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Transformation of the Crystal Structure in the Series of K1xCsxBSi2O6 Borosilicate Solid Solutions. / Derkacheva, E. S.; Krzhizhanovskaya, M. G.; Bubnova, R. S.; Filatov, S. K.

In: Glass Physics and Chemistry, Vol. 37, No. 5, 2011, p. 572-578.

Research output: Contribution to journal › Article

Harvard

Derkacheva, ES, Krzhizhanovskaya, MG, Bubnova, RS & Filatov, SK 2011, 'Transformation of the Crystal Structure in the Series of K1xCsxBSi2O6 Borosilicate Solid Solutions', Glass Physics and Chemistry, vol. 37, no. 5, pp. 572-578. https://doi.org/DOI: 10.1134/S108765961105004X

APA

Derkacheva, E. S., Krzhizhanovskaya, M. G., Bubnova, R. S., & Filatov, S. K. (2011). Transformation of the Crystal Structure in the Series of K1xCsxBSi2O6 Borosilicate Solid Solutions. Glass Physics and Chemistry, 37(5), 572-578. https://doi.org/DOI: 10.1134/S108765961105004X

Vancouver

Derkacheva ES, Krzhizhanovskaya MG, Bubnova RS, Filatov SK. Transformation of the Crystal Structure in the Series of K1xCsxBSi2O6 Borosilicate Solid Solutions. Glass Physics and Chemistry. 2011;37(5):572-578. https://doi.org/DOI: 10.1134/S108765961105004X

Author

Derkacheva, E. S. ; Krzhizhanovskaya, M. G. ; Bubnova, R. S. ; Filatov, S. K. / Transformation of the Crystal Structure in the Series of K1xCsxBSi2O6 Borosilicate Solid Solutions. In: Glass Physics and Chemistry. 2011 ; Vol. 37, No. 5. pp. 572-578.

BibTeX

@article{af2a2c2105234fedb585aadbfcb077a4,
title = "Transformation of the Crystal Structure in the Series of K1xCsxBSi2O6 Borosilicate Solid Solutions",
abstract = "The transformation of the crystal structure by isomorphous K+–Cs+ substitutions in the non-tetra- hedral positions leading to the phase transition has been studied in the series of K1–xCsxBSi2O6 solid solutions. The samples have been crystallized from the glass at 850C for 10 h. According to the data on the crystal structures refined by the Rietveld method, the compositions with 0 x 0.35 crystallize in space group I3d, structural type KBSi2O6, and those with 0.37 x 1.0, crystallize in Iad, structural type CsBSi2O6. The reversible cubic–cubic phase transition I3d Iad occurs in the composition range x= 0.35–0.37.",
keywords = "crystal structure, phase transition, solid solutions, Rietveld method, borosilicates",
author = "Derkacheva, {E. S.} and Krzhizhanovskaya, {M. G.} and Bubnova, {R. S.} and Filatov, {S. K.}",
year = "2011",
doi = "DOI: 10.1134/S108765961105004X",
language = "не определен",
volume = "37",
pages = "572--578",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "5",

}

RIS

TY - JOUR

T1 - Transformation of the Crystal Structure in the Series of K1xCsxBSi2O6 Borosilicate Solid Solutions

AU - Derkacheva, E. S.

AU - Krzhizhanovskaya, M. G.

AU - Bubnova, R. S.

AU - Filatov, S. K.

PY - 2011

Y1 - 2011

N2 - The transformation of the crystal structure by isomorphous K+–Cs+ substitutions in the non-tetra- hedral positions leading to the phase transition has been studied in the series of K1–xCsxBSi2O6 solid solutions. The samples have been crystallized from the glass at 850C for 10 h. According to the data on the crystal structures refined by the Rietveld method, the compositions with 0 x 0.35 crystallize in space group I3d, structural type KBSi2O6, and those with 0.37 x 1.0, crystallize in Iad, structural type CsBSi2O6. The reversible cubic–cubic phase transition I3d Iad occurs in the composition range x= 0.35–0.37.

AB - The transformation of the crystal structure by isomorphous K+–Cs+ substitutions in the non-tetra- hedral positions leading to the phase transition has been studied in the series of K1–xCsxBSi2O6 solid solutions. The samples have been crystallized from the glass at 850C for 10 h. According to the data on the crystal structures refined by the Rietveld method, the compositions with 0 x 0.35 crystallize in space group I3d, structural type KBSi2O6, and those with 0.37 x 1.0, crystallize in Iad, structural type CsBSi2O6. The reversible cubic–cubic phase transition I3d Iad occurs in the composition range x= 0.35–0.37.

KW - crystal structure

KW - phase transition

KW - solid solutions

KW - Rietveld method

KW - borosilicates

U2 - DOI: 10.1134/S108765961105004X

DO - DOI: 10.1134/S108765961105004X

M3 - статья

VL - 37

SP - 572

EP - 578

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 5

ER -

ID: 5177084