тагирова, Яна Галиевна.

In: Zeitschrift fur Kristallographie - Crystalline Materials, 29.08.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Назарчук, ЕВ, Сийдра, ОИ, Чаркин, ДО & Тагирова, ЯГ 2023, 'Uranyl silicate nanotubules in Rb2[(UO2)2O(Si3O8)]: synthesis and crystal structure', Zeitschrift fur Kristallographie - Crystalline Materials. https://doi.org/10.1515/zkri-2023-0019

APA

Назарчук, Е. В., Сийдра, О. И., Чаркин, Д. О., & Тагирова, Я. Г. (2023). Uranyl silicate nanotubules in Rb2[(UO2)2O(Si3O8)]: synthesis and crystal structure. Zeitschrift fur Kristallographie - Crystalline Materials. https://doi.org/10.1515/zkri-2023-0019

Vancouver

Назарчук ЕВ, Сийдра ОИ, Чаркин ДО, Тагирова ЯГ. Uranyl silicate nanotubules in Rb2[(UO2)2O(Si3O8)]: synthesis and crystal structure. Zeitschrift fur Kristallographie - Crystalline Materials. 2023 Aug 29. https://doi.org/10.1515/zkri-2023-0019

Author

Назарчук, Евгений Васильевич ; Сийдра, Олег Иоханнесович ; Чаркин, Д. О. ; Тагирова, Яна Галиевна. / Uranyl silicate nanotubules in Rb2[(UO2)2O(Si3O8)]: synthesis and crystal structure. In: Zeitschrift fur Kristallographie - Crystalline Materials. 2023.

BibTeX

@article{d5a68bf5205041f2bc5923ae277c4aeb,
title = "Uranyl silicate nanotubules in Rb2[(UO2)2O(Si3O8)]: synthesis and crystal structure",
abstract = "A new rubidium uranyl silicate, Rb2(UO2)2O(Si3O8) (1), was obtained using high-temperature approach from the melt in silica tubes. Its crystal structure was solved by direct methods: hexagonal, P6/m, a = 27.7992(7), c = 7.2346(2) » {\AA}, V = 4841.8(3) » {\AA}3, R1 = 0.033. The structure of 1 represents a new structure type with unprecedented topology not observed before among U(VI) oxides and oxysalts. It is comprised of layers with large voids derived from the U3O8 structure formed exclusively by pentagonal UrO5 bipyramids. The low-occupied Rb sites are located in the interlayer space. The SiO4 silicate tetrahedra in the structure of 1 share vertices to form rolled [Si6O16]8- chains. The nanotubules [(UO2)(Si6O16)]6- penetrate through both U3O8-derived layers and Rb interlayer. These tubules are attached to the U3O8 derived sheets via uranyl-uranyl interactions and edge-sharing between silicate tetrahedra and UrO5 bipyramids.",
keywords = "inorganic synthesis, microporous structures, nanotubules, silicates, uranyl oxysalts",
author = "Назарчук, {Евгений Васильевич} and Сийдра, {Олег Иоханнесович} and Чаркин, {Д. О.} and Тагирова, {Яна Галиевна}",
year = "2023",
month = aug,
day = "29",
doi = "10.1515/zkri-2023-0019",
language = "English",
journal = "Zeitschrift fur Kristallographie - Crystalline Materials",
issn = "2194-4946",
publisher = "De Gruyter",

}

RIS

TY - JOUR

T1 - Uranyl silicate nanotubules in Rb2[(UO2)2O(Si3O8)]: synthesis and crystal structure

AU - Назарчук, Евгений Васильевич

AU - Сийдра, Олег Иоханнесович

AU - Чаркин, Д. О.

AU - Тагирова, Яна Галиевна

PY - 2023/8/29

Y1 - 2023/8/29

N2 - A new rubidium uranyl silicate, Rb2(UO2)2O(Si3O8) (1), was obtained using high-temperature approach from the melt in silica tubes. Its crystal structure was solved by direct methods: hexagonal, P6/m, a = 27.7992(7), c = 7.2346(2) » Å, V = 4841.8(3) » Å3, R1 = 0.033. The structure of 1 represents a new structure type with unprecedented topology not observed before among U(VI) oxides and oxysalts. It is comprised of layers with large voids derived from the U3O8 structure formed exclusively by pentagonal UrO5 bipyramids. The low-occupied Rb sites are located in the interlayer space. The SiO4 silicate tetrahedra in the structure of 1 share vertices to form rolled [Si6O16]8- chains. The nanotubules [(UO2)(Si6O16)]6- penetrate through both U3O8-derived layers and Rb interlayer. These tubules are attached to the U3O8 derived sheets via uranyl-uranyl interactions and edge-sharing between silicate tetrahedra and UrO5 bipyramids.

AB - A new rubidium uranyl silicate, Rb2(UO2)2O(Si3O8) (1), was obtained using high-temperature approach from the melt in silica tubes. Its crystal structure was solved by direct methods: hexagonal, P6/m, a = 27.7992(7), c = 7.2346(2) » Å, V = 4841.8(3) » Å3, R1 = 0.033. The structure of 1 represents a new structure type with unprecedented topology not observed before among U(VI) oxides and oxysalts. It is comprised of layers with large voids derived from the U3O8 structure formed exclusively by pentagonal UrO5 bipyramids. The low-occupied Rb sites are located in the interlayer space. The SiO4 silicate tetrahedra in the structure of 1 share vertices to form rolled [Si6O16]8- chains. The nanotubules [(UO2)(Si6O16)]6- penetrate through both U3O8-derived layers and Rb interlayer. These tubules are attached to the U3O8 derived sheets via uranyl-uranyl interactions and edge-sharing between silicate tetrahedra and UrO5 bipyramids.

KW - inorganic synthesis

KW - microporous structures

KW - nanotubules

KW - silicates

KW - uranyl oxysalts

UR - https://www.mendeley.com/catalogue/971ee98d-1e6e-39fc-b913-e1a5199afc46/

U2 - 10.1515/zkri-2023-0019

DO - 10.1515/zkri-2023-0019

M3 - Article

JO - Zeitschrift fur Kristallographie - Crystalline Materials

JF - Zeitschrift fur Kristallographie - Crystalline Materials

SN - 2194-4946

ER -

ID: 108473138