TY - JOUR

T1 - The Ti3SiC2 max phases as promising materials for high temperature applications

T2 - Formation under various synthesis conditions

AU - Perevislov, S. N.

AU - Sokolova, T. V.

AU - Stolyarova, V. L.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research and ROSATOM [grant number 20-21-00056 ]. Publisher Copyright: © 2021 Elsevier B.V. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/7/1

Y1 - 2021/7/1

N2 - In the present study, for the first time, a new method for the synthesis of MAX phases of the composition Ti3SiC2, combining high-temperature sintering and hot pressing, was proposed and implemented, and this made it possible to obtain the purest material with a Ti3SiC2 phase content equal to 99.2%. The Ti3SiC2 MAX phases are extremely promising materials for protection of containers and fuel cladding of nuclear reactors taking into consideration their high values of mechanical properties and the unique ability of successful radiation resistance. According to this task, the synthesis methods and formation conditions of the Ti3SiC2 MAX phases are considered in the present study involving the following approaches. Among them the second was used for the first time. Various mixtures from initial powders Ti/Si/C, Ti/Si/TiC, Ti/SiC/C and Ti/SiC/TiC were used to synthesize ternary titanium-silicon carbide (Ti3SiC2) by sintering followed by hot pressing. The powder Ti/SiС/TiC is the best among all powder mixtures for synthesis Ti3SiC2. The relative density of the samples synthesized and consolidated by the hot pressing method reaches 99.4%. It is shown that practically single-phase Ti3SiC2consists of elongated laminar grains. The influence of time and temperature of sintering on the formation of the MAX-phase Ti3SiC2 from original powders Ti/Si/C was determined. Titanium carbide, as an intermediate phase, is always present in final products. Excess silicon contributes to the greatest phase formation Ti3SiC2. The high content of the Ti3SiC2 phase in the samples makes it possible to predict their high mechanical properties and resistance to radiation, as well as to consider these materials as the most promising for the further protection of containers and casings of fuel elements of nuclear reactors.

AB - In the present study, for the first time, a new method for the synthesis of MAX phases of the composition Ti3SiC2, combining high-temperature sintering and hot pressing, was proposed and implemented, and this made it possible to obtain the purest material with a Ti3SiC2 phase content equal to 99.2%. The Ti3SiC2 MAX phases are extremely promising materials for protection of containers and fuel cladding of nuclear reactors taking into consideration their high values of mechanical properties and the unique ability of successful radiation resistance. According to this task, the synthesis methods and formation conditions of the Ti3SiC2 MAX phases are considered in the present study involving the following approaches. Among them the second was used for the first time. Various mixtures from initial powders Ti/Si/C, Ti/Si/TiC, Ti/SiC/C and Ti/SiC/TiC were used to synthesize ternary titanium-silicon carbide (Ti3SiC2) by sintering followed by hot pressing. The powder Ti/SiС/TiC is the best among all powder mixtures for synthesis Ti3SiC2. The relative density of the samples synthesized and consolidated by the hot pressing method reaches 99.4%. It is shown that practically single-phase Ti3SiC2consists of elongated laminar grains. The influence of time and temperature of sintering on the formation of the MAX-phase Ti3SiC2 from original powders Ti/Si/C was determined. Titanium carbide, as an intermediate phase, is always present in final products. Excess silicon contributes to the greatest phase formation Ti3SiC2. The high content of the Ti3SiC2 phase in the samples makes it possible to predict their high mechanical properties and resistance to radiation, as well as to consider these materials as the most promising for the further protection of containers and casings of fuel elements of nuclear reactors.

KW - MAX-Phase

KW - Phase diagram

KW - Structural materials

KW - Ternary titanium-silicon carbide

KW - LIQUID REACTION

KW - MECHANICAL-PROPERTIES

KW - TERNARY COMPOUND TI3SIC2

KW - OXIDATION BEHAVIOR

KW - FRACTURE PROPERTIES

KW - M(N+1)AX(N) PHASES

KW - FABRICATION

KW - RAPID SYNTHESIS

KW - FATIGUE-CRACK GROWTH

KW - MICROSTRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=85104664031&partnerID=8YFLogxK

U2 - 10.1016/j.matchemphys.2021.124625

DO - 10.1016/j.matchemphys.2021.124625

M3 - Article

AN - SCOPUS:85104664031

VL - 267

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

SN - 0254-0584

M1 - 124625

ER -