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Tuning the luminescence of transition metal complexes with acyclic diaminocarbene ligands. / Kinzhalov, Mikhail A.; Grachova, Elena V.; Luzyanin, Konstantin V.

In: Inorganic Chemistry Frontiers, Vol. 9, No. 3, 07.02.2022, p. 417-439.

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Kinzhalov, Mikhail A. ; Grachova, Elena V. ; Luzyanin, Konstantin V. / Tuning the luminescence of transition metal complexes with acyclic diaminocarbene ligands. In: Inorganic Chemistry Frontiers. 2022 ; Vol. 9, No. 3. pp. 417-439.

BibTeX

@article{e8ee32a9e73f48969cdc40f20e87ddc4,
title = "Tuning the luminescence of transition metal complexes with acyclic diaminocarbene ligands",
abstract = "Metal complexes featuring acyclic diaminocarbene ligands have recently emerged as powerful emitters for prospective use in OLEDs and other electroluminescent technologies. Owing to their strong σ-donating properties and broad synthetic availability, acyclic diaminocarbenes have successfully challenged the application of other ancillary ligands for fine-tuning of luminescence emission. This review systematises the data reported concerning the preparation of luminescent metal complexes bearing acyclic diaminocarbene ligands, uncovers their photophysical properties as a function of the carbene ligand structure and metal characteristics, and draws attention to the potential of ADCs and the advantages that the application of metal-(acyclic diaminocarbenes) provides to the family of transition-metal-based phosphors. ",
keywords = "CYCLOMETALATED IRIDIUM COMPLEXES, EXCITED-STATE PROPERTIES, PLATINUM(II) COMPLEXES, CARBENE COMPLEXES, MECHANOCHROMIC LUMINESCENCE, ISOCYANIDE COMPLEXES, CHELATING DICARBENE, TEMPLATE SYNTHESIS, OPTICAL-PROPERTIES, IR(III) COMPLEXES",
author = "Kinzhalov, {Mikhail A.} and Grachova, {Elena V.} and Luzyanin, {Konstantin V.}",
note = "Publisher Copyright: {\textcopyright} 2022 the Partner Organisations.",
year = "2022",
month = feb,
day = "7",
doi = "10.1039/d1qi01288f",
language = "English",
volume = "9",
pages = "417--439",
journal = "Inorganic Chemistry Frontiers",
issn = "2052-1545",
publisher = "Royal Society of Chemistry",
number = "3",

}

RIS

TY - JOUR

T1 - Tuning the luminescence of transition metal complexes with acyclic diaminocarbene ligands

AU - Kinzhalov, Mikhail A.

AU - Grachova, Elena V.

AU - Luzyanin, Konstantin V.

N1 - Publisher Copyright: © 2022 the Partner Organisations.

PY - 2022/2/7

Y1 - 2022/2/7

N2 - Metal complexes featuring acyclic diaminocarbene ligands have recently emerged as powerful emitters for prospective use in OLEDs and other electroluminescent technologies. Owing to their strong σ-donating properties and broad synthetic availability, acyclic diaminocarbenes have successfully challenged the application of other ancillary ligands for fine-tuning of luminescence emission. This review systematises the data reported concerning the preparation of luminescent metal complexes bearing acyclic diaminocarbene ligands, uncovers their photophysical properties as a function of the carbene ligand structure and metal characteristics, and draws attention to the potential of ADCs and the advantages that the application of metal-(acyclic diaminocarbenes) provides to the family of transition-metal-based phosphors.

AB - Metal complexes featuring acyclic diaminocarbene ligands have recently emerged as powerful emitters for prospective use in OLEDs and other electroluminescent technologies. Owing to their strong σ-donating properties and broad synthetic availability, acyclic diaminocarbenes have successfully challenged the application of other ancillary ligands for fine-tuning of luminescence emission. This review systematises the data reported concerning the preparation of luminescent metal complexes bearing acyclic diaminocarbene ligands, uncovers their photophysical properties as a function of the carbene ligand structure and metal characteristics, and draws attention to the potential of ADCs and the advantages that the application of metal-(acyclic diaminocarbenes) provides to the family of transition-metal-based phosphors.

KW - CYCLOMETALATED IRIDIUM COMPLEXES

KW - EXCITED-STATE PROPERTIES

KW - PLATINUM(II) COMPLEXES

KW - CARBENE COMPLEXES

KW - MECHANOCHROMIC LUMINESCENCE

KW - ISOCYANIDE COMPLEXES

KW - CHELATING DICARBENE

KW - TEMPLATE SYNTHESIS

KW - OPTICAL-PROPERTIES

KW - IR(III) COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85121918762&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/79a1e8e1-6bcc-3383-afdb-209e8d8b0830/

U2 - 10.1039/d1qi01288f

DO - 10.1039/d1qi01288f

M3 - Review article

AN - SCOPUS:85121918762

VL - 9

SP - 417

EP - 439

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

SN - 2052-1545

IS - 3

ER -

ID: 92035927