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Transport of small molecules through polyphenylene oxide membranes modified by fullerene. / Polotskaya, G. A.; Penkova, A. V.; Toikka, A. M.; Pientka, Z.; Brozova, L.; Bleha, M.

In: Separation Science and Technology, Vol. 42, No. 2, 01.01.2007, p. 333-347.

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Polotskaya, G. A. ; Penkova, A. V. ; Toikka, A. M. ; Pientka, Z. ; Brozova, L. ; Bleha, M. / Transport of small molecules through polyphenylene oxide membranes modified by fullerene. In: Separation Science and Technology. 2007 ; Vol. 42, No. 2. pp. 333-347.

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@article{d1067a8e70d1471faec312bcb5310776,
title = "Transport of small molecules through polyphenylene oxide membranes modified by fullerene",
abstract = "Homogeneous membranes based on fullerene-polyphenylene oxide compositions containing up to 2 wt% fullerene C60 were prepared. The effect of fullerene addition on PPO transport properties was studied in gas separation and pervaporation processes. Permeability coefficients of H2, O2, N2, CH4, and CO2 were measured; a correlation between gas transport properties and membrane free volume was established. Pervaporation properties were studied for the system with ethyl acetate synthesis reaction: quaternary system ethanol - acetic acid - water - ethyl acetate and some constituent binary and ternary mixtures. Pervaporation in binary systems, ethanol-water and ethyl acetate-water was considered with the use of the data on sorption capacities and interaction parameters. In pervaporation of a quaternary reacting mixture, the permeate containing essentially ethyl acetate was obtained. Results show that membranes with fullerene additives exhibit improved transport properties.",
keywords = "Fullerene, Gas separation, Homogeneous membranes, Pervaporation, Polyphenylene oxide",
author = "Polotskaya, {G. A.} and Penkova, {A. V.} and Toikka, {A. M.} and Z. Pientka and L. Brozova and M. Bleha",
year = "2007",
month = jan,
day = "1",
doi = "10.1080/01496390600997963",
language = "English",
volume = "42",
pages = "333--347",
journal = "Separation Science and Technology",
issn = "0149-6395",
publisher = "Taylor & Francis",
number = "2",

}

RIS

TY - JOUR

T1 - Transport of small molecules through polyphenylene oxide membranes modified by fullerene

AU - Polotskaya, G. A.

AU - Penkova, A. V.

AU - Toikka, A. M.

AU - Pientka, Z.

AU - Brozova, L.

AU - Bleha, M.

PY - 2007/1/1

Y1 - 2007/1/1

N2 - Homogeneous membranes based on fullerene-polyphenylene oxide compositions containing up to 2 wt% fullerene C60 were prepared. The effect of fullerene addition on PPO transport properties was studied in gas separation and pervaporation processes. Permeability coefficients of H2, O2, N2, CH4, and CO2 were measured; a correlation between gas transport properties and membrane free volume was established. Pervaporation properties were studied for the system with ethyl acetate synthesis reaction: quaternary system ethanol - acetic acid - water - ethyl acetate and some constituent binary and ternary mixtures. Pervaporation in binary systems, ethanol-water and ethyl acetate-water was considered with the use of the data on sorption capacities and interaction parameters. In pervaporation of a quaternary reacting mixture, the permeate containing essentially ethyl acetate was obtained. Results show that membranes with fullerene additives exhibit improved transport properties.

AB - Homogeneous membranes based on fullerene-polyphenylene oxide compositions containing up to 2 wt% fullerene C60 were prepared. The effect of fullerene addition on PPO transport properties was studied in gas separation and pervaporation processes. Permeability coefficients of H2, O2, N2, CH4, and CO2 were measured; a correlation between gas transport properties and membrane free volume was established. Pervaporation properties were studied for the system with ethyl acetate synthesis reaction: quaternary system ethanol - acetic acid - water - ethyl acetate and some constituent binary and ternary mixtures. Pervaporation in binary systems, ethanol-water and ethyl acetate-water was considered with the use of the data on sorption capacities and interaction parameters. In pervaporation of a quaternary reacting mixture, the permeate containing essentially ethyl acetate was obtained. Results show that membranes with fullerene additives exhibit improved transport properties.

KW - Fullerene

KW - Gas separation

KW - Homogeneous membranes

KW - Pervaporation

KW - Polyphenylene oxide

UR - http://www.scopus.com/inward/record.url?scp=33847082877&partnerID=8YFLogxK

U2 - 10.1080/01496390600997963

DO - 10.1080/01496390600997963

M3 - Article

AN - SCOPUS:33847082877

VL - 42

SP - 333

EP - 347

JO - Separation Science and Technology

JF - Separation Science and Technology

SN - 0149-6395

IS - 2

ER -

ID: 50076101