DOI

CO interacts with exchangeable cations M+ (gray spheres in the picture) of zeolites to form M+ ··· CO and M+ ·· OC species (C: black; O: white) which are in a temperature-dependent equilibrium. For Na-ZSM-5 (M+ = Na+) the difference in interaction energy amounts to 3.8 kJ mol-1, as determined by means of variable-temperature FT-IR spectroscopy.

Original languageEnglish
Pages (from-to)3161-3163
Number of pages3
JournalAngewandte Chemie - International Edition
Volume37
Issue number22
DOIs
StatePublished - 4 Dec 1998

    Research areas

  • Adsorption, Carbon monoxide, Heterogeneous catalysis, IR spectroscopy, Zeolites

    Scopus subject areas

  • Catalysis
  • Chemistry(all)

ID: 41683516