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The HeI2 van der Waals complexes in a “free-rotor” configuration. / Baturo, V.V.; Lukashov, S.S.; Poretsky, S.A.; Pravilov, A.M.; Zhironkin, A.I.

In: Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 53, No. 3, 035101, 06.01.2020, p. 035101.

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Baturo, V.V. ; Lukashov, S.S. ; Poretsky, S.A. ; Pravilov, A.M. ; Zhironkin, A.I. / The HeI2 van der Waals complexes in a “free-rotor” configuration. In: Journal of Physics B: Atomic, Molecular and Optical Physics. 2020 ; Vol. 53, No. 3. pp. 035101.

BibTeX

@article{acfbc038ea7d4ef1bc42bbf5bc3629e0,
title = "The HeI2 van der Waals complexes in a “free-rotor” configuration",
abstract = "The HeI 2(E0 + g , vE=0-6, nE>) van der Waals complexes in a free-rotor configuration populated in the excitation pathway via HeI 2(B0 + u=19, nB=2-4) intermediate levels have been studied utilizing laser-induced luminescence spectroscopy methods. Analysis of the excitation pathway has been performed, and the I 2(E0 + g→B0 + u→D0 + u) luminescence spectra have been measured. These I 2(E and D) molecules are the product of the HeI 2(E, vE= 0E) vibrational and electronic predissociation, respectively. We have defined the probabilities of the HeI 2(E, = E) predissociation channels, vibrational populations of the I2(E and D) states as well as binding energies of the HeI 2(E, vE=0-6, nE, J=0) states. A modified ab initio potential of the HeI 2(E) state has been used to explain experimental results. ",
keywords = "Vander Waals complexes, iodine molecule, ion-pair states, potential energy surface, EXCITATION, GROUND-STATE, van der Waals complexes, DYNAMICS, TRANSITIONS, AR-CENTER-DOT-CENTER-DOT-CENTER-DOT-I-2",
author = "V.V. Baturo and S.S. Lukashov and S.A. Poretsky and A.M. Pravilov and A.I. Zhironkin",
note = "V. V. Baturo et al. 2020 J. Phys. B: At. Mol. Opt. Phys. 53 035101",
year = "2020",
month = jan,
day = "6",
doi = "https://doi.org/10.1088/1361-6455/ab582b",
language = "English",
volume = "53",
pages = "035101",
journal = "Journal of the European Optical Society Part B: Quantum Optics",
issn = "0953-4075",
publisher = "IOP Publishing Ltd.",
number = "3",

}

RIS

TY - JOUR

T1 - The HeI2 van der Waals complexes in a “free-rotor” configuration

AU - Baturo, V.V.

AU - Lukashov, S.S.

AU - Poretsky, S.A.

AU - Pravilov, A.M.

AU - Zhironkin, A.I.

N1 - V. V. Baturo et al. 2020 J. Phys. B: At. Mol. Opt. Phys. 53 035101

PY - 2020/1/6

Y1 - 2020/1/6

N2 - The HeI 2(E0 + g , vE=0-6, nE>) van der Waals complexes in a free-rotor configuration populated in the excitation pathway via HeI 2(B0 + u=19, nB=2-4) intermediate levels have been studied utilizing laser-induced luminescence spectroscopy methods. Analysis of the excitation pathway has been performed, and the I 2(E0 + g→B0 + u→D0 + u) luminescence spectra have been measured. These I 2(E and D) molecules are the product of the HeI 2(E, vE= 0E) vibrational and electronic predissociation, respectively. We have defined the probabilities of the HeI 2(E, = E) predissociation channels, vibrational populations of the I2(E and D) states as well as binding energies of the HeI 2(E, vE=0-6, nE, J=0) states. A modified ab initio potential of the HeI 2(E) state has been used to explain experimental results.

AB - The HeI 2(E0 + g , vE=0-6, nE>) van der Waals complexes in a free-rotor configuration populated in the excitation pathway via HeI 2(B0 + u=19, nB=2-4) intermediate levels have been studied utilizing laser-induced luminescence spectroscopy methods. Analysis of the excitation pathway has been performed, and the I 2(E0 + g→B0 + u→D0 + u) luminescence spectra have been measured. These I 2(E and D) molecules are the product of the HeI 2(E, vE= 0E) vibrational and electronic predissociation, respectively. We have defined the probabilities of the HeI 2(E, = E) predissociation channels, vibrational populations of the I2(E and D) states as well as binding energies of the HeI 2(E, vE=0-6, nE, J=0) states. A modified ab initio potential of the HeI 2(E) state has been used to explain experimental results.

KW - Vander Waals complexes

KW - iodine molecule

KW - ion-pair states

KW - potential energy surface

KW - EXCITATION

KW - GROUND-STATE

KW - van der Waals complexes

KW - DYNAMICS

KW - TRANSITIONS

KW - AR-CENTER-DOT-CENTER-DOT-CENTER-DOT-I-2

UR - http://www.scopus.com/inward/record.url?scp=85081668166&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/7a3bd282-37dc-3260-a493-613d6a239f82/

U2 - https://doi.org/10.1088/1361-6455/ab582b

DO - https://doi.org/10.1088/1361-6455/ab582b

M3 - Article

VL - 53

SP - 035101

JO - Journal of the European Optical Society Part B: Quantum Optics

JF - Journal of the European Optical Society Part B: Quantum Optics

SN - 0953-4075

IS - 3

M1 - 035101

ER -

ID: 51203494