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The Field Of Main Group Lewis Acids and Lewis Superacids: Important Basics and Recent Developments. / Тимошкин, Алексей Юрьевич.

In: Chemistry - A European Journal, 14.11.2023.

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@article{c88c7817b84c4236ac8700f4949969ac,
title = "The Field Of Main Group Lewis Acids and Lewis Superacids: Important Basics and Recent Developments",
abstract = "New developments in the field of Lewis acidity are highlighted, with the focus of novel Lewis acids and Lewis superacids of group 2, 13, 14, and 15 elements. Several important basics, illustrated by modern examples (classification of Donor-Acceptor (DA) complexes, amphoteric nature of any compound in terms of DA interactions, reorganization energies of main group Lewis acids and the role of the energies of frontier orbitals) are presented and discussed. It is emphasized that the Lewis acidity phenomena are general and play vital role in different areas of chemistry: from weak “atomophilic” interactions to the complexes of Lewis superacids.",
keywords = "Lewis acidity scales, Lewis acids, Lewis superacids, main group chemistry, molecular complexes",
author = "Тимошкин, {Алексей Юрьевич}",
year = "2023",
month = nov,
day = "14",
doi = "10.1002/chem.202302457",
language = "English",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-Blackwell",

}

RIS

TY - JOUR

T1 - The Field Of Main Group Lewis Acids and Lewis Superacids: Important Basics and Recent Developments

AU - Тимошкин, Алексей Юрьевич

PY - 2023/11/14

Y1 - 2023/11/14

N2 - New developments in the field of Lewis acidity are highlighted, with the focus of novel Lewis acids and Lewis superacids of group 2, 13, 14, and 15 elements. Several important basics, illustrated by modern examples (classification of Donor-Acceptor (DA) complexes, amphoteric nature of any compound in terms of DA interactions, reorganization energies of main group Lewis acids and the role of the energies of frontier orbitals) are presented and discussed. It is emphasized that the Lewis acidity phenomena are general and play vital role in different areas of chemistry: from weak “atomophilic” interactions to the complexes of Lewis superacids.

AB - New developments in the field of Lewis acidity are highlighted, with the focus of novel Lewis acids and Lewis superacids of group 2, 13, 14, and 15 elements. Several important basics, illustrated by modern examples (classification of Donor-Acceptor (DA) complexes, amphoteric nature of any compound in terms of DA interactions, reorganization energies of main group Lewis acids and the role of the energies of frontier orbitals) are presented and discussed. It is emphasized that the Lewis acidity phenomena are general and play vital role in different areas of chemistry: from weak “atomophilic” interactions to the complexes of Lewis superacids.

KW - Lewis acidity scales

KW - Lewis acids

KW - Lewis superacids

KW - main group chemistry

KW - molecular complexes

UR - https://www.mendeley.com/catalogue/d6bb9128-83d5-3338-8844-86edfb56e4da/

U2 - 10.1002/chem.202302457

DO - 10.1002/chem.202302457

M3 - Article

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

M1 - e202302457

ER -

ID: 111819909