The performance evaluation of nanostructured perovskite-type complex oxides GdBO3 (B = Fe, Co, Mn) for carbon monoxide hydrogenation

Standard

The performance evaluation of nanostructured perovskite-type complex oxides GdBO₃ (B = Fe, Co, Mn) for carbon monoxide hydrogenation. / Sheshko, T. F.; Kryuchkova, T. A.; Sharaeva, A. A.; Serov, Y. M.; Yafarova, L. V.; Zvereva, I. A.

In: Journal of Physics: Conference Series, Vol. 1310, No. 1, 012007, 08.10.2019.

Research output: Contribution to journal › Conference article › peer-review

Author

Sheshko, T. F. ; Kryuchkova, T. A. ; Sharaeva, A. A. ; Serov, Y. M. ; Yafarova, L. V. ; Zvereva, I. A. / The performance evaluation of nanostructured perovskite-type complex oxides GdBO₃ (B = Fe, Co, Mn) for carbon monoxide hydrogenation. In: Journal of Physics: Conference Series. 2019 ; Vol. 1310, No. 1.

BibTeX

@article{9e8e99d4611f42ff88edf2cc51ac06be,

title = "The performance evaluation of nanostructured perovskite-type complex oxides GdBO3 (B = Fe, Co, Mn) for carbon monoxide hydrogenation",

abstract = "Nanostructured perovskite-type oxides GdBO3 (B = Fe, Co, Mn) synthesized by sol-gel technology, have been used as catalysts for the light olefins production by carbon monoxide hydrogenation. Perovskite materials were characterized using different techniques: XRD, SEM+EDX, BET, TG to study structure and morphology. Oxidation state of Fe and Mn was determined by XPS. The catalytic activity test was carried out in a continuous-flow mode with chromatographic analysis of the reaction mixture. It was found that the catalytic characteristics are determined by the nature of the metal in the B-site of perovskite. The specific catalytic activity increases in the series GdMnO3 <GdFeO3 <GdCoO3, and selectivity for olefins - in the reverse order.",

author = "Sheshko, {T. F.} and Kryuchkova, {T. A.} and Sharaeva, {A. A.} and Serov, {Y. M.} and Yafarova, {L. V.} and Zvereva, {I. A.}",

note = "Funding Information: This work was supported by Russian Foundation for Basic Research, research project № 17-03-00647. The publication has been prepared with the support of the «RUDN University Program 5-100». Scientific researches were performed at the Center of X-ray Diffraction Methods nad Nnotechanology, Center for Stadies in Surface Science, Center for Thermogravimetric and Calorimetric Research of Research park of St. Petersburg State University. Publisher Copyright: {\textcopyright} Published under licence by IOP Publishing Ltd. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.; Applied Nanotechnology and Nanoscience International Conference, ANNIC 2018 ; Conference date: 22-10-2018 Through 24-10-2018",

year = "2019",

month = oct,

day = "8",

doi = "10.1088/1742-6596/1310/1/012007",

language = "English",

volume = "1310",

journal = "Journal of Physics: Conference Series",

issn = "1742-6588",

publisher = "IOP Publishing Ltd.",

number = "1",

}

RIS

TY - JOUR

T1 - The performance evaluation of nanostructured perovskite-type complex oxides GdBO3 (B = Fe, Co, Mn) for carbon monoxide hydrogenation

AU - Sheshko, T. F.

AU - Kryuchkova, T. A.

AU - Sharaeva, A. A.

AU - Serov, Y. M.

AU - Yafarova, L. V.

AU - Zvereva, I. A.

N1 - Funding Information: This work was supported by Russian Foundation for Basic Research, research project № 17-03-00647. The publication has been prepared with the support of the «RUDN University Program 5-100». Scientific researches were performed at the Center of X-ray Diffraction Methods nad Nnotechanology, Center for Stadies in Surface Science, Center for Thermogravimetric and Calorimetric Research of Research park of St. Petersburg State University. Publisher Copyright: © Published under licence by IOP Publishing Ltd. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/10/8

Y1 - 2019/10/8

N2 - Nanostructured perovskite-type oxides GdBO3 (B = Fe, Co, Mn) synthesized by sol-gel technology, have been used as catalysts for the light olefins production by carbon monoxide hydrogenation. Perovskite materials were characterized using different techniques: XRD, SEM+EDX, BET, TG to study structure and morphology. Oxidation state of Fe and Mn was determined by XPS. The catalytic activity test was carried out in a continuous-flow mode with chromatographic analysis of the reaction mixture. It was found that the catalytic characteristics are determined by the nature of the metal in the B-site of perovskite. The specific catalytic activity increases in the series GdMnO3 <GdFeO3 <GdCoO3, and selectivity for olefins - in the reverse order.

AB - Nanostructured perovskite-type oxides GdBO3 (B = Fe, Co, Mn) synthesized by sol-gel technology, have been used as catalysts for the light olefins production by carbon monoxide hydrogenation. Perovskite materials were characterized using different techniques: XRD, SEM+EDX, BET, TG to study structure and morphology. Oxidation state of Fe and Mn was determined by XPS. The catalytic activity test was carried out in a continuous-flow mode with chromatographic analysis of the reaction mixture. It was found that the catalytic characteristics are determined by the nature of the metal in the B-site of perovskite. The specific catalytic activity increases in the series GdMnO3 <GdFeO3 <GdCoO3, and selectivity for olefins - in the reverse order.

UR - http://www.scopus.com/inward/record.url?scp=85074876216&partnerID=8YFLogxK

U2 - 10.1088/1742-6596/1310/1/012007

DO - 10.1088/1742-6596/1310/1/012007

M3 - Conference article

AN - SCOPUS:85074876216

VL - 1310

JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

SN - 1742-6588

IS - 1

M1 - 012007

T2 - Applied Nanotechnology and Nanoscience International Conference, ANNIC 2018

Y2 - 22 October 2018 through 24 October 2018

ER -

ID: 70817103