Research output: Contribution to journal › Article › peer-review
A relationship between the work of the aggregate formation and the equilibrium aggregate concentration is established with allowances made for the mobility of molecular aggregates in a solution of a colloidal nonionic surfactant. The relation between the intensities of emission and absorption of surfactant monomers by the aggregates is found. A kinetic equation of the formation of molecular aggregates is obtained. Conditions of aggregation/disaggregation processes are revealed. Kinetic substantiation of the irreversible tendency of a solution to the aggregation equilibrium is given.
Translated title of the contribution | Термодинамические и кинетические основы теории мицеллообразования. 1. Общие соотношения |
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Original language | English |
Pages (from-to) | 167-171 |
Number of pages | 5 |
Journal | Colloid Journal |
Volume | 62 |
Issue number | 2 |
State | Published - 1 Mar 2000 |
ID: 5113446