A short review of works devoted to studying the effect of hydrogen-containing fragments of the structure (mainly H2O and OH-groups) on the physicochemical (mainly electrical) properties of oxide glass has been presented. It was noted that the conduction of alkali-free oxide glass is due to the migration of protons. When introducing alkali metal oxides in their composition in the region of low Me2O concentrations, the electric current transport is due to the combined migration of protons and alkali metal ions; the conduction due to the migration of exclusively alkali ions is observed at concentrations of alkali metal ion oxides higher than 20 mol %. It was noted that in oxide glass containing ions of alkaline earth metals the conduction is also due to the migration of impurity protons. No participation of ions of alkaline earth metals in the electricity transport was observed.

Original languageEnglish
Pages (from-to)54-58
Number of pages5
JournalGlass Physics and Chemistry
Volume41
Issue number1
DOIs
StatePublished - 2015

    Scopus subject areas

  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

    Research areas

  • concentration dependence of the electric conduction, ionic conduction, mixed protonic-ionic conduction, nature of the conduction of glass, oxide glass, protonic conduction

ID: 3936291