Research output: Contribution to journal › Article › peer-review
The theory of the equation of state formulated earlier and based on excluded volume analysis was extended to the entire density range by using higher-order approximations. The equations were derived to satisfy the requirement of maximum simplicity and contained a single adjustment parameter found by numerically simulating a fluid of hard spheres. The accuracy of the equation of state was raised to 0.7% over the entire density range. Simultaneously, the best-known modern equations of state for hard spheres were reproduced and the place that each of them occupied in the hierarchy of approximations was established.
Original language | English |
---|---|
Pages (from-to) | 186-190 |
Number of pages | 5 |
Journal | Russian Journal of Physical Chemistry A |
Volume | 79 |
Issue number | 2 |
State | Published - 1 Feb 2005 |
ID: 51306674