Research output: Contribution to journal › Article › peer-review
Thermodynamic Potentials of Solid-State Systems. / Русанов, Анатолий Иванович.
In: Russian Journal of General Chemistry, Vol. 94, No. suppl 1, 14.01.2024, p. S157-S164.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Thermodynamic Potentials of Solid-State Systems
AU - Русанов, Анатолий Иванович
PY - 2024/1/14
Y1 - 2024/1/14
N2 - Abstract: By now, the thermodynamics of fluid systems is well developed, but many issues related to solids still require discussion. In this work, six characteristic functions of classical thermodynamics are investigated in application to solid-state systems: energy, free energy, Gibbs energy, enthalpy, grand thermodynamic potential, and a new characteristic function recently discovered by the author, called the J-potential. The need to introduce such a potential appears in the thermodynamics of solid-state or mixed systems subjected to complex mechanical impacts, and also in colloidal science. Definitions are given for all six functions, fundamental thermodynamic equations are derived, and the conditions under which this function assumes the status of a thermodynamic potential are established.
AB - Abstract: By now, the thermodynamics of fluid systems is well developed, but many issues related to solids still require discussion. In this work, six characteristic functions of classical thermodynamics are investigated in application to solid-state systems: energy, free energy, Gibbs energy, enthalpy, grand thermodynamic potential, and a new characteristic function recently discovered by the author, called the J-potential. The need to introduce such a potential appears in the thermodynamics of solid-state or mixed systems subjected to complex mechanical impacts, and also in colloidal science. Definitions are given for all six functions, fundamental thermodynamic equations are derived, and the conditions under which this function assumes the status of a thermodynamic potential are established.
KW - Gibbs energy
KW - J-potential
KW - energy
KW - enthalpy
KW - free energy
KW - grand thermodynamic potential
UR - https://www.mendeley.com/catalogue/b0990324-d895-3dc9-b1b2-e911a99df9d1/
U2 - 10.1134/s1070363224140160
DO - 10.1134/s1070363224140160
M3 - Article
VL - 94
SP - S157-S164
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - suppl 1
ER -
ID: 127185043