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Thermodynamic properties of the gaseous gallium molybdates and tungstates. / Lopatin, S. I.; Shugurov, S. M.; Gunina, A. O.

In: Journal of Physical Chemistry A, Vol. 113, No. 48, 01.12.2009, p. 13469-13474.

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Lopatin, SI, Shugurov, SM & Gunina, AO 2009, 'Thermodynamic properties of the gaseous gallium molybdates and tungstates', Journal of Physical Chemistry A, vol. 113, no. 48, pp. 13469-13474. https://doi.org/10.1021/jp903619g

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Lopatin, S. I. ; Shugurov, S. M. ; Gunina, A. O. / Thermodynamic properties of the gaseous gallium molybdates and tungstates. In: Journal of Physical Chemistry A. 2009 ; Vol. 113, No. 48. pp. 13469-13474.

BibTeX

@article{7089d6c21fc54f67a861f91dffda1e81,
title = "Thermodynamic properties of the gaseous gallium molybdates and tungstates",
abstract = "A number of gaseous oxyacid salts have been identified by Knudsen effusion mass spectrometry by vaporizing Ga2O3 from molybdenum and tungsten cells. The stability of gaseous molecules Ga2MoO 4, Ga2WO4, Ga2Mo2O7, and Ga2W2O7 was deduced from the measurements. The structures and molecular parameters of all salts investigated were obtained using quantum chemical calculations. On the basis of equilibrium constants measured for gas-phase reactions, the standard formation enthalpies were determined to be-827 ± 26,-843 ± 26,-1578 ± 32, and-1525 ± 34 kJ · mol-1 for Ga2MoO4, Ga2 WO2, Ga2 Mo2O7, and Ga2W2O7, respectively.",
author = "Lopatin, {S. I.} and Shugurov, {S. M.} and Gunina, {A. O.}",
year = "2009",
month = dec,
day = "1",
doi = "10.1021/jp903619g",
language = "English",
volume = "113",
pages = "13469--13474",
journal = "Journal of Physical Chemistry B",
issn = "1520-6106",
publisher = "American Chemical Society",
number = "48",

}

RIS

TY - JOUR

T1 - Thermodynamic properties of the gaseous gallium molybdates and tungstates

AU - Lopatin, S. I.

AU - Shugurov, S. M.

AU - Gunina, A. O.

PY - 2009/12/1

Y1 - 2009/12/1

N2 - A number of gaseous oxyacid salts have been identified by Knudsen effusion mass spectrometry by vaporizing Ga2O3 from molybdenum and tungsten cells. The stability of gaseous molecules Ga2MoO 4, Ga2WO4, Ga2Mo2O7, and Ga2W2O7 was deduced from the measurements. The structures and molecular parameters of all salts investigated were obtained using quantum chemical calculations. On the basis of equilibrium constants measured for gas-phase reactions, the standard formation enthalpies were determined to be-827 ± 26,-843 ± 26,-1578 ± 32, and-1525 ± 34 kJ · mol-1 for Ga2MoO4, Ga2 WO2, Ga2 Mo2O7, and Ga2W2O7, respectively.

AB - A number of gaseous oxyacid salts have been identified by Knudsen effusion mass spectrometry by vaporizing Ga2O3 from molybdenum and tungsten cells. The stability of gaseous molecules Ga2MoO 4, Ga2WO4, Ga2Mo2O7, and Ga2W2O7 was deduced from the measurements. The structures and molecular parameters of all salts investigated were obtained using quantum chemical calculations. On the basis of equilibrium constants measured for gas-phase reactions, the standard formation enthalpies were determined to be-827 ± 26,-843 ± 26,-1578 ± 32, and-1525 ± 34 kJ · mol-1 for Ga2MoO4, Ga2 WO2, Ga2 Mo2O7, and Ga2W2O7, respectively.

UR - http://www.scopus.com/inward/record.url?scp=72949110042&partnerID=8YFLogxK

U2 - 10.1021/jp903619g

DO - 10.1021/jp903619g

M3 - Article

C2 - 19831372

AN - SCOPUS:72949110042

VL - 113

SP - 13469

EP - 13474

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

SN - 1520-6106

IS - 48

ER -

ID: 40340898