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The Implication of 1,3-Dipolar Cycloaddition of Azomethine Ylides to the Synthesis of Main-Chain Porphyrin Oligomers. / Konev, A.S.; Lukyanov, D.A.; Vlasov, P.S.; Levin, O.V.; Virtsev, A.A.; Kislyakov, I.M.; Khlebnikov, A.F.

In: Macromolecular Chemistry and Physics, Vol. 215, No. 6, 2014, p. 516-529.

Research output: Contribution to journal › Article

Harvard

Konev, AS, Lukyanov, DA, Vlasov, PS, Levin, OV, Virtsev, AA, Kislyakov, IM & Khlebnikov, AF 2014, 'The Implication of 1,3-Dipolar Cycloaddition of Azomethine Ylides to the Synthesis of Main-Chain Porphyrin Oligomers', Macromolecular Chemistry and Physics, vol. 215, no. 6, pp. 516-529. https://doi.org/10.1002/macp.201300679

APA

Konev, A. S., Lukyanov, D. A., Vlasov, P. S., Levin, O. V., Virtsev, A. A., Kislyakov, I. M., & Khlebnikov, A. F. (2014). The Implication of 1,3-Dipolar Cycloaddition of Azomethine Ylides to the Synthesis of Main-Chain Porphyrin Oligomers. Macromolecular Chemistry and Physics, 215(6), 516-529. https://doi.org/10.1002/macp.201300679

Vancouver

Konev AS, Lukyanov DA, Vlasov PS, Levin OV, Virtsev AA, Kislyakov IM et al. The Implication of 1,3-Dipolar Cycloaddition of Azomethine Ylides to the Synthesis of Main-Chain Porphyrin Oligomers. Macromolecular Chemistry and Physics. 2014;215(6):516-529. https://doi.org/10.1002/macp.201300679

Author

Konev, A.S. ; Lukyanov, D.A. ; Vlasov, P.S. ; Levin, O.V. ; Virtsev, A.A. ; Kislyakov, I.M. ; Khlebnikov, A.F. / The Implication of 1,3-Dipolar Cycloaddition of Azomethine Ylides to the Synthesis of Main-Chain Porphyrin Oligomers. In: Macromolecular Chemistry and Physics. 2014 ; Vol. 215, No. 6. pp. 516-529.

BibTeX

@article{328bd7904d0b4342a0692f90954ccc41,
title = "The Implication of 1,3-Dipolar Cycloaddition of Azomethine Ylides to the Synthesis of Main-Chain Porphyrin Oligomers",
abstract = "The polycycloaddition of azomethine ylides to dipolarophiles is described for the first time. Use of (cis,cis)-bis-aziridines as a source of azomethine ylides allows selective polyaddition to be realized, which leads to oligomers exclusively with trans-substituted pyrrolidine rings and modest molecular weights (ca. 5–10 kDa). The fluorescent, electrochemical, electrochromic, and non-linear optical properties of the main-chain free-base porphyrin oligomer, synthesized by the developed procedure, are studied. An enhancement of the optical power limiting effect in a porphyrin oligomer solution is registered against that of the monomer.",
keywords = "conducting polymers, electrochemistry, optical power limiting, polymerization, porphyrins",
author = "A.S. Konev and D.A. Lukyanov and P.S. Vlasov and O.V. Levin and A.A. Virtsev and I.M. Kislyakov and A.F. Khlebnikov",
year = "2014",
doi = "10.1002/macp.201300679",
language = "English",
volume = "215",
pages = "516--529",
journal = "Macromolecular Chemistry and Physics",
issn = "1022-1352",
publisher = "Wiley-Blackwell",
number = "6",

}

RIS

TY - JOUR

T1 - The Implication of 1,3-Dipolar Cycloaddition of Azomethine Ylides to the Synthesis of Main-Chain Porphyrin Oligomers

AU - Konev, A.S.

AU - Lukyanov, D.A.

AU - Vlasov, P.S.

AU - Levin, O.V.

AU - Virtsev, A.A.

AU - Kislyakov, I.M.

AU - Khlebnikov, A.F.

PY - 2014

Y1 - 2014

N2 - The polycycloaddition of azomethine ylides to dipolarophiles is described for the first time. Use of (cis,cis)-bis-aziridines as a source of azomethine ylides allows selective polyaddition to be realized, which leads to oligomers exclusively with trans-substituted pyrrolidine rings and modest molecular weights (ca. 5–10 kDa). The fluorescent, electrochemical, electrochromic, and non-linear optical properties of the main-chain free-base porphyrin oligomer, synthesized by the developed procedure, are studied. An enhancement of the optical power limiting effect in a porphyrin oligomer solution is registered against that of the monomer.

AB - The polycycloaddition of azomethine ylides to dipolarophiles is described for the first time. Use of (cis,cis)-bis-aziridines as a source of azomethine ylides allows selective polyaddition to be realized, which leads to oligomers exclusively with trans-substituted pyrrolidine rings and modest molecular weights (ca. 5–10 kDa). The fluorescent, electrochemical, electrochromic, and non-linear optical properties of the main-chain free-base porphyrin oligomer, synthesized by the developed procedure, are studied. An enhancement of the optical power limiting effect in a porphyrin oligomer solution is registered against that of the monomer.

KW - conducting polymers

KW - electrochemistry

KW - optical power limiting

KW - polymerization

KW - porphyrins

U2 - 10.1002/macp.201300679

DO - 10.1002/macp.201300679

M3 - Article

VL - 215

SP - 516

EP - 529

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

SN - 1022-1352

IS - 6

ER -

ID: 6994457