Two-Dimensional Coordination Polymer {[Bi(Рyz)I3]}

Two-Dimensional Coordination Polymer {[Bi(Рyz)I₃]}: Structure and Analysis of the Packing Using the Hirshfeld Surface Method

Research output: Contribution to journal › Article › peer-review

Institute of Chemistry

DOI

https://doi.org/10.1134/S107032842001008X
Final published version

A. N. Usoltsev
S. A. Adonin
A. S. Novikov
M. N. Sokolov
V. P. Fedin

Abstract: The reaction of BiI₃ with pyrazine in tetrahydrofuran affords the two-dimensional coordination polymer {[Bi(Pyz)I₃]} (I), whose structure is determined by X-ray diffraction analysis (СIF file ССDС no. 1904990). The contributions of various interatomic contacts to the crystal packing of compound I are studied using the Hirshfeld surface analysis performed for the elementary unit of compound I. The interatomic distances I···H make the largest contribution to the crystal packing of compound I.

Original language	English
Pages (from-to)	23-27
Number of pages	5
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	46
Issue number	1
DOIs	https://doi.org/10.1134/S107032842001008X
State	Published - 1 Jan 2020

Scopus subject areas

Chemical Engineering(all)
Chemistry(all)

Research areas

analysis of Hirshfeld surfaces, bismuth, coordination polymers, crystal structure, pyrazine, M-II, CRYSTAL-STRUCTURE, COMPLEXES, METAL-ORGANIC FRAMEWORK, CL, NI, ARCHITECTURES

ID: 52884993