Research output: Contribution to journal › Article › peer-review
The Field Of Main Group Lewis Acids and Lewis Superacids: Important Basics and Recent Developments. / Тимошкин, Алексей Юрьевич.
In: Chemistry - A European Journal, 14.11.2023.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - The Field Of Main Group Lewis Acids and Lewis Superacids: Important Basics and Recent Developments
AU - Тимошкин, Алексей Юрьевич
PY - 2023/11/14
Y1 - 2023/11/14
N2 - New developments in the field of Lewis acidity are highlighted, with the focus of novel Lewis acids and Lewis superacids of group 2, 13, 14, and 15 elements. Several important basics, illustrated by modern examples (classification of Donor-Acceptor (DA) complexes, amphoteric nature of any compound in terms of DA interactions, reorganization energies of main group Lewis acids and the role of the energies of frontier orbitals) are presented and discussed. It is emphasized that the Lewis acidity phenomena are general and play vital role in different areas of chemistry: from weak “atomophilic” interactions to the complexes of Lewis superacids.
AB - New developments in the field of Lewis acidity are highlighted, with the focus of novel Lewis acids and Lewis superacids of group 2, 13, 14, and 15 elements. Several important basics, illustrated by modern examples (classification of Donor-Acceptor (DA) complexes, amphoteric nature of any compound in terms of DA interactions, reorganization energies of main group Lewis acids and the role of the energies of frontier orbitals) are presented and discussed. It is emphasized that the Lewis acidity phenomena are general and play vital role in different areas of chemistry: from weak “atomophilic” interactions to the complexes of Lewis superacids.
KW - Lewis acidity scales
KW - Lewis acids
KW - Lewis superacids
KW - main group chemistry
KW - molecular complexes
UR - https://www.mendeley.com/catalogue/d6bb9128-83d5-3338-8844-86edfb56e4da/
U2 - 10.1002/chem.202302457
DO - 10.1002/chem.202302457
M3 - Article
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
M1 - e202302457
ER -
ID: 111819909