Research output: Contribution to journal › Article › peer-review
Thermodynamic Analysis of Chemical Hydrogen Storage: Energetics of Liquid Organic Hydrogen Carrier Systems Based on Methyl-Substituted Indoles. / Vostrikov, Sergey V.; Samarov, Artemiy A.; Turovtsev, Vladimir V.; Wasserscheid, Peter; Müller, Karsten; Verevkin, Sergey P.
In: Materials, Vol. 16, No. 7, 2924, 06.04.2023.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Thermodynamic Analysis of Chemical Hydrogen Storage: Energetics of Liquid Organic Hydrogen Carrier Systems Based on Methyl-Substituted Indoles
AU - Vostrikov, Sergey V.
AU - Samarov, Artemiy A.
AU - Turovtsev, Vladimir V.
AU - Wasserscheid, Peter
AU - Müller, Karsten
AU - Verevkin, Sergey P.
N1 - Vostrikov, S.V.; Samarov, A.A.; Turovtsev, V.V.; Wasserscheid, P.; Müller, K.; Verevkin, S.P. Thermodynamic Analysis of Chemical Hydrogen Storage: Energetics of Liquid Organic Hydrogen Carrier Systems Based on Methyl-Substituted Indoles. Materials 2023, 16, 2924. https://doi.org/10.3390/ma16072924
PY - 2023/4/6
Y1 - 2023/4/6
N2 - Liquid organic hydrogen carriers can store hydrogen in a safe and dense form through covalent bonds. Hydrogen uptake and release are realized by catalytic hydrogenation and dehydrogenation, respectively. Indoles have been demonstrated to be interesting candidates for this task. The enthalpy of reaction is a crucial parameter in this regard as it determines not only the heat demand for hydrogen release, but also the reaction equilibrium at given conditions. In this work, a combination of experimental measurements, quantum chemical methods and a group-additivity approach has been applied to obtain a consistent dataset on the enthalpies of formation of different methylated indole derivatives and their hydrogenated counterparts. The results show a namable influence of the number and position of methyl groups on the enthalpy of reaction. The enthalpy of reaction of the overall hydrogenation reaction varies in the range of up to 18.2 kJ·mol−1 (corresponding to 4.6 kJ·mol(H2)−1). The widest range of enthalpy of reaction data for different methyl indoles has been observed for the last step (hydrogenation for the last double bond in the five-membered ring). Here a difference of up to 7.3 kJ·mol(H2)−1 between the highest and the lowest value was found.
AB - Liquid organic hydrogen carriers can store hydrogen in a safe and dense form through covalent bonds. Hydrogen uptake and release are realized by catalytic hydrogenation and dehydrogenation, respectively. Indoles have been demonstrated to be interesting candidates for this task. The enthalpy of reaction is a crucial parameter in this regard as it determines not only the heat demand for hydrogen release, but also the reaction equilibrium at given conditions. In this work, a combination of experimental measurements, quantum chemical methods and a group-additivity approach has been applied to obtain a consistent dataset on the enthalpies of formation of different methylated indole derivatives and their hydrogenated counterparts. The results show a namable influence of the number and position of methyl groups on the enthalpy of reaction. The enthalpy of reaction of the overall hydrogenation reaction varies in the range of up to 18.2 kJ·mol−1 (corresponding to 4.6 kJ·mol(H2)−1). The widest range of enthalpy of reaction data for different methyl indoles has been observed for the last step (hydrogenation for the last double bond in the five-membered ring). Here a difference of up to 7.3 kJ·mol(H2)−1 between the highest and the lowest value was found.
KW - vapor pressure
KW - enthalpy of vaporization
KW - enthalpy of formation
KW - structure–property relationships
KW - quantum chemical calculations
UR - https://www.mendeley.com/catalogue/c199a253-44b5-3e16-bda8-10d4a0ab94b7/
U2 - 10.3390/ma16072924
DO - 10.3390/ma16072924
M3 - Article
C2 - 37049216
VL - 16
JO - Materials
JF - Materials
SN - 1996-1944
IS - 7
M1 - 2924
ER -
ID: 104252300