Research output: Contribution to journal › Review article › peer-review
Tuning the luminescence of transition metal complexes with acyclic diaminocarbene ligands. / Kinzhalov, Mikhail A.; Grachova, Elena V.; Luzyanin, Konstantin V.
In: Inorganic Chemistry Frontiers, Vol. 9, No. 3, 07.02.2022, p. 417-439.Research output: Contribution to journal › Review article › peer-review
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TY - JOUR
T1 - Tuning the luminescence of transition metal complexes with acyclic diaminocarbene ligands
AU - Kinzhalov, Mikhail A.
AU - Grachova, Elena V.
AU - Luzyanin, Konstantin V.
N1 - Publisher Copyright: © 2022 the Partner Organisations.
PY - 2022/2/7
Y1 - 2022/2/7
N2 - Metal complexes featuring acyclic diaminocarbene ligands have recently emerged as powerful emitters for prospective use in OLEDs and other electroluminescent technologies. Owing to their strong σ-donating properties and broad synthetic availability, acyclic diaminocarbenes have successfully challenged the application of other ancillary ligands for fine-tuning of luminescence emission. This review systematises the data reported concerning the preparation of luminescent metal complexes bearing acyclic diaminocarbene ligands, uncovers their photophysical properties as a function of the carbene ligand structure and metal characteristics, and draws attention to the potential of ADCs and the advantages that the application of metal-(acyclic diaminocarbenes) provides to the family of transition-metal-based phosphors.
AB - Metal complexes featuring acyclic diaminocarbene ligands have recently emerged as powerful emitters for prospective use in OLEDs and other electroluminescent technologies. Owing to their strong σ-donating properties and broad synthetic availability, acyclic diaminocarbenes have successfully challenged the application of other ancillary ligands for fine-tuning of luminescence emission. This review systematises the data reported concerning the preparation of luminescent metal complexes bearing acyclic diaminocarbene ligands, uncovers their photophysical properties as a function of the carbene ligand structure and metal characteristics, and draws attention to the potential of ADCs and the advantages that the application of metal-(acyclic diaminocarbenes) provides to the family of transition-metal-based phosphors.
KW - CYCLOMETALATED IRIDIUM COMPLEXES
KW - EXCITED-STATE PROPERTIES
KW - PLATINUM(II) COMPLEXES
KW - CARBENE COMPLEXES
KW - MECHANOCHROMIC LUMINESCENCE
KW - ISOCYANIDE COMPLEXES
KW - CHELATING DICARBENE
KW - TEMPLATE SYNTHESIS
KW - OPTICAL-PROPERTIES
KW - IR(III) COMPLEXES
UR - http://www.scopus.com/inward/record.url?scp=85121918762&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/79a1e8e1-6bcc-3383-afdb-209e8d8b0830/
U2 - 10.1039/d1qi01288f
DO - 10.1039/d1qi01288f
M3 - Review article
AN - SCOPUS:85121918762
VL - 9
SP - 417
EP - 439
JO - Inorganic Chemistry Frontiers
JF - Inorganic Chemistry Frontiers
SN - 2052-1545
IS - 3
ER -
ID: 92035927