Standard

Thermodynamic and kinetic foundations of the theory of micellization : 2. Direct and reverse fluxes of molecular aggregates over the activation barrier of micellization. / Kuni, F. M.; Shchekin, A. K.; Grinin, A. P.; Rusanov, A. I.

In: Colloid Journal, Vol. 62, No. 2, 01.03.2000, p. 172-178.

Research output: Contribution to journalArticlepeer-review

Harvard

APA

Vancouver

Author

BibTeX

@article{972250ed9b3f4a9399366c2866963d2e,
title = "Thermodynamic and kinetic foundations of the theory of micellization: 2. Direct and reverse fluxes of molecular aggregates over the activation barrier of micellization",
abstract = "The conditions of the applicability of a macroscopic description of the kinetics of micellization in a solution of a nonionic surfactant are revealed. Quasi-equilibrium concentrations of molecular aggregates in precritical and supercritical ranges of their sizes are determined. The kinetic equation of the formation of molecular aggregates in the near-critical and micellar ranges of their sizes is derived. Boundary conditions for the equation are formulated. Direct and reverse overcoming of the activation barrier of micellization by the aggregates is described. Quasi-stationary aggregates fluxes over the activation barrier of micellization are found.",
author = "Kuni, {F. M.} and Shchekin, {A. K.} and Grinin, {A. P.} and Rusanov, {A. I.}",
year = "2000",
month = mar,
day = "1",
language = "English",
volume = "62",
pages = "172--178",
journal = "Colloid Journal",
issn = "1061-933X",
publisher = "Pleiades Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Thermodynamic and kinetic foundations of the theory of micellization

T2 - 2. Direct and reverse fluxes of molecular aggregates over the activation barrier of micellization

AU - Kuni, F. M.

AU - Shchekin, A. K.

AU - Grinin, A. P.

AU - Rusanov, A. I.

PY - 2000/3/1

Y1 - 2000/3/1

N2 - The conditions of the applicability of a macroscopic description of the kinetics of micellization in a solution of a nonionic surfactant are revealed. Quasi-equilibrium concentrations of molecular aggregates in precritical and supercritical ranges of their sizes are determined. The kinetic equation of the formation of molecular aggregates in the near-critical and micellar ranges of their sizes is derived. Boundary conditions for the equation are formulated. Direct and reverse overcoming of the activation barrier of micellization by the aggregates is described. Quasi-stationary aggregates fluxes over the activation barrier of micellization are found.

AB - The conditions of the applicability of a macroscopic description of the kinetics of micellization in a solution of a nonionic surfactant are revealed. Quasi-equilibrium concentrations of molecular aggregates in precritical and supercritical ranges of their sizes are determined. The kinetic equation of the formation of molecular aggregates in the near-critical and micellar ranges of their sizes is derived. Boundary conditions for the equation are formulated. Direct and reverse overcoming of the activation barrier of micellization by the aggregates is described. Quasi-stationary aggregates fluxes over the activation barrier of micellization are found.

UR - http://www.scopus.com/inward/record.url?scp=0034158596&partnerID=8YFLogxK

M3 - Article

VL - 62

SP - 172

EP - 178

JO - Colloid Journal

JF - Colloid Journal

SN - 1061-933X

IS - 2

ER -

ID: 5113408