Standard

Thermal Decomposition of B(C6F5)3·Py Complex. / Shcherbina, N.A.; Kazakov, I.V.; Gugin, N.Yu.; Lisovenko, A.S.; Pomogaeva, A.V.; Kondrat’ev, Yu.V.; Suslonov, V.V.; Timoshkin, A.Yu.

In: Russian Journal of General Chemistry, Vol. 89, No. 6, 01.06.2019, p. 1162–1168.

Research output: Contribution to journal › Article › peer-review

Harvard

Shcherbina, NA, Kazakov, IV, Gugin, NY, Lisovenko, AS, Pomogaeva, AV, Kondrat’ev, YV, Suslonov, VV & Timoshkin, AY 2019, 'Thermal Decomposition of B(C6F5)3·Py Complex', Russian Journal of General Chemistry, vol. 89, no. 6, pp. 1162–1168. https://doi.org/10.1134/S1070363219060100

APA

Shcherbina, N. A., Kazakov, I. V., Gugin, N. Y., Lisovenko, A. S., Pomogaeva, A. V., Kondrat’ev, Y. V., Suslonov, V. V., & Timoshkin, A. Y. (2019). Thermal Decomposition of B(C6F5)3·Py Complex. Russian Journal of General Chemistry, 89(6), 1162–1168. https://doi.org/10.1134/S1070363219060100

Vancouver

Shcherbina NA, Kazakov IV, Gugin NY, Lisovenko AS, Pomogaeva AV, Kondrat’ev YV et al. Thermal Decomposition of B(C6F5)3·Py Complex. Russian Journal of General Chemistry. 2019 Jun 1;89(6):1162–1168. https://doi.org/10.1134/S1070363219060100

Author

Shcherbina, N.A. ; Kazakov, I.V. ; Gugin, N.Yu. ; Lisovenko, A.S. ; Pomogaeva, A.V. ; Kondrat’ev, Yu.V. ; Suslonov, V.V. ; Timoshkin, A.Yu. / Thermal Decomposition of B(C6F5)3·Py Complex. In: Russian Journal of General Chemistry. 2019 ; Vol. 89, No. 6. pp. 1162–1168.

BibTeX

@article{fb189d0a8f6d4efe8637ee07dab6bf5c,
title = "Thermal Decomposition of B(C6F5)3·Py Complex",
abstract = "The crystal structure of the new polymorphic modification of B(C6F5)(3)Py complex was determined. It was shown by a static tensimetric method using a membrane null manometer that in the condensed phase in an excess of pyridine, B(C6F5)(3)Py complex is stable up to 220 degrees C. When temperature rises to 230 degrees C, the complex undergoes irreversible thermal decomposition, with the release of pentafluorobenzene and the polymerization of pyridine. The sublimation enthalpy of B(C6F5)(3)Py was determined for the first time by the calorimetric method. The results of quantum chemical calculations using the M06-2X method provide qualitative agreement with the experiment, in contrast to the B3LYP method.",
keywords = "calorimetry, donor-acceptor complex, pyridine, sublimation, tensimetry, tris(pentafluorophenyl)borane, ELEMENTS, PERFLUOROPHENYL DERIVATIVES, PYRIDINE, BASIS-SETS",
author = "N.A. Shcherbina and I.V. Kazakov and N.Yu. Gugin and A.S. Lisovenko and A.V. Pomogaeva and Yu.V. Kondrat{\textquoteright}ev and V.V. Suslonov and A.Yu. Timoshkin",
note = "Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd.",
year = "2019",
month = jun,
day = "1",
doi = "10.1134/S1070363219060100",
language = "English",
volume = "89",
pages = "1162–1168",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "6",

}

RIS

TY - JOUR

T1 - Thermal Decomposition of B(C6F5)3·Py Complex

AU - Shcherbina, N.A.

AU - Kazakov, I.V.

AU - Gugin, N.Yu.

AU - Lisovenko, A.S.

AU - Pomogaeva, A.V.

AU - Kondrat’ev, Yu.V.

AU - Suslonov, V.V.

AU - Timoshkin, A.Yu.

N1 - Publisher Copyright: © 2019, Pleiades Publishing, Ltd.

PY - 2019/6/1

Y1 - 2019/6/1

N2 - The crystal structure of the new polymorphic modification of B(C6F5)(3)Py complex was determined. It was shown by a static tensimetric method using a membrane null manometer that in the condensed phase in an excess of pyridine, B(C6F5)(3)Py complex is stable up to 220 degrees C. When temperature rises to 230 degrees C, the complex undergoes irreversible thermal decomposition, with the release of pentafluorobenzene and the polymerization of pyridine. The sublimation enthalpy of B(C6F5)(3)Py was determined for the first time by the calorimetric method. The results of quantum chemical calculations using the M06-2X method provide qualitative agreement with the experiment, in contrast to the B3LYP method.

AB - The crystal structure of the new polymorphic modification of B(C6F5)(3)Py complex was determined. It was shown by a static tensimetric method using a membrane null manometer that in the condensed phase in an excess of pyridine, B(C6F5)(3)Py complex is stable up to 220 degrees C. When temperature rises to 230 degrees C, the complex undergoes irreversible thermal decomposition, with the release of pentafluorobenzene and the polymerization of pyridine. The sublimation enthalpy of B(C6F5)(3)Py was determined for the first time by the calorimetric method. The results of quantum chemical calculations using the M06-2X method provide qualitative agreement with the experiment, in contrast to the B3LYP method.

KW - calorimetry

KW - donor-acceptor complex

KW - pyridine

KW - sublimation

KW - tensimetry

KW - tris(pentafluorophenyl)borane

KW - ELEMENTS

KW - PERFLUOROPHENYL DERIVATIVES

KW - PYRIDINE

KW - BASIS-SETS

UR - http://www.scopus.com/inward/record.url?scp=85068666996&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/thermal-decomposition-bc6f53py-complex/

U2 - 10.1134/S1070363219060100

DO - 10.1134/S1070363219060100

M3 - Article

VL - 89

SP - 1162

EP - 1168

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 6

ER -

ID: 43297020