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Thermochemistry of hydrogen bonding of ethers with aliphatic alcohols. / Rakipov, Ilnaz T.; Semenov, Konstantin N.; Petrov, Artem A.; Akhmadiyarov, Aydar A.; Khachatrian, Artashes A.; Gainutdinova, Aliya Z.; Varfolomeev, Mikhail A.

In: Thermochimica Acta, Vol. 711, 179203, 05.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Rakipov, IT, Semenov, KN, Petrov, AA, Akhmadiyarov, AA, Khachatrian, AA, Gainutdinova, AZ & Varfolomeev, MA 2022, 'Thermochemistry of hydrogen bonding of ethers with aliphatic alcohols', Thermochimica Acta, vol. 711, 179203. https://doi.org/10.1016/j.tca.2022.179203

APA

Rakipov, I. T., Semenov, K. N., Petrov, A. A., Akhmadiyarov, A. A., Khachatrian, A. A., Gainutdinova, A. Z., & Varfolomeev, M. A. (2022). Thermochemistry of hydrogen bonding of ethers with aliphatic alcohols. Thermochimica Acta, 711, [179203]. https://doi.org/10.1016/j.tca.2022.179203

Vancouver

Rakipov IT, Semenov KN, Petrov AA, Akhmadiyarov AA, Khachatrian AA, Gainutdinova AZ et al. Thermochemistry of hydrogen bonding of ethers with aliphatic alcohols. Thermochimica Acta. 2022 May;711. 179203. https://doi.org/10.1016/j.tca.2022.179203

Author

Rakipov, Ilnaz T. ; Semenov, Konstantin N. ; Petrov, Artem A. ; Akhmadiyarov, Aydar A. ; Khachatrian, Artashes A. ; Gainutdinova, Aliya Z. ; Varfolomeev, Mikhail A. / Thermochemistry of hydrogen bonding of ethers with aliphatic alcohols. In: Thermochimica Acta. 2022 ; Vol. 711.

BibTeX

@article{f3f1a3c2b41b4dec8647064183ed4cbe,
title = "Thermochemistry of hydrogen bonding of ethers with aliphatic alcohols",
abstract = "In present work an enthalpies of solution at infinite dilution and solvation of ethers (diethyl ether, diglyme, 1,4-dioxane, 12-crown-4 and 15-crown-5) in aliphatic alcohols at 298.15 K and enthalpies of aliphatic alcohols, alkanes in ethers were determined. The enthalpies of hydrogen bonding for these systems were calculated using experimental data. The hydrogen bond enthalpies of ethers in alcohols are significantly lower by absolute values than the enthalpies of hydrogen bonding in the complexes 1:1 of alcohols in ethers solution due to reorganization effects of aliphatic alcohols as a solvent (breaking of solvent-solvent hydrogen bonds). The cooperative effects in multi-particle complexes of alcohols with ethers were evaluated taking into account reorganization effect.",
keywords = "aliphatic alcohols, enthalpies of solution, ethers, hydrogen bonding, reorganization, cooperativity",
author = "Rakipov, {Ilnaz T.} and Semenov, {Konstantin N.} and Petrov, {Artem A.} and Akhmadiyarov, {Aydar A.} and Khachatrian, {Artashes A.} and Gainutdinova, {Aliya Z.} and Varfolomeev, {Mikhail A.}",
note = "Publisher Copyright: {\textcopyright} 2022",
year = "2022",
month = may,
doi = "10.1016/j.tca.2022.179203",
language = "English",
volume = "711",
journal = "Thermochimica Acta",
issn = "0040-6031",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Thermochemistry of hydrogen bonding of ethers with aliphatic alcohols

AU - Rakipov, Ilnaz T.

AU - Semenov, Konstantin N.

AU - Petrov, Artem A.

AU - Akhmadiyarov, Aydar A.

AU - Khachatrian, Artashes A.

AU - Gainutdinova, Aliya Z.

AU - Varfolomeev, Mikhail A.

N1 - Publisher Copyright: © 2022

PY - 2022/5

Y1 - 2022/5

N2 - In present work an enthalpies of solution at infinite dilution and solvation of ethers (diethyl ether, diglyme, 1,4-dioxane, 12-crown-4 and 15-crown-5) in aliphatic alcohols at 298.15 K and enthalpies of aliphatic alcohols, alkanes in ethers were determined. The enthalpies of hydrogen bonding for these systems were calculated using experimental data. The hydrogen bond enthalpies of ethers in alcohols are significantly lower by absolute values than the enthalpies of hydrogen bonding in the complexes 1:1 of alcohols in ethers solution due to reorganization effects of aliphatic alcohols as a solvent (breaking of solvent-solvent hydrogen bonds). The cooperative effects in multi-particle complexes of alcohols with ethers were evaluated taking into account reorganization effect.

AB - In present work an enthalpies of solution at infinite dilution and solvation of ethers (diethyl ether, diglyme, 1,4-dioxane, 12-crown-4 and 15-crown-5) in aliphatic alcohols at 298.15 K and enthalpies of aliphatic alcohols, alkanes in ethers were determined. The enthalpies of hydrogen bonding for these systems were calculated using experimental data. The hydrogen bond enthalpies of ethers in alcohols are significantly lower by absolute values than the enthalpies of hydrogen bonding in the complexes 1:1 of alcohols in ethers solution due to reorganization effects of aliphatic alcohols as a solvent (breaking of solvent-solvent hydrogen bonds). The cooperative effects in multi-particle complexes of alcohols with ethers were evaluated taking into account reorganization effect.

KW - aliphatic alcohols

KW - enthalpies of solution

KW - ethers

KW - hydrogen bonding

KW - reorganization, cooperativity

UR - http://www.scopus.com/inward/record.url?scp=85127132713&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/1713997c-dbdf-3c98-b173-c77538c0a3f8/

U2 - 10.1016/j.tca.2022.179203

DO - 10.1016/j.tca.2022.179203

M3 - Article

AN - SCOPUS:85127132713

VL - 711

JO - Thermochimica Acta

JF - Thermochimica Acta

SN - 0040-6031

M1 - 179203

ER -

ID: 100131168