Research output: Contribution to journal › Article › peer-review
Thermal investigation of ammonioborite (NH4)3[B 15O20(OH)8] • 4H2O. / Anderson, J. E.; Bubnova, R. S.; Filatov, S. K.; Ugolkov, V. L.; Britvin, S. N.
In: Glass Physics and Chemistry, Vol. 35, No. 2, 01.04.2009, p. 191-198.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Thermal investigation of ammonioborite (NH4)3[B 15O20(OH)8] • 4H2O
AU - Anderson, J. E.
AU - Bubnova, R. S.
AU - Filatov, S. K.
AU - Ugolkov, V. L.
AU - Britvin, S. N.
PY - 2009/4/1
Y1 - 2009/4/1
N2 - The thermal behavior of ammonioborite (NH4)3[B 15O20(OH)8] • 4H2O is investigated using thermal X-ray diffraction, differential thermal analysis (DTA) in air and vacuum, and thermogravimetry. It is shown that the decomposition of the mineral (dehydration, dehydroxylation, deammoniation) proceeds in several stages, and the dehydration is accompanied by the amorphization. The thermal expansion of ammonioborite is sharply anisotropic. As in the case of other hydrous pentaborates, the thermal expansion is maximum in the direction in which pentaborate groups alternate with ammonium cations.
AB - The thermal behavior of ammonioborite (NH4)3[B 15O20(OH)8] • 4H2O is investigated using thermal X-ray diffraction, differential thermal analysis (DTA) in air and vacuum, and thermogravimetry. It is shown that the decomposition of the mineral (dehydration, dehydroxylation, deammoniation) proceeds in several stages, and the dehydration is accompanied by the amorphization. The thermal expansion of ammonioborite is sharply anisotropic. As in the case of other hydrous pentaborates, the thermal expansion is maximum in the direction in which pentaborate groups alternate with ammonium cations.
UR - http://www.scopus.com/inward/record.url?scp=66649118883&partnerID=8YFLogxK
U2 - 10.1134/S1087659609020114
DO - 10.1134/S1087659609020114
M3 - Article
AN - SCOPUS:66649118883
VL - 35
SP - 191
EP - 198
JO - Glass Physics and Chemistry
JF - Glass Physics and Chemistry
SN - 1087-6596
IS - 2
ER -
ID: 40648686