Trifluoromethanesulfonic acid in organic synthesis

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Trifluoromethanesulfonic acid in organic synthesis. / Kazakova, A. N.; Vasilyev, A. V.

In: Russian Journal of Organic Chemistry, Vol. 53, No. 4, 01.01.2017, p. 485-509.

Research output: Contribution to journal › Review article › peer-review

Author

Kazakova, A. N. ; Vasilyev, A. V. / Trifluoromethanesulfonic acid in organic synthesis. In: Russian Journal of Organic Chemistry. 2017 ; Vol. 53, No. 4. pp. 485-509.

BibTeX

@article{b566c9b3dd004127b7d48195799e99ce,

title = "Trifluoromethanesulfonic acid in organic synthesis",

abstract = "The review analyzes data published in the past decade on the use of trifluoromethanesulfonic acid (triflic acid, CF3SO3H, TfOH) in organic synthesis, in particular in electrophilic aromatic substitution (Friedel–Crafts) reactions, formation of carbon–carbon and carbon–heteroatom bonds, isomerizations, syntheses of carboand heterocyclic structures, and other reactions, as well as in natural and organometallic compounds chemistry. The high protonating power and low nucleophilicity makes trifluoromethanesulfonic acid capable of generating from organic molecules cationic species which can be detected by spectral methods (NMR, IR spectroscopy, etc.), and their transformations can be studied. Experimental simplicity and efficiency of reactions promoted by trifluoromethanesulfonic acid make it a convenient reagent for the synthesis of new organic compounds.",

author = "Kazakova, {A. N.} and Vasilyev, {A. V.}",

year = "2017",

month = jan,

day = "1",

doi = "10.1134/S1070428017040017",

language = "English",

volume = "53",

pages = "485--509",

journal = "Russian Journal of Organic Chemistry",

issn = "1070-4280",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "4",

}

RIS

TY - JOUR

T1 - Trifluoromethanesulfonic acid in organic synthesis

AU - Kazakova, A. N.

AU - Vasilyev, A. V.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The review analyzes data published in the past decade on the use of trifluoromethanesulfonic acid (triflic acid, CF3SO3H, TfOH) in organic synthesis, in particular in electrophilic aromatic substitution (Friedel–Crafts) reactions, formation of carbon–carbon and carbon–heteroatom bonds, isomerizations, syntheses of carboand heterocyclic structures, and other reactions, as well as in natural and organometallic compounds chemistry. The high protonating power and low nucleophilicity makes trifluoromethanesulfonic acid capable of generating from organic molecules cationic species which can be detected by spectral methods (NMR, IR spectroscopy, etc.), and their transformations can be studied. Experimental simplicity and efficiency of reactions promoted by trifluoromethanesulfonic acid make it a convenient reagent for the synthesis of new organic compounds.

AB - The review analyzes data published in the past decade on the use of trifluoromethanesulfonic acid (triflic acid, CF3SO3H, TfOH) in organic synthesis, in particular in electrophilic aromatic substitution (Friedel–Crafts) reactions, formation of carbon–carbon and carbon–heteroatom bonds, isomerizations, syntheses of carboand heterocyclic structures, and other reactions, as well as in natural and organometallic compounds chemistry. The high protonating power and low nucleophilicity makes trifluoromethanesulfonic acid capable of generating from organic molecules cationic species which can be detected by spectral methods (NMR, IR spectroscopy, etc.), and their transformations can be studied. Experimental simplicity and efficiency of reactions promoted by trifluoromethanesulfonic acid make it a convenient reagent for the synthesis of new organic compounds.

UR - http://www.scopus.com/inward/record.url?scp=85019989986&partnerID=8YFLogxK

U2 - 10.1134/S1070428017040017

DO - 10.1134/S1070428017040017

M3 - Review article

AN - SCOPUS:85019989986

VL - 53

SP - 485

EP - 509

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 4

ER -

ID: 44003155