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@article{23b84a2278db46d7bc6fb2b08414ca5c,
title = "Triaryl-substituted pyrrolo-p-phenylene-linked porphyrin-fullerene dyads: Expanding the structural diversity of photoactive materials",
abstract = "A protocol for the synthesis of pyrrolo-p-phenylene-linked porphyrin-fullerene dyads suitable as photoactive materials was developed. The sequence of aziridination – aziridine ring opening – 1,3-dipolar cycloaddition reactions enabled us to provide structural variability both to the porphyrin core and to pyrrole linker, which facilitates designing the electronic structure and morphological parameters of the dyads. The key porphyrin building blocks, nitro-porphyrins, were synthesized by a stochastic cyclocondensation of arenecarbaldehydes with p-nitrophenyl(dipyrrolyl)methane.",
keywords = "Aziridines, Dipolar cycloaddition, Donor-acceptor conjugates, Fullerenes, Porphyrins, COMPLEXES, AZOMETHINE YLIDES, FUNCTIONALIZATION, CYCLOADDITION, ELECTRON-TRANSFER, CHEMISTRY, STEREOSELECTIVE-SYNTHESIS, C-60, DERIVATIVES, EFFICIENT",
author = "Strelnikov, {Artem A.} and Androsov, {Dmitriy V.} and Konev, {Alexander S.} and Lukyanov, {Daniil A.} and Khlebnikov, {Alexander F.} and Povolotskiy, {Alexey V.} and Kaoru Yamanouchi",
year = "2018",
month = jun,
day = "14",
doi = "10.1016/j.tet.2018.04.084",
language = "English",
volume = "74",
pages = "3007--3019",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier",
number = "24",

}

RIS

TY - JOUR

T1 - Triaryl-substituted pyrrolo-p-phenylene-linked porphyrin-fullerene dyads

T2 - Expanding the structural diversity of photoactive materials

AU - Strelnikov, Artem A.

AU - Androsov, Dmitriy V.

AU - Konev, Alexander S.

AU - Lukyanov, Daniil A.

AU - Khlebnikov, Alexander F.

AU - Povolotskiy, Alexey V.

AU - Yamanouchi, Kaoru

PY - 2018/6/14

Y1 - 2018/6/14

N2 - A protocol for the synthesis of pyrrolo-p-phenylene-linked porphyrin-fullerene dyads suitable as photoactive materials was developed. The sequence of aziridination – aziridine ring opening – 1,3-dipolar cycloaddition reactions enabled us to provide structural variability both to the porphyrin core and to pyrrole linker, which facilitates designing the electronic structure and morphological parameters of the dyads. The key porphyrin building blocks, nitro-porphyrins, were synthesized by a stochastic cyclocondensation of arenecarbaldehydes with p-nitrophenyl(dipyrrolyl)methane.

AB - A protocol for the synthesis of pyrrolo-p-phenylene-linked porphyrin-fullerene dyads suitable as photoactive materials was developed. The sequence of aziridination – aziridine ring opening – 1,3-dipolar cycloaddition reactions enabled us to provide structural variability both to the porphyrin core and to pyrrole linker, which facilitates designing the electronic structure and morphological parameters of the dyads. The key porphyrin building blocks, nitro-porphyrins, were synthesized by a stochastic cyclocondensation of arenecarbaldehydes with p-nitrophenyl(dipyrrolyl)methane.

KW - Aziridines

KW - Dipolar cycloaddition

KW - Donor-acceptor conjugates

KW - Fullerenes

KW - Porphyrins

KW - COMPLEXES

KW - AZOMETHINE YLIDES

KW - FUNCTIONALIZATION

KW - CYCLOADDITION

KW - ELECTRON-TRANSFER

KW - CHEMISTRY

KW - STEREOSELECTIVE-SYNTHESIS

KW - C-60

KW - DERIVATIVES

KW - EFFICIENT

UR - http://www.scopus.com/inward/record.url?scp=85046760439&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2018.04.084

DO - 10.1016/j.tet.2018.04.084

M3 - Article

AN - SCOPUS:85046760439

VL - 74

SP - 3007

EP - 3019

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 24

ER -

ID: 28187318