Research output: Contribution to journal › Article › peer-review
Triple-bridged helical binuclear copper(i) complexes: Head-to-head and head-to-tail isomerism and the solid-state luminescence. / Shamsieva, A. V.; Musina, Elvira I.; Gerasimova, T.P.; Strelnik, Igor D.; Strelnik, Anna; Колесников, Илья Евгеньевич; Калиничев, Алексей Андреевич; Islamov, Daut; Samigullina, Aida; Lӧnnecke, Peter ; Katsyuba, Sergey A.; Hey-Hawkins, Evamarie ; Karasik, Andrey A.; Sinyashin, Oleg G.
In: Dalton Transactions, Vol. 49, No. 34, 14.09.2020, p. 11997-12008.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Triple-bridged helical binuclear copper(i) complexes: Head-to-head and head-to-tail isomerism and the solid-state luminescence
AU - Shamsieva, A. V.
AU - Musina, Elvira I.
AU - Gerasimova, T.P.
AU - Strelnik, Igor D.
AU - Strelnik, Anna
AU - Колесников, Илья Евгеньевич
AU - Калиничев, Алексей Андреевич
AU - Islamov, Daut
AU - Samigullina, Aida
AU - Lӧnnecke, Peter
AU - Katsyuba, Sergey A.
AU - Hey-Hawkins, Evamarie
AU - Karasik, Andrey A.
AU - Sinyashin, Oleg G.
N1 - Publisher Copyright: © The Royal Society of Chemistry.
PY - 2020/9/14
Y1 - 2020/9/14
N2 - A family of helical dinuclear copper(i) pyridylphospholane complexes [Cu2L3X]X (X = BF4-, Cl- and Br-) was prepared. The family includes the first examples of this type of complex based on copper(i) chloride and copper(i) bromide. The two isomers typical of this class of compounds, namely head-to-head and head-to-tail complexes, were studied in solution by spectroscopic and optical methods, and in the solid state by X-ray diffraction. Furthermore, the solid-state luminescence of the complexes at different temperatures was studied, and the results were interpreted using quantum-chemical calculations. It was shown that the luminescence of the complexes is attributed to the 3(M + X)LCT transitions. This journal is
AB - A family of helical dinuclear copper(i) pyridylphospholane complexes [Cu2L3X]X (X = BF4-, Cl- and Br-) was prepared. The family includes the first examples of this type of complex based on copper(i) chloride and copper(i) bromide. The two isomers typical of this class of compounds, namely head-to-head and head-to-tail complexes, were studied in solution by spectroscopic and optical methods, and in the solid state by X-ray diffraction. Furthermore, the solid-state luminescence of the complexes at different temperatures was studied, and the results were interpreted using quantum-chemical calculations. It was shown that the luminescence of the complexes is attributed to the 3(M + X)LCT transitions. This journal is
KW - CLUSTER
KW - CRYSTAL-STRUCTURE
KW - CU(I) COMPLEXES
KW - DENSITY-FUNCTIONAL THEORY
KW - DESIGN
KW - EMISSION
KW - LIGAND
KW - OPTICAL SPECTROSCOPY
KW - PYRIDYL
UR - http://www.scopus.com/inward/record.url?scp=85090175711&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/3dd78f2b-762c-33fb-806a-214051a02daa/
U2 - 10.1039/D0DT01843K
DO - 10.1039/D0DT01843K
M3 - Article
VL - 49
SP - 11997
EP - 12008
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 34
ER -
ID: 70188731