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Transport properties of solid electrolytes based on MeSm2S 4. / Ushakova, Yu N.; Kalinina, L. A.; Yurlov, I. S.; Fominykh, E. G.; Ananchenko, B. A.; Rossikhina, A. A.; Murin, I. V.

In: Glass Physics and Chemistry, Vol. 33, No. 4, 08.2007, p. 369-378.

Research output: Contribution to journal › Article › peer-review

Harvard

Ushakova, YN, Kalinina, LA, Yurlov, IS, Fominykh, EG, Ananchenko, BA, Rossikhina, AA & Murin, IV 2007, 'Transport properties of solid electrolytes based on MeSm2S 4', Glass Physics and Chemistry, vol. 33, no. 4, pp. 369-378. https://doi.org/10.1134/S1087659607040116

APA

Ushakova, Y. N., Kalinina, L. A., Yurlov, I. S., Fominykh, E. G., Ananchenko, B. A., Rossikhina, A. A., & Murin, I. V. (2007). Transport properties of solid electrolytes based on MeSm2S 4. Glass Physics and Chemistry, 33(4), 369-378. https://doi.org/10.1134/S1087659607040116

Vancouver

Ushakova YN, Kalinina LA, Yurlov IS, Fominykh EG, Ananchenko BA, Rossikhina AA et al. Transport properties of solid electrolytes based on MeSm2S 4. Glass Physics and Chemistry. 2007 Aug;33(4):369-378. https://doi.org/10.1134/S1087659607040116

Author

Ushakova, Yu N. ; Kalinina, L. A. ; Yurlov, I. S. ; Fominykh, E. G. ; Ananchenko, B. A. ; Rossikhina, A. A. ; Murin, I. V. / Transport properties of solid electrolytes based on MeSm2S 4. In: Glass Physics and Chemistry. 2007 ; Vol. 33, No. 4. pp. 369-378.

BibTeX

@article{2d8a448bd5a547eebf65c05ecbcd6747,
title = "Transport properties of solid electrolytes based on MeSm2S 4",
abstract = "The solid-solution regions in the MeSm2S4-MeS and MeSm2S4-Sm2S3 (Me = Ca, Ba) systems are revealed. The average ion, cation, and anion transport number of the synthesized solid electrolytes xSm2S3[Ca(Ba)S] • (100 - x)Ca(Ba)Sm2S4 (x = 1-10 mol %) are determined by the electromotive force (emf) method with the use of concentration cells with and without transfer. In the phases under investigation, the ion transfer in the temperature range 673-723 K is provided by sulfide ions (tS2 = 1.00±0.02). The diffusion coefficients of S2- ions in the solid electrolytes are determined by potentiostatic chronoamperometry. A vacancy mechanism of defect formation is proposed. It is demonstrated that the transport characteristics of the solid electrolytes based on the CaSm 2S4 compound are worse than those of the solid electrolytes based on the BaSm2S4 compound.",
author = "Ushakova, {Yu N.} and Kalinina, {L. A.} and Yurlov, {I. S.} and Fominykh, {E. G.} and Ananchenko, {B. A.} and Rossikhina, {A. A.} and Murin, {I. V.}",
note = "Funding Information: ACKNOWLEDGMENTS This study was supported by the Russian Foundation for Basic Research, project no. 06-03-96353.",
year = "2007",
month = aug,
doi = "10.1134/S1087659607040116",
language = "English",
volume = "33",
pages = "369--378",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Transport properties of solid electrolytes based on MeSm2S 4

AU - Ushakova, Yu N.

AU - Kalinina, L. A.

AU - Yurlov, I. S.

AU - Fominykh, E. G.

AU - Ananchenko, B. A.

AU - Rossikhina, A. A.

AU - Murin, I. V.

N1 - Funding Information: ACKNOWLEDGMENTS This study was supported by the Russian Foundation for Basic Research, project no. 06-03-96353.

PY - 2007/8

Y1 - 2007/8

N2 - The solid-solution regions in the MeSm2S4-MeS and MeSm2S4-Sm2S3 (Me = Ca, Ba) systems are revealed. The average ion, cation, and anion transport number of the synthesized solid electrolytes xSm2S3[Ca(Ba)S] • (100 - x)Ca(Ba)Sm2S4 (x = 1-10 mol %) are determined by the electromotive force (emf) method with the use of concentration cells with and without transfer. In the phases under investigation, the ion transfer in the temperature range 673-723 K is provided by sulfide ions (tS2 = 1.00±0.02). The diffusion coefficients of S2- ions in the solid electrolytes are determined by potentiostatic chronoamperometry. A vacancy mechanism of defect formation is proposed. It is demonstrated that the transport characteristics of the solid electrolytes based on the CaSm 2S4 compound are worse than those of the solid electrolytes based on the BaSm2S4 compound.

AB - The solid-solution regions in the MeSm2S4-MeS and MeSm2S4-Sm2S3 (Me = Ca, Ba) systems are revealed. The average ion, cation, and anion transport number of the synthesized solid electrolytes xSm2S3[Ca(Ba)S] • (100 - x)Ca(Ba)Sm2S4 (x = 1-10 mol %) are determined by the electromotive force (emf) method with the use of concentration cells with and without transfer. In the phases under investigation, the ion transfer in the temperature range 673-723 K is provided by sulfide ions (tS2 = 1.00±0.02). The diffusion coefficients of S2- ions in the solid electrolytes are determined by potentiostatic chronoamperometry. A vacancy mechanism of defect formation is proposed. It is demonstrated that the transport characteristics of the solid electrolytes based on the CaSm 2S4 compound are worse than those of the solid electrolytes based on the BaSm2S4 compound.

UR - http://www.scopus.com/inward/record.url?scp=34548426846&partnerID=8YFLogxK

U2 - 10.1134/S1087659607040116

DO - 10.1134/S1087659607040116

M3 - Article

AN - SCOPUS:34548426846

VL - 33

SP - 369

EP - 378

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 4

ER -

ID: 87998958