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@article{35bb936c69924f0eaccc2d7a61a97c29,
title = "Ultrasound-Assisted Synthesis of Microcrystalline Lanthanide Terephthalates: Insights into Morphology and Structural Properties",
abstract = "Crystalline lanthanide terephthalates, Ln2bdc3‧nH2O (Ln = La–Lu, excluding Pm), were synthesized using a surfactant-free, ultrasound-assisted method. This approach yielded microcrystals with diverse shapes and sizes ranging from 2 to 10 μm. Notably, under these conditions, lutetium terephthalate uniquely crystallized as Lu2(1,4-bdc)3·2.5H2O, while the remaining lanthanides formed tetrahydrate terephthalates, Ln2bdc3‧4H2O (Ln = La–Nd, Sm–Yb).",
keywords = "MOF, coordination polymer, f-element, lanthanide, microparticle, rare earth, terephthalate, ultrasound",
author = "Тойкка, {Юлия Николаевна} and Гусева, {Полина Борисовна} and Богачев, {Никита Александрович} and Колесник, {Стефания Сергеевна} and Глухоедов, {Никита Алексеевич} and Орлов, {Сергей Николаевич} and Рязанцев, {Михаил Николаевич} and Скрипкин, {Михаил Юрьевич} and Мерещенко, {Андрей Сергеевич}",
year = "2025",
month = mar,
day = "28",
doi = "10.3390/chemistry7020049",
language = "English",
volume = "7",
journal = "Chemistry (Switzerland)",
issn = "2624-8549",
publisher = "MDPI AG",
number = "2",

}

RIS

TY - JOUR

T1 - Ultrasound-Assisted Synthesis of Microcrystalline Lanthanide Terephthalates: Insights into Morphology and Structural Properties

AU - Тойкка, Юлия Николаевна

AU - Гусева, Полина Борисовна

AU - Богачев, Никита Александрович

AU - Колесник, Стефания Сергеевна

AU - Глухоедов, Никита Алексеевич

AU - Орлов, Сергей Николаевич

AU - Рязанцев, Михаил Николаевич

AU - Скрипкин, Михаил Юрьевич

AU - Мерещенко, Андрей Сергеевич

PY - 2025/3/28

Y1 - 2025/3/28

N2 - Crystalline lanthanide terephthalates, Ln2bdc3‧nH2O (Ln = La–Lu, excluding Pm), were synthesized using a surfactant-free, ultrasound-assisted method. This approach yielded microcrystals with diverse shapes and sizes ranging from 2 to 10 μm. Notably, under these conditions, lutetium terephthalate uniquely crystallized as Lu2(1,4-bdc)3·2.5H2O, while the remaining lanthanides formed tetrahydrate terephthalates, Ln2bdc3‧4H2O (Ln = La–Nd, Sm–Yb).

AB - Crystalline lanthanide terephthalates, Ln2bdc3‧nH2O (Ln = La–Lu, excluding Pm), were synthesized using a surfactant-free, ultrasound-assisted method. This approach yielded microcrystals with diverse shapes and sizes ranging from 2 to 10 μm. Notably, under these conditions, lutetium terephthalate uniquely crystallized as Lu2(1,4-bdc)3·2.5H2O, while the remaining lanthanides formed tetrahydrate terephthalates, Ln2bdc3‧4H2O (Ln = La–Nd, Sm–Yb).

KW - MOF

KW - coordination polymer

KW - f-element

KW - lanthanide

KW - microparticle

KW - rare earth

KW - terephthalate

KW - ultrasound

UR - https://www.mendeley.com/catalogue/f24d2f65-f8c8-3ffc-b9b0-69fae4ac2697/

U2 - 10.3390/chemistry7020049

DO - 10.3390/chemistry7020049

M3 - Article

VL - 7

JO - Chemistry (Switzerland)

JF - Chemistry (Switzerland)

SN - 2624-8549

IS - 2

M1 - 49

ER -

ID: 135973941