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The new method for obtaining titanosilicate AM-4 and its decationated form : Crystal chemistry, properties and advanced areas of application. / Kalashnikova, G. O.; Zhitova, E. S.; Selivanova, E. A.; Pakhomovsky, Ya A.; Yakovenchuk, V. N.; Ivanyuk, G. Yu; Kasikov, A. G.; Drogobuzhskaya, S. V.; Elizarova, I. R.; Kiselev, Yu G.; Knyazeva, A. I.; Korovin, V. N.; Nikolaev, A. I.; Krivovichev, S. V.

In: Microporous and Mesoporous Materials, Vol. 313, 110787, 01.01.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Kalashnikova, GO, Zhitova, ES, Selivanova, EA, Pakhomovsky, YA, Yakovenchuk, VN, Ivanyuk, GY, Kasikov, AG, Drogobuzhskaya, SV, Elizarova, IR, Kiselev, YG, Knyazeva, AI, Korovin, VN, Nikolaev, AI & Krivovichev, SV 2021, 'The new method for obtaining titanosilicate AM-4 and its decationated form: Crystal chemistry, properties and advanced areas of application', Microporous and Mesoporous Materials, vol. 313, 110787. https://doi.org/10.1016/j.micromeso.2020.110787

APA

Kalashnikova, G. O., Zhitova, E. S., Selivanova, E. A., Pakhomovsky, Y. A., Yakovenchuk, V. N., Ivanyuk, G. Y., Kasikov, A. G., Drogobuzhskaya, S. V., Elizarova, I. R., Kiselev, Y. G., Knyazeva, A. I., Korovin, V. N., Nikolaev, A. I., & Krivovichev, S. V. (2021). The new method for obtaining titanosilicate AM-4 and its decationated form: Crystal chemistry, properties and advanced areas of application. Microporous and Mesoporous Materials, 313, [110787]. https://doi.org/10.1016/j.micromeso.2020.110787

Vancouver

Kalashnikova GO, Zhitova ES, Selivanova EA, Pakhomovsky YA, Yakovenchuk VN, Ivanyuk GY et al. The new method for obtaining titanosilicate AM-4 and its decationated form: Crystal chemistry, properties and advanced areas of application. Microporous and Mesoporous Materials. 2021 Jan 1;313. 110787. https://doi.org/10.1016/j.micromeso.2020.110787

Author

Kalashnikova, G. O. ; Zhitova, E. S. ; Selivanova, E. A. ; Pakhomovsky, Ya A. ; Yakovenchuk, V. N. ; Ivanyuk, G. Yu ; Kasikov, A. G. ; Drogobuzhskaya, S. V. ; Elizarova, I. R. ; Kiselev, Yu G. ; Knyazeva, A. I. ; Korovin, V. N. ; Nikolaev, A. I. ; Krivovichev, S. V. / The new method for obtaining titanosilicate AM-4 and its decationated form : Crystal chemistry, properties and advanced areas of application. In: Microporous and Mesoporous Materials. 2021 ; Vol. 313.

BibTeX

@article{d09682a21f6f408fa8e43478631d749b,
title = "The new method for obtaining titanosilicate AM-4 and its decationated form: Crystal chemistry, properties and advanced areas of application",
abstract = "Layered microporous titanosilicate AM-4 (Aveiro-Manchester-4) is a synthetic analog of microporous lintisite-type minerals. We applied the hydrothermal method to synthesize AM-4 compound from different titanium sources, i.e. titanium (III) chloride solution, titanyl-sulfate (titanite ore treatment product) and sodium metasilicate by stepwise cooling of an initial titanium-silicate mixture. In acid solution the crystal structure of AM-4 transformed into a novel layered titanosilicate SL3 (synthetic decationated lintisite) with a unique topology that consists of Ti2Si4O10(OH)4 nano-blocks. It was found that SL3 compound had a tendency for uptake of Ag from the standard test copper-nickel electrolyte. A possibility of repeated use of SL3 as a renewable sorbent was shown on the example of sorption Ca2+ cations. Both AM-4 and SL3 compounds can be considered as new functional materials of renewable and thermally stable nature with potential application for sorption and immobilization of the radioactive iodine isotopes.",
keywords = "AM-4, Hydrothermal synthesis, Lintisite, Renewable sorbent, SL3, Titanosilicate, TITANIUM SILICATE, CATION-EXCHANGED FORMS, ION-EXCHANGE, KHIBINY, HYDROTHERMAL SYNTHESIS, MASSIF KOLA-PENINSULA, CU, ZEOLITE",
author = "Kalashnikova, {G. O.} and Zhitova, {E. S.} and Selivanova, {E. A.} and Pakhomovsky, {Ya A.} and Yakovenchuk, {V. N.} and Ivanyuk, {G. Yu} and Kasikov, {A. G.} and Drogobuzhskaya, {S. V.} and Elizarova, {I. R.} and Kiselev, {Yu G.} and Knyazeva, {A. I.} and Korovin, {V. N.} and Nikolaev, {A. I.} and Krivovichev, {S. V.}",
note = "Funding Information: We thank A.V. Bazai (Geological Institute KSC RAS) for the electron microprobe analyses of some samples and L.G. Gerasimova (I.V. Tananaev Institute of Chemistry KSC RAS) for valued comments on hydrothermal synthesis of titanosilicates. The X-ray diffraction experiments were carried out using facilities of XRD Resource Center at the St. Petersburg State University. This work was supported by the framework of the budget project 0226-2019-009 for Nanomaterials Research Centre of FRC KSC RAS (investigations of the opportunity of the STA salt in synthesis), and by the Russian Foundation for Basic Research, Grant 18-29-12039 (investigations of SL3 sorption properties). Funding Information: This work was supported by the framework of the budget project 0226-2019-009 for Nanomaterials Research Centre of FRC KSC RAS (investigations of the opportunity of the STA salt in synthesis), and by the Russian Foundation for Basic Research , Grant 18-29-12039 (investigations of SL3 sorption properties). Publisher Copyright: {\textcopyright} 2020 Elsevier Inc. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = jan,
day = "1",
doi = "10.1016/j.micromeso.2020.110787",
language = "English",
volume = "313",
journal = "Zeolites",
issn = "1387-1811",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - The new method for obtaining titanosilicate AM-4 and its decationated form

