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Thermal Decomposition of the Complex [tBu3PH][HB(C6F5)3]. / Астахов, Егор Александрович; Казаков, Игорь Владимирович.

In: Russian Journal of General Chemistry, Vol. 94, No. Suppl 1, 2024, p. S36-S39.

Research output: Contribution to journal › Article › peer-review

Harvard

Астахов, ЕА & Казаков, ИВ 2024, 'Thermal Decomposition of the Complex [tBu3PH][HB(C6F5)3]', Russian Journal of General Chemistry, vol. 94, no. Suppl 1, pp. S36-S39. https://doi.org/10.1134/s1070363224140056

APA

Астахов, Е. А., & Казаков, И. В. (2024). Thermal Decomposition of the Complex [tBu3PH][HB(C6F5)3]. Russian Journal of General Chemistry, 94(Suppl 1), S36-S39. https://doi.org/10.1134/s1070363224140056

Vancouver

Астахов ЕА, Казаков ИВ. Thermal Decomposition of the Complex [tBu3PH][HB(C6F5)3]. Russian Journal of General Chemistry. 2024;94(Suppl 1):S36-S39. https://doi.org/10.1134/s1070363224140056

Author

Астахов, Егор Александрович ; Казаков, Игорь Владимирович. / Thermal Decomposition of the Complex [tBu3PH][HB(C6F5)3]. In: Russian Journal of General Chemistry. 2024 ; Vol. 94, No. Suppl 1. pp. S36-S39.

BibTeX

@article{368035bf9387468a85b413ca6b1097f6,
title = "Thermal Decomposition of the Complex [tBu3PH][HB(C6F5)3]",
abstract = "Abstract: The thermal stability of the [tBu3PH][HB(C6F5)3] complex, which is a product of molecular hydrogen activation by the tBu3P·B(C6F5)3 frustrated Lewis pair (FLP), was studied using a static tensimetric method with a membrane null-manometer. It was found that heating [tBu3PH][HB(C6F5)3] to temperatures above 430 K is accompanied by thermal dissociation with passing into vapor of molecular hydrogen, pentafluorobenzene, and 2-methylpropene, as the main volatile products.",
keywords = "Тензиметрия, донорно-акцепторные комплексы, Frustrated Lewis Pairs (FLP), donor-acceptor complex, tensimetry, thermal decomposition, tris(pentafluorophenyl)boran",
author = "Астахов, {Егор Александрович} and Казаков, {Игорь Владимирович}",
year = "2024",
doi = "10.1134/s1070363224140056",
language = "English",
volume = "94",
pages = "S36--S39",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "Suppl 1",

}

RIS

TY - JOUR

T1 - Thermal Decomposition of the Complex [tBu3PH][HB(C6F5)3]

AU - Астахов, Егор Александрович

AU - Казаков, Игорь Владимирович

PY - 2024

Y1 - 2024

N2 - Abstract: The thermal stability of the [tBu3PH][HB(C6F5)3] complex, which is a product of molecular hydrogen activation by the tBu3P·B(C6F5)3 frustrated Lewis pair (FLP), was studied using a static tensimetric method with a membrane null-manometer. It was found that heating [tBu3PH][HB(C6F5)3] to temperatures above 430 K is accompanied by thermal dissociation with passing into vapor of molecular hydrogen, pentafluorobenzene, and 2-methylpropene, as the main volatile products.

AB - Abstract: The thermal stability of the [tBu3PH][HB(C6F5)3] complex, which is a product of molecular hydrogen activation by the tBu3P·B(C6F5)3 frustrated Lewis pair (FLP), was studied using a static tensimetric method with a membrane null-manometer. It was found that heating [tBu3PH][HB(C6F5)3] to temperatures above 430 K is accompanied by thermal dissociation with passing into vapor of molecular hydrogen, pentafluorobenzene, and 2-methylpropene, as the main volatile products.

KW - Тензиметрия, донорно-акцепторные комплексы

KW - Frustrated Lewis Pairs (FLP)

KW - donor-acceptor complex

KW - tensimetry

KW - thermal decomposition

KW - tris(pentafluorophenyl)boran

UR - https://www.mendeley.com/catalogue/f0864364-29ed-33ab-bc88-f5b4c63bee68/

U2 - 10.1134/s1070363224140056

DO - 10.1134/s1070363224140056

M3 - Article

VL - 94

SP - S36-S39

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - Suppl 1

ER -

ID: 121015771