Unusual selective substitution of triply bridging carbonyl ligands for GaCp* in Rh6(CO)16. Synthesis and structural characterization of the Rh6(μ3-CO)4 - x(μ3-GaCp*)x(CO)12 clusters, x = 1-4

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Unusual selective substitution of triply bridging carbonyl ligands for GaCp* in Rh₆(CO)₁₆. Synthesis and structural characterization of the Rh₆(μ₃-CO)_{4 - x}(μ₃-GaCp*)_x(CO)₁₂ clusters, x = 1-4

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Department of General and Inorganic Chemistry

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Elena V. Grachova
Peter Jutzi
Beate Neumann
Lars O. Schebaum
Hans Georg Stammler
Sergey P. Tunik

Reactions of hexanuclear rhodium clusters with GaCp* (Cp* = C₅Me₅) result in unusual substitution of face bridging CO ligands to give a series of the Rh₆(μ₃-CO)_{4 - x} (μ₃-GaCp*)_x(CO)₁₂ substituted derivatives.

Original language	English
Pages (from-to)	302-304
Number of pages	3
Journal	Dalton Transactions
Issue number	3
State	Published - 18 Feb 2002

Scopus subject areas

Chemistry(all)

ID: 36018095