T2 - Crystal chemistry, properties and advanced areas of application

AU - Kalashnikova, G. O.

AU - Zhitova, E. S.

AU - Selivanova, E. A.

AU - Pakhomovsky, Ya A.

AU - Yakovenchuk, V. N.

AU - Ivanyuk, G. Yu

AU - Kasikov, A. G.

AU - Drogobuzhskaya, S. V.

AU - Elizarova, I. R.

AU - Kiselev, Yu G.

AU - Knyazeva, A. I.

AU - Korovin, V. N.

AU - Nikolaev, A. I.

AU - Krivovichev, S. V.

N1 - Funding Information: We thank A.V. Bazai (Geological Institute KSC RAS) for the electron microprobe analyses of some samples and L.G. Gerasimova (I.V. Tananaev Institute of Chemistry KSC RAS) for valued comments on hydrothermal synthesis of titanosilicates. The X-ray diffraction experiments were carried out using facilities of XRD Resource Center at the St. Petersburg State University. This work was supported by the framework of the budget project 0226-2019-009 for Nanomaterials Research Centre of FRC KSC RAS (investigations of the opportunity of the STA salt in synthesis), and by the Russian Foundation for Basic Research, Grant 18-29-12039 (investigations of SL3 sorption properties). Funding Information: This work was supported by the framework of the budget project 0226-2019-009 for Nanomaterials Research Centre of FRC KSC RAS (investigations of the opportunity of the STA salt in synthesis), and by the Russian Foundation for Basic Research , Grant 18-29-12039 (investigations of SL3 sorption properties). Publisher Copyright: © 2020 Elsevier Inc. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/1/1

Y1 - 2021/1/1

N2 - Layered microporous titanosilicate AM-4 (Aveiro-Manchester-4) is a synthetic analog of microporous lintisite-type minerals. We applied the hydrothermal method to synthesize AM-4 compound from different titanium sources, i.e. titanium (III) chloride solution, titanyl-sulfate (titanite ore treatment product) and sodium metasilicate by stepwise cooling of an initial titanium-silicate mixture. In acid solution the crystal structure of AM-4 transformed into a novel layered titanosilicate SL3 (synthetic decationated lintisite) with a unique topology that consists of Ti2Si4O10(OH)4 nano-blocks. It was found that SL3 compound had a tendency for uptake of Ag from the standard test copper-nickel electrolyte. A possibility of repeated use of SL3 as a renewable sorbent was shown on the example of sorption Ca2+ cations. Both AM-4 and SL3 compounds can be considered as new functional materials of renewable and thermally stable nature with potential application for sorption and immobilization of the radioactive iodine isotopes.

AB - Layered microporous titanosilicate AM-4 (Aveiro-Manchester-4) is a synthetic analog of microporous lintisite-type minerals. We applied the hydrothermal method to synthesize AM-4 compound from different titanium sources, i.e. titanium (III) chloride solution, titanyl-sulfate (titanite ore treatment product) and sodium metasilicate by stepwise cooling of an initial titanium-silicate mixture. In acid solution the crystal structure of AM-4 transformed into a novel layered titanosilicate SL3 (synthetic decationated lintisite) with a unique topology that consists of Ti2Si4O10(OH)4 nano-blocks. It was found that SL3 compound had a tendency for uptake of Ag from the standard test copper-nickel electrolyte. A possibility of repeated use of SL3 as a renewable sorbent was shown on the example of sorption Ca2+ cations. Both AM-4 and SL3 compounds can be considered as new functional materials of renewable and thermally stable nature with potential application for sorption and immobilization of the radioactive iodine isotopes.

KW - AM-4

KW - Hydrothermal synthesis

KW - Lintisite

KW - Renewable sorbent

KW - SL3

KW - Titanosilicate

KW - TITANIUM SILICATE

KW - CATION-EXCHANGED FORMS

KW - ION-EXCHANGE

KW - KHIBINY

KW - HYDROTHERMAL SYNTHESIS

KW - MASSIF KOLA-PENINSULA

KW - CU

KW - ZEOLITE

UR - http://www.scopus.com/inward/record.url?scp=85098179582&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/78c9421d-b73a-3309-ae90-812f4296a6a1/

U2 - 10.1016/j.micromeso.2020.110787

DO - 10.1016/j.micromeso.2020.110787

M3 - Article

AN - SCOPUS:85098179582

VL - 313

JO - Zeolites

JF - Zeolites

SN - 1387-1811

M1 - 110787

ER -

ID: 75306096