Research output: Contribution to journal › Article › peer-review
Thermodynamic and kinetic foundations of the micellization theory. 3. Initial stages of micellization. / Kuni, F. M.; Grinin, A. P.; Shchekin, A. K.; Rusanov, A. I.
In: Colloid Journal, Vol. 62, No. 4, 01.07.2000, p. 451-456.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Thermodynamic and kinetic foundations of the micellization theory. 3. Initial stages of micellization
AU - Kuni, F. M.
AU - Grinin, A. P.
AU - Shchekin, A. K.
AU - Rusanov, A. I.
PY - 2000/7/1
Y1 - 2000/7/1
N2 - The kinetics of the initial stages of micellization was considered for the solution of a nonionic colloidal surfactant. Quasi-equilibrium concentrations of molecular surfactant aggregates in subcritical and over-critical regions of their sizes, as well as the quasi-steady-state concentration of molecular surfactant aggregates in the near-critical region of their sizes, are established at these stages. The average time between two successive acts of emission of a surfactant monomer by a micelle, the average resident time of a monomer in a micelle, and the average micelle lifetime were treated from a statistical point of view.
AB - The kinetics of the initial stages of micellization was considered for the solution of a nonionic colloidal surfactant. Quasi-equilibrium concentrations of molecular surfactant aggregates in subcritical and over-critical regions of their sizes, as well as the quasi-steady-state concentration of molecular surfactant aggregates in the near-critical region of their sizes, are established at these stages. The average time between two successive acts of emission of a surfactant monomer by a micelle, the average resident time of a monomer in a micelle, and the average micelle lifetime were treated from a statistical point of view.
UR - http://www.scopus.com/inward/record.url?scp=0034232838&partnerID=8YFLogxK
M3 - Article
VL - 62
SP - 451
EP - 456
JO - Colloid Journal
JF - Colloid Journal
SN - 1061-933X
IS - 4
ER -
ID: 5113377