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Thermodynamic properties of the Lu2O3-ZrO2 solid solutions by Knudsen effusion mass spectrometry at high temperature. / Lopatin, S.I.; Shugurov, S.M.

In: Journal of Chemical Thermodynamics, Vol. 72, No. 5, 2014, p. 85-88.

Research output: Contribution to journal › Article

Harvard

Lopatin, SI & Shugurov, SM 2014, 'Thermodynamic properties of the Lu2O3-ZrO2 solid solutions by Knudsen effusion mass spectrometry at high temperature', Journal of Chemical Thermodynamics, vol. 72, no. 5, pp. 85-88. https://doi.org/dx.doi.org./10.1016/j.jct.201.01.014, https://doi.org/10.1016/j.jct.2014.01.014

APA

Lopatin, S. I., & Shugurov, S. M. (2014). Thermodynamic properties of the Lu2O3-ZrO2 solid solutions by Knudsen effusion mass spectrometry at high temperature. Journal of Chemical Thermodynamics, 72(5), 85-88. https://doi.org/dx.doi.org./10.1016/j.jct.201.01.014, https://doi.org/10.1016/j.jct.2014.01.014

Vancouver

Lopatin SI, Shugurov SM. Thermodynamic properties of the Lu2O3-ZrO2 solid solutions by Knudsen effusion mass spectrometry at high temperature. Journal of Chemical Thermodynamics. 2014;72(5):85-88. https://doi.org/dx.doi.org./10.1016/j.jct.201.01.014, https://doi.org/10.1016/j.jct.2014.01.014

Author

Lopatin, S.I. ; Shugurov, S.M. / Thermodynamic properties of the Lu2O3-ZrO2 solid solutions by Knudsen effusion mass spectrometry at high temperature. In: Journal of Chemical Thermodynamics. 2014 ; Vol. 72, No. 5. pp. 85-88.

BibTeX

@article{a1ab1dc995944c38b40121c53e54daf7,
title = "Thermodynamic properties of the Lu2O3-ZrO2 solid solutions by Knudsen effusion mass spectrometry at high temperature",
abstract = "The zirconium oxide based ceramics with addition of rare-earth metal oxides is widely used for production of high temperature materials. Knudsen effusion mass spectrometry was used to study vaporization processes and thermodynamic properties of solid solutions in the ZrO2-Lu2O3 system at the temperature 2700 K. The Lu, LuO, ZrO and ZrO2 were found as the main vapor species over the samples studied. The ZrO2 and Lu2O3 activities, the Gibbs free energy of formation, the excess Gibbs free energy of formation in the samples studied were calculated. The activities of lutetium oxide in all concentration range of condensed phase have low negative deviation from ideal case whereas zirconium dioxide activities have strong negative deviation from ideal case. {\textcopyright} 2014 Elsevier Ltd. All rights reserved.",
author = "S.I. Lopatin and S.M. Shugurov",
year = "2014",
doi = "dx.doi.org./10.1016/j.jct.201.01.014",
language = "English",
volume = "72",
pages = "85--88",
journal = "Journal of Chemical Thermodynamics",
issn = "0021-9614",
publisher = "Elsevier",
number = "5",

}

RIS

TY - JOUR

T1 - Thermodynamic properties of the Lu2O3-ZrO2 solid solutions by Knudsen effusion mass spectrometry at high temperature

AU - Lopatin, S.I.

AU - Shugurov, S.M.

PY - 2014

Y1 - 2014

N2 - The zirconium oxide based ceramics with addition of rare-earth metal oxides is widely used for production of high temperature materials. Knudsen effusion mass spectrometry was used to study vaporization processes and thermodynamic properties of solid solutions in the ZrO2-Lu2O3 system at the temperature 2700 K. The Lu, LuO, ZrO and ZrO2 were found as the main vapor species over the samples studied. The ZrO2 and Lu2O3 activities, the Gibbs free energy of formation, the excess Gibbs free energy of formation in the samples studied were calculated. The activities of lutetium oxide in all concentration range of condensed phase have low negative deviation from ideal case whereas zirconium dioxide activities have strong negative deviation from ideal case. © 2014 Elsevier Ltd. All rights reserved.

AB - The zirconium oxide based ceramics with addition of rare-earth metal oxides is widely used for production of high temperature materials. Knudsen effusion mass spectrometry was used to study vaporization processes and thermodynamic properties of solid solutions in the ZrO2-Lu2O3 system at the temperature 2700 K. The Lu, LuO, ZrO and ZrO2 were found as the main vapor species over the samples studied. The ZrO2 and Lu2O3 activities, the Gibbs free energy of formation, the excess Gibbs free energy of formation in the samples studied were calculated. The activities of lutetium oxide in all concentration range of condensed phase have low negative deviation from ideal case whereas zirconium dioxide activities have strong negative deviation from ideal case. © 2014 Elsevier Ltd. All rights reserved.

U2 - dx.doi.org./10.1016/j.jct.201.01.014

DO - dx.doi.org./10.1016/j.jct.201.01.014

M3 - Article

VL - 72

SP - 85

EP - 88

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

SN - 0021-9614

IS - 5

ER -

ID: 5689479