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Universal asymptotics of the thermodynamic characteristics of the nucleation on small macroscopic nuclei of soluble surfactants. / Shchekin, A. K.; Yakovenko, T. M.; Rusanov, A. I.; Kuni, F. M.

In: Colloid Journal, Vol. 64, No. 4, 01.07.2002, p. 499-507.

Research output: Contribution to journal › Article › peer-review

Harvard

Shchekin, AK, Yakovenko, TM, Rusanov, AI & Kuni, FM 2002, 'Universal asymptotics of the thermodynamic characteristics of the nucleation on small macroscopic nuclei of soluble surfactants', Colloid Journal, vol. 64, no. 4, pp. 499-507. https://doi.org/10.1023/A:1016832423342

APA

Shchekin, A. K., Yakovenko, T. M., Rusanov, A. I., & Kuni, F. M. (2002). Universal asymptotics of the thermodynamic characteristics of the nucleation on small macroscopic nuclei of soluble surfactants. Colloid Journal, 64(4), 499-507. https://doi.org/10.1023/A:1016832423342

Vancouver

Shchekin AK, Yakovenko TM, Rusanov AI, Kuni FM. Universal asymptotics of the thermodynamic characteristics of the nucleation on small macroscopic nuclei of soluble surfactants. Colloid Journal. 2002 Jul 1;64(4):499-507. https://doi.org/10.1023/A:1016832423342

Author

Shchekin, A. K. ; Yakovenko, T. M. ; Rusanov, A. I. ; Kuni, F. M. / Universal asymptotics of the thermodynamic characteristics of the nucleation on small macroscopic nuclei of soluble surfactants. In: Colloid Journal. 2002 ; Vol. 64, No. 4. pp. 499-507.

BibTeX

@article{e5af09725dad47abae0b4ce00d71f1ec,
title = "Universal asymptotics of the thermodynamic characteristics of the nucleation on small macroscopic nuclei of soluble surfactants",
abstract = "Asymptotic behavior of thermodynamic characteristics of nucleation on small macroscopic nuclei of soluble surfactants at their complete dissolution in a nucleating droplet is studied. It is taken into account that, in the region of small sizes of nuclei and corresponding small sizes of critical nuclei of liquid phase, the chemical potential of condensate and the work of droplet formation are affected by the presence of dense surfactant adsorption monolayer on the droplet surface. It is shown that, as the limiting surface area per surfactant molecule in adsorption monolayer increases, the behavior of thermodynamic characteristics of nucleation in the region of small nucleus sizes is characterized by the transition from asymptotics at the adsorption of almost all substance comprising nucleus in a monolayer to the asymptotics at constant adsorption. The study performed is not limited by the selection of specific adsorption isotherms; therefore, the obtained asymptotic dependences of thermodynamic characteristics on the nucleus size can be considered as universal for the heterogeneous nucleation on the nuclei of soluble surfactants.",
author = "Shchekin, {A. K.} and Yakovenko, {T. M.} and Rusanov, {A. I.} and Kuni, {F. M.}",
year = "2002",
month = jul,
day = "1",
doi = "10.1023/A:1016832423342",
language = "English",
volume = "64",
pages = "499--507",
journal = "Colloid Journal",
issn = "1061-933X",
publisher = "Pleiades Publishing",
number = "4",

}

RIS

TY - JOUR

T1 - Universal asymptotics of the thermodynamic characteristics of the nucleation on small macroscopic nuclei of soluble surfactants

AU - Shchekin, A. K.

AU - Yakovenko, T. M.

AU - Rusanov, A. I.

AU - Kuni, F. M.

PY - 2002/7/1

Y1 - 2002/7/1

N2 - Asymptotic behavior of thermodynamic characteristics of nucleation on small macroscopic nuclei of soluble surfactants at their complete dissolution in a nucleating droplet is studied. It is taken into account that, in the region of small sizes of nuclei and corresponding small sizes of critical nuclei of liquid phase, the chemical potential of condensate and the work of droplet formation are affected by the presence of dense surfactant adsorption monolayer on the droplet surface. It is shown that, as the limiting surface area per surfactant molecule in adsorption monolayer increases, the behavior of thermodynamic characteristics of nucleation in the region of small nucleus sizes is characterized by the transition from asymptotics at the adsorption of almost all substance comprising nucleus in a monolayer to the asymptotics at constant adsorption. The study performed is not limited by the selection of specific adsorption isotherms; therefore, the obtained asymptotic dependences of thermodynamic characteristics on the nucleus size can be considered as universal for the heterogeneous nucleation on the nuclei of soluble surfactants.

AB - Asymptotic behavior of thermodynamic characteristics of nucleation on small macroscopic nuclei of soluble surfactants at their complete dissolution in a nucleating droplet is studied. It is taken into account that, in the region of small sizes of nuclei and corresponding small sizes of critical nuclei of liquid phase, the chemical potential of condensate and the work of droplet formation are affected by the presence of dense surfactant adsorption monolayer on the droplet surface. It is shown that, as the limiting surface area per surfactant molecule in adsorption monolayer increases, the behavior of thermodynamic characteristics of nucleation in the region of small nucleus sizes is characterized by the transition from asymptotics at the adsorption of almost all substance comprising nucleus in a monolayer to the asymptotics at constant adsorption. The study performed is not limited by the selection of specific adsorption isotherms; therefore, the obtained asymptotic dependences of thermodynamic characteristics on the nucleus size can be considered as universal for the heterogeneous nucleation on the nuclei of soluble surfactants.

UR - http://www.scopus.com/inward/record.url?scp=14244271539&partnerID=8YFLogxK

U2 - 10.1023/A:1016832423342

DO - 10.1023/A:1016832423342

M3 - Article

VL - 64

SP - 499

EP - 507

JO - Colloid Journal

JF - Colloid Journal

SN - 1061-933X

IS - 4

ER -

ID: 5113477