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Thermal decomposition of donor-stabilized phosphinoborane PH2BH2NMe3: a tensimetry study. / Butlak, Alina V. ; Kazakov, Igor V. ; Stauber, Andreas; Hegen, Oliver; Scheer, Manfred; Pomogaeva, Anna V.; Timoshkin, Alexey Y. .

In: European Journal of Inorganic Chemistry, Vol. 2019, No. 35, 22.09.2019, p. 3885-3891.

Research output: Contribution to journal › Article › peer-review

Harvard

Butlak, AV, Kazakov, IV, Stauber, A, Hegen, O, Scheer, M, Pomogaeva, AV & Timoshkin, AY 2019, 'Thermal decomposition of donor-stabilized phosphinoborane PH2BH2NMe3: a tensimetry study', European Journal of Inorganic Chemistry, vol. 2019, no. 35, pp. 3885-3891. https://doi.org/10.1002/ejic.201900817

APA

Butlak, A. V., Kazakov, I. V., Stauber, A., Hegen, O., Scheer, M., Pomogaeva, A. V., & Timoshkin, A. Y. (2019). Thermal decomposition of donor-stabilized phosphinoborane PH2BH2NMe3: a tensimetry study. European Journal of Inorganic Chemistry, 2019(35), 3885-3891. https://doi.org/10.1002/ejic.201900817

Vancouver

Butlak AV, Kazakov IV, Stauber A, Hegen O, Scheer M, Pomogaeva AV et al. Thermal decomposition of donor-stabilized phosphinoborane PH2BH2NMe3: a tensimetry study. European Journal of Inorganic Chemistry. 2019 Sep 22;2019(35):3885-3891. https://doi.org/10.1002/ejic.201900817

Author

Butlak, Alina V. ; Kazakov, Igor V. ; Stauber, Andreas ; Hegen, Oliver ; Scheer, Manfred ; Pomogaeva, Anna V. ; Timoshkin, Alexey Y. . / Thermal decomposition of donor-stabilized phosphinoborane PH2BH2NMe3: a tensimetry study. In: European Journal of Inorganic Chemistry. 2019 ; Vol. 2019, No. 35. pp. 3885-3891.

BibTeX

@article{6a1e530cb57841ce9cb380569041a539,
title = "Thermal decomposition of donor-stabilized phosphinoborane PH2BH2NMe3: a tensimetry study",
abstract = "The thermal decomposition of PH2BH2·NMe3 (1) in closed system was studied by static tensimetry with membrane null‐manometer. Compound 1 is unstable already at room temperature and partially decomposes with the release of gaseous trimethylamine and nonvolatile polymeric material. Storage of 1 at 311 K for 53 days results in evolution of small amounts of hydrogen and phosphine. At temperatures up to 329 K, PH3 evolution and BH3NMe3 adduct formation is observed after 3 days, and above 387 K, considerable amount of hydrogen gas is released. The data obtained indicate that the pyrolysis of 1 in the closed system may result in the enrichment of the condensed phase with boron due to phosphine loss.",
keywords = "Phosphorus, Boron, Hydrides, Thermolysis, Tensimetry, PHOSPHORUS-BORON BONDS, MOLECULAR-STRUCTURE, CATALYZED FORMATION, CRYSTAL-STRUCTURE, BORANE ADDUCTS, LEWIS, CHAINS, ROUTE, POLY(PHOSPHINOBORANES), PHOSPHANYLBORANES",
author = "Butlak, {Alina V.} and Kazakov, {Igor V.} and Andreas Stauber and Oliver Hegen and Manfred Scheer and Pomogaeva, {Anna V.} and Timoshkin, {Alexey Y.}",
year = "2019",
month = sep,
day = "22",
doi = "10.1002/ejic.201900817",
language = "English",
volume = "2019",
pages = "3885--3891",
journal = "Berichte der deutschen chemischen Gesellschaft",
issn = "0365-9496",
publisher = "Wiley-Blackwell",
number = "35",

}

RIS

TY - JOUR

T1 - Thermal decomposition of donor-stabilized phosphinoborane PH2BH2NMe3: a tensimetry study

AU - Butlak, Alina V.

AU - Kazakov, Igor V.

AU - Stauber, Andreas

AU - Hegen, Oliver

AU - Scheer, Manfred

AU - Pomogaeva, Anna V.

AU - Timoshkin, Alexey Y.

PY - 2019/9/22

Y1 - 2019/9/22

N2 - The thermal decomposition of PH2BH2·NMe3 (1) in closed system was studied by static tensimetry with membrane null‐manometer. Compound 1 is unstable already at room temperature and partially decomposes with the release of gaseous trimethylamine and nonvolatile polymeric material. Storage of 1 at 311 K for 53 days results in evolution of small amounts of hydrogen and phosphine. At temperatures up to 329 K, PH3 evolution and BH3NMe3 adduct formation is observed after 3 days, and above 387 K, considerable amount of hydrogen gas is released. The data obtained indicate that the pyrolysis of 1 in the closed system may result in the enrichment of the condensed phase with boron due to phosphine loss.

AB - The thermal decomposition of PH2BH2·NMe3 (1) in closed system was studied by static tensimetry with membrane null‐manometer. Compound 1 is unstable already at room temperature and partially decomposes with the release of gaseous trimethylamine and nonvolatile polymeric material. Storage of 1 at 311 K for 53 days results in evolution of small amounts of hydrogen and phosphine. At temperatures up to 329 K, PH3 evolution and BH3NMe3 adduct formation is observed after 3 days, and above 387 K, considerable amount of hydrogen gas is released. The data obtained indicate that the pyrolysis of 1 in the closed system may result in the enrichment of the condensed phase with boron due to phosphine loss.

KW - Phosphorus

KW - Boron

KW - Hydrides

KW - Thermolysis

KW - Tensimetry

KW - PHOSPHORUS-BORON BONDS

KW - MOLECULAR-STRUCTURE

KW - CATALYZED FORMATION

KW - CRYSTAL-STRUCTURE

KW - BORANE ADDUCTS

KW - LEWIS

KW - CHAINS

KW - ROUTE

KW - POLY(PHOSPHINOBORANES)

KW - PHOSPHANYLBORANES

UR - https://onlinelibrary.wiley.com/doi/full/10.1002/ejic.201900817

UR - http://www.mendeley.com/research/thermal-decomposition-donorstabilized-phosphinoborane-ph-2-bh-2-nme-3-tensimetry-study-thermal-dec

U2 - 10.1002/ejic.201900817

DO - 10.1002/ejic.201900817

M3 - Article

VL - 2019

SP - 3885

EP - 3891

JO - Berichte der deutschen chemischen Gesellschaft

JF - Berichte der deutschen chemischen Gesellschaft

SN - 0365-9496

IS - 35

ER -

ID: 46217965