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The vibrational spectrum of the OCS molecule based on the data on spectra of liquid and cryosolutions. / Bocharov, V. N.; Burtsev, A. P.; Gulidova, O. S.; Kolomiĭtsova, T. D.; Shchepkin, D. N.

In: Optics and Spectroscopy (English translation of Optika i Spektroskopiya), Vol. 105, No. 2, 08.2008, p. 242-250.

Research output: Contribution to journal › Article › peer-review

Harvard

Bocharov, VN, Burtsev, AP, Gulidova, OS, Kolomiĭtsova, TD & Shchepkin, DN 2008, 'The vibrational spectrum of the OCS molecule based on the data on spectra of liquid and cryosolutions', Optics and Spectroscopy (English translation of Optika i Spektroskopiya), vol. 105, no. 2, pp. 242-250. https://doi.org/10.1134/S0030400X08080122

APA

Bocharov, V. N., Burtsev, A. P., Gulidova, O. S., Kolomiĭtsova, T. D., & Shchepkin, D. N. (2008). The vibrational spectrum of the OCS molecule based on the data on spectra of liquid and cryosolutions. Optics and Spectroscopy (English translation of Optika i Spektroskopiya), 105(2), 242-250. https://doi.org/10.1134/S0030400X08080122

Vancouver

Bocharov VN, Burtsev AP, Gulidova OS, Kolomiĭtsova TD, Shchepkin DN. The vibrational spectrum of the OCS molecule based on the data on spectra of liquid and cryosolutions. Optics and Spectroscopy (English translation of Optika i Spektroskopiya). 2008 Aug;105(2):242-250. https://doi.org/10.1134/S0030400X08080122

Author

Bocharov, V. N. ; Burtsev, A. P. ; Gulidova, O. S. ; Kolomiĭtsova, T. D. ; Shchepkin, D. N. / The vibrational spectrum of the OCS molecule based on the data on spectra of liquid and cryosolutions. In: Optics and Spectroscopy (English translation of Optika i Spektroskopiya). 2008 ; Vol. 105, No. 2. pp. 242-250.

BibTeX

@article{fae5a7310a8246199c53928d4db3bd25,
title = "The vibrational spectrum of the OCS molecule based on the data on spectra of liquid and cryosolutions",
abstract = " The IR absorption spectra of liquid OCS (T = 135(1) K) and of the following solutions-OCS + Ar (T = 90 K), OCS + N 2 (T = 90 K), OCS + Kr (T = 130 K), and OCS + Xe (T = 163 K)-are measured in the range 800-7000 cm -1 . From 16 to 40 bands corresponding to transitions to vibrational states up to the third order inclusive are interpreted for basic isotope modification and for the isotopically substituted molecules 18 O 12 C 32 S, 16 O 13 C 32 S, and 16 O 12 C 34 S. In the spectra of the liquids, the spectral moments M(1) and M(2) of all the observed bands are determined. The harmonic frequencies ω i and the anharmonicity constants x ik are calculated for all the systems, including the liquid. The anharmonicity is found to be constant within the experimental error. A large shift Δω 3 is primarily determined by the dipole-induced dipole interaction.",
author = "Bocharov, {V. N.} and Burtsev, {A. P.} and Gulidova, {O. S.} and Kolomiĭtsova, {T. D.} and Shchepkin, {D. N.}",
year = "2008",
month = aug,
doi = "10.1134/S0030400X08080122",
language = "English",
volume = "105",
pages = "242--250",
journal = "OPTICS AND SPECTROSCOPY",
issn = "0030-400X",
publisher = "Pleiades Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - The vibrational spectrum of the OCS molecule based on the data on spectra of liquid and cryosolutions

AU - Bocharov, V. N.

AU - Burtsev, A. P.

AU - Gulidova, O. S.

AU - Kolomiĭtsova, T. D.

AU - Shchepkin, D. N.

PY - 2008/8

Y1 - 2008/8

N2 - The IR absorption spectra of liquid OCS (T = 135(1) K) and of the following solutions-OCS + Ar (T = 90 K), OCS + N 2 (T = 90 K), OCS + Kr (T = 130 K), and OCS + Xe (T = 163 K)-are measured in the range 800-7000 cm -1 . From 16 to 40 bands corresponding to transitions to vibrational states up to the third order inclusive are interpreted for basic isotope modification and for the isotopically substituted molecules 18 O 12 C 32 S, 16 O 13 C 32 S, and 16 O 12 C 34 S. In the spectra of the liquids, the spectral moments M(1) and M(2) of all the observed bands are determined. The harmonic frequencies ω i and the anharmonicity constants x ik are calculated for all the systems, including the liquid. The anharmonicity is found to be constant within the experimental error. A large shift Δω 3 is primarily determined by the dipole-induced dipole interaction.

AB - The IR absorption spectra of liquid OCS (T = 135(1) K) and of the following solutions-OCS + Ar (T = 90 K), OCS + N 2 (T = 90 K), OCS + Kr (T = 130 K), and OCS + Xe (T = 163 K)-are measured in the range 800-7000 cm -1 . From 16 to 40 bands corresponding to transitions to vibrational states up to the third order inclusive are interpreted for basic isotope modification and for the isotopically substituted molecules 18 O 12 C 32 S, 16 O 13 C 32 S, and 16 O 12 C 34 S. In the spectra of the liquids, the spectral moments M(1) and M(2) of all the observed bands are determined. The harmonic frequencies ω i and the anharmonicity constants x ik are calculated for all the systems, including the liquid. The anharmonicity is found to be constant within the experimental error. A large shift Δω 3 is primarily determined by the dipole-induced dipole interaction.

UR - http://www.scopus.com/inward/record.url?scp=50249128683&partnerID=8YFLogxK

U2 - 10.1134/S0030400X08080122

DO - 10.1134/S0030400X08080122

M3 - Article

AN - SCOPUS:50249128683

VL - 105

SP - 242

EP - 250

JO - OPTICS AND SPECTROSCOPY

JF - OPTICS AND SPECTROSCOPY

SN - 0030-400X

IS - 2

ER -

ID: 49683680