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Thermodynamic properties of the Cs2O—Al2O3—SiO2 system at high temperatures. / Stolyarova, V.L.; Shilov, A.L.; Lopatin, S.I.; Fedorova, A.V.; Vorozhtcov, V.A.

In: Russian Chemical Bulletin, Vol. 73, No. 11, 2024, p. 3204-3214.

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Stolyarova, V.L. ; Shilov, A.L. ; Lopatin, S.I. ; Fedorova, A.V. ; Vorozhtcov, V.A. / Thermodynamic properties of the Cs2O—Al2O3—SiO2 system at high temperatures. In: Russian Chemical Bulletin. 2024 ; Vol. 73, No. 11. pp. 3204-3214.

BibTeX

@article{f0eb80024443405a8113f042015728b2,
title = "Thermodynamic properties of the Cs2O—Al2O3—SiO2 system at high temperatures",
abstract = "Evaporation processes and thermodynamic properties were for the first time investigated using the Knudsen effusion mass spectrometric method for ceramics based on the Cs2O—Al2O3—SiO2 system within the temperature range of 1000–1200 K. The found values of partial pressures of vapor species, activities of components, and Gibbs energy indicated negative deviations of the thermodynamic properties from the model of ideal solution. The obtained experimental values of thermodynamic properties were optimized using the generalized lattice theory of the associated solutions. {\textcopyright} 2025 Elsevier B.V., All rights reserved.",
keywords = "cesium oxide, high-temperature mass spectrometry, modeling, thermodynamic properties",
author = "V.L. Stolyarova and A.L. Shilov and S.I. Lopatin and A.V. Fedorova and V.A. Vorozhtcov",
note = "Export Date: 01 November 2025; Cited By: 3; Correspondence Address: V.A. Vorozhtcov; St. Petersburg State University, St. Petersburg, 7–9 Universitetskaya nab., 199034, Russian Federation; email: v.vorozhcov@rambler.ru; CODEN: RCBUE",
year = "2024",
doi = "10.1007/s11172-024-4436-y",
language = "Английский",
volume = "73",
pages = "3204--3214",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "11",

}

RIS

TY - JOUR

T1 - Thermodynamic properties of the Cs2O—Al2O3—SiO2 system at high temperatures

AU - Stolyarova, V.L.

AU - Shilov, A.L.

AU - Lopatin, S.I.

AU - Fedorova, A.V.

AU - Vorozhtcov, V.A.

N1 - Export Date: 01 November 2025; Cited By: 3; Correspondence Address: V.A. Vorozhtcov; St. Petersburg State University, St. Petersburg, 7–9 Universitetskaya nab., 199034, Russian Federation; email: v.vorozhcov@rambler.ru; CODEN: RCBUE

PY - 2024

Y1 - 2024

N2 - Evaporation processes and thermodynamic properties were for the first time investigated using the Knudsen effusion mass spectrometric method for ceramics based on the Cs2O—Al2O3—SiO2 system within the temperature range of 1000–1200 K. The found values of partial pressures of vapor species, activities of components, and Gibbs energy indicated negative deviations of the thermodynamic properties from the model of ideal solution. The obtained experimental values of thermodynamic properties were optimized using the generalized lattice theory of the associated solutions. © 2025 Elsevier B.V., All rights reserved.

AB - Evaporation processes and thermodynamic properties were for the first time investigated using the Knudsen effusion mass spectrometric method for ceramics based on the Cs2O—Al2O3—SiO2 system within the temperature range of 1000–1200 K. The found values of partial pressures of vapor species, activities of components, and Gibbs energy indicated negative deviations of the thermodynamic properties from the model of ideal solution. The obtained experimental values of thermodynamic properties were optimized using the generalized lattice theory of the associated solutions. © 2025 Elsevier B.V., All rights reserved.

KW - cesium oxide

KW - high-temperature mass spectrometry

KW - modeling

KW - thermodynamic properties

U2 - 10.1007/s11172-024-4436-y

DO - 10.1007/s11172-024-4436-y

M3 - статья

VL - 73

SP - 3204

EP - 3214

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 11

ER -

ID: 143412835