Thermal Expansion of a Synthetic Analog of Matteuccite NaHSO4·H2O and α-NaHSO4

Standard

Thermal Expansion of a Synthetic Analog of Matteuccite NaHSO4·H2O and α-NaHSO4. / Shablinskii, A. P.; Dmitrieva, N. V.; Bubnova, R. S.; Filatov, S. K.; Krzhizhanovskaya, M. G.; Ugolkov, V. L.

In: Glass Physics and Chemistry, Vol. 50, No. 2, 01.04.2024, p. 184-190.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{859a64928e5245a39b92474ba23f9bd5,

title = "Thermal Expansion of a Synthetic Analog of Matteuccite NaHSO4·H2O and α-NaHSO4",

abstract = "Abstract: The thermal behavior of aqueous sulfate NaHSO4·H2O and the product of its dehydration α‑NaHS-O4 is studied. The studies are carried out using high temperature X-ray diffraction and complex thermal analysis. Based on the data of three experiments, the temperature, nature, and sequence of phase transformations are established: NaHSO4·H2O(30–50°C) → α-NaHSO4(140–180°C) → Na2S2O7 + Na3H(SO4)2. With increasing temperature increasing in the NaHSO4·H2O structure hinge deformations occur at the level of a chain of NaO3(OH)(H2O)2 polyhedra. The anisotropy of thermal expansion is αmax/αmin = 1.9 for NaHSO-4·H2O and αmax/αmin = 1.3 for NaHSO4.",

keywords = "high temperature X-ray diffraction, phase transformations, sulfates, thermal expansion",

author = "Shablinskii, {A. P.} and Dmitrieva, {N. V.} and Bubnova, {R. S.} and Filatov, {S. K.} and Krzhizhanovskaya, {M. G.} and Ugolkov, {V. L.}",

year = "2024",

month = apr,

day = "1",

doi = "10.1134/s1087659624600297",

language = "English",

volume = "50",

pages = "184--190",

journal = "Glass Physics and Chemistry",

issn = "1087-6596",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "2",

}

RIS

TY - JOUR

T1 - Thermal Expansion of a Synthetic Analog of Matteuccite NaHSO4·H2O and α-NaHSO4

AU - Shablinskii, A. P.

AU - Dmitrieva, N. V.

AU - Bubnova, R. S.

AU - Filatov, S. K.

AU - Krzhizhanovskaya, M. G.

AU - Ugolkov, V. L.

PY - 2024/4/1

Y1 - 2024/4/1

N2 - Abstract: The thermal behavior of aqueous sulfate NaHSO4·H2O and the product of its dehydration α‑NaHS-O4 is studied. The studies are carried out using high temperature X-ray diffraction and complex thermal analysis. Based on the data of three experiments, the temperature, nature, and sequence of phase transformations are established: NaHSO4·H2O(30–50°C) → α-NaHSO4(140–180°C) → Na2S2O7 + Na3H(SO4)2. With increasing temperature increasing in the NaHSO4·H2O structure hinge deformations occur at the level of a chain of NaO3(OH)(H2O)2 polyhedra. The anisotropy of thermal expansion is αmax/αmin = 1.9 for NaHSO-4·H2O and αmax/αmin = 1.3 for NaHSO4.

AB - Abstract: The thermal behavior of aqueous sulfate NaHSO4·H2O and the product of its dehydration α‑NaHS-O4 is studied. The studies are carried out using high temperature X-ray diffraction and complex thermal analysis. Based on the data of three experiments, the temperature, nature, and sequence of phase transformations are established: NaHSO4·H2O(30–50°C) → α-NaHSO4(140–180°C) → Na2S2O7 + Na3H(SO4)2. With increasing temperature increasing in the NaHSO4·H2O structure hinge deformations occur at the level of a chain of NaO3(OH)(H2O)2 polyhedra. The anisotropy of thermal expansion is αmax/αmin = 1.9 for NaHSO-4·H2O and αmax/αmin = 1.3 for NaHSO4.

KW - high temperature X-ray diffraction

KW - phase transformations

KW - sulfates

KW - thermal expansion

UR - https://www.mendeley.com/catalogue/3d24413d-0ac6-3c78-8e4f-22c3855b5271/

U2 - 10.1134/s1087659624600297

DO - 10.1134/s1087659624600297

M3 - Article

VL - 50

SP - 184

EP - 190

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 2

ER -

ID: 126749952