Research output: Contribution to journal › Article › peer-review
Triaryl-substituted pyrrolo-p-phenylene-linked porphyrin-fullerene dyads : Expanding the structural diversity of photoactive materials. / Strelnikov, Artem A.; Androsov, Dmitriy V.; Konev, Alexander S.; Lukyanov, Daniil A.; Khlebnikov, Alexander F.; Povolotskiy, Alexey V.; Yamanouchi, Kaoru.
In: Tetrahedron, Vol. 74, No. 24, 14.06.2018, p. 3007-3019.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Triaryl-substituted pyrrolo-p-phenylene-linked porphyrin-fullerene dyads
T2 - Expanding the structural diversity of photoactive materials
AU - Strelnikov, Artem A.
AU - Androsov, Dmitriy V.
AU - Konev, Alexander S.
AU - Lukyanov, Daniil A.
AU - Khlebnikov, Alexander F.
AU - Povolotskiy, Alexey V.
AU - Yamanouchi, Kaoru
PY - 2018/6/14
Y1 - 2018/6/14
N2 - A protocol for the synthesis of pyrrolo-p-phenylene-linked porphyrin-fullerene dyads suitable as photoactive materials was developed. The sequence of aziridination – aziridine ring opening – 1,3-dipolar cycloaddition reactions enabled us to provide structural variability both to the porphyrin core and to pyrrole linker, which facilitates designing the electronic structure and morphological parameters of the dyads. The key porphyrin building blocks, nitro-porphyrins, were synthesized by a stochastic cyclocondensation of arenecarbaldehydes with p-nitrophenyl(dipyrrolyl)methane.
AB - A protocol for the synthesis of pyrrolo-p-phenylene-linked porphyrin-fullerene dyads suitable as photoactive materials was developed. The sequence of aziridination – aziridine ring opening – 1,3-dipolar cycloaddition reactions enabled us to provide structural variability both to the porphyrin core and to pyrrole linker, which facilitates designing the electronic structure and morphological parameters of the dyads. The key porphyrin building blocks, nitro-porphyrins, were synthesized by a stochastic cyclocondensation of arenecarbaldehydes with p-nitrophenyl(dipyrrolyl)methane.
KW - Aziridines
KW - Dipolar cycloaddition
KW - Donor-acceptor conjugates
KW - Fullerenes
KW - Porphyrins
KW - COMPLEXES
KW - AZOMETHINE YLIDES
KW - FUNCTIONALIZATION
KW - CYCLOADDITION
KW - ELECTRON-TRANSFER
KW - CHEMISTRY
KW - STEREOSELECTIVE-SYNTHESIS
KW - C-60
KW - DERIVATIVES
KW - EFFICIENT
UR - http://www.scopus.com/inward/record.url?scp=85046760439&partnerID=8YFLogxK
U2 - 10.1016/j.tet.2018.04.084
DO - 10.1016/j.tet.2018.04.084
M3 - Article
AN - SCOPUS:85046760439
VL - 74
SP - 3007
EP - 3019
JO - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
IS - 24
ER -
ID: 28187